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    • 1. 发明授权
    • Coating agent, and resin molded article having coated layer
    • 涂布剂和具有涂层的树脂模塑制品
    • US06348537B2
    • 2002-02-19
    • US09774069
    • 2001-01-31
    • Hideyuki SugamotoOsamu KawaiTetsuya Sawano
    • Hideyuki SugamotoOsamu KawaiTetsuya Sawano
    • C08K334
    • C08F290/147C08F283/002C08F290/06C08F290/067C08F290/14C08F2222/1013C08F2222/1086C09D4/06C08F2230/085
    • A coating agent comprising 50 to 99 parts by weight of a monomer or monomer mixture (M) composed of 50 to 100% by weight of a polyfunctional (meth)acrylate monomer (m-1) having two or more (meth)acryloyloxy groups and 0 to 50% by weight of a monofunctional (meth)acrylate monomer (m-2), and 1 to 50 parts by weight of colloidal silica, wherein the colloidal silica contains colloidal silica in a narrow and long form having an average diameter of 5 to 20 nm and an average length of 40 to 300 nm in an amount of 5 to 100% by weight based on the total colloidal silica weight; and a resin molded article having a coated layer obtained by hardening this coating agent, are disclosed. This colloidal silica-containing coating agent is excellent in appearance, hardness, abrasion resistance, weather resistance, adhesion with a substrate, no need of a solvent, and the like.
    • 包含50至99重量份由50至100重量%的具有两个或多个(甲基)丙烯酰氧基的多官能(甲基)丙烯酸酯单体(m-1)组成的单体或单体混合物(M)的涂料, 0〜50重量%的单官能(甲基)丙烯酸酯单体(m-2),和1〜50重量份胶体二氧化硅,其中,胶体二氧化硅含有平均粒径为5〜 至20nm,平均长度为40〜300nm,相对于总胶体二氧化硅重量为5〜100重量% 并且公开了具有通过使该涂布剂硬化而得到的涂布层的树脂成形品。 这种胶态二氧化硅的涂布剂的外观,硬度,耐磨性,耐候性,与基材的粘合性,不需要溶剂等都是优异的。
    • 2. 发明授权
    • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them
    • 丙烯酸树脂,树脂板,用于触摸面板的透明电极板,触摸面板及其制造方法
    • US08231981B2
    • 2012-07-31
    • US12171074
    • 2008-07-10
    • Hideyuki SugamotoOsamu KawaiHiroki Hatakeyama
    • Hideyuki SugamotoOsamu KawaiHiroki Hatakeyama
    • B23B27/00B23B27/08
    • G06F3/045C08F220/18Y10T428/31855Y10T428/31909
    • A method of producing an acrylic resin plate, comprising a step of adding 0.001 to 1 part by weight of a polymerization initiator having 10 hours half life temperature of 80° C. or more and 0.015 to 0.2 parts by weight of cyclohexadiene or terpenoid-based compound into 100 parts by weight of a mixture composed of an alkyl methacrylate having a C1-4 alkyl group and a poly-functional (meth)acrylate to give a polymerizable mixture, and a step of polymerizing said polymerizable mixture; an acrylic resin comprising 3 to 30 wt % of an alkyl methacrylate unit having a C8-20 alkyl group, 2 to 35 wt % of a mono-ethylenically unsaturated monomer unit containing an alkyl methacrylate unit having a C1-4 alkyl group and 35 to 95 wt % of a poly-functional (meth)acrylate unit; an acrylic resin plate made of the resin and production process the same, and a transparent electrode plate for touch panel and a touch panel having them.
    • 一种丙烯酸树脂板的制造方法,其特征在于,包括将0.001〜1重量份的10分钟半衰期为80℃以上的聚合引发剂和0.015〜0.2重量份的环己二烯或萜类系 将100重量份由具有C1-4烷基的甲基丙烯酸烷基酯和多官能(甲基)丙烯酸酯组成的混合物混合,得到可聚合的混合物,以及使所述可聚合混合物聚合的步骤; 包含3至30重量%的具有C8-20烷基的甲基丙烯酸烷基酯单元,2至35重量%的含有具有C 1-4烷基的甲基丙烯酸烷基酯单元的单烯属不饱和单体单元和35至 95重量%的多官能(甲基)丙烯酸酯单元; 由树脂制成的丙烯酸树脂板和制造方法相同,以及用于触摸面板的透明电极板和具有它们的触摸面板。
    • 3. 发明申请
    • ACRYLIC RESIN, RESIN BOARDS, TRANSPARENT ELECTRODE BOARDS FOR TOUCH PANELS, TOUCH PANELS, AND PROCESSES FOR PRODUCTION OF THEM
    • 丙烯酸树脂,树脂板,触控面板,触控面板的透明电极板及其生产工艺
    • US20080278457A1
    • 2008-11-13
    • US12171074
    • 2008-07-10
    • Hideyuki SugamotoOsamu KawaiHiroki Hatakeyama
    • Hideyuki SugamotoOsamu KawaiHiroki Hatakeyama
    • G06F3/044B29D11/00
    • G06F3/045C08F220/18Y10T428/31855Y10T428/31909
    • A method of producing an acrylic resin plate, comprising a step of adding 0.001 to 1 part by weight of a polymerization initiator having 10 hours half life temperature of 80° C. or more and 0.015 to 0.2 parts by weight of cyclohexadiene or terpenoid-based compound into 100 parts by weight of a mixture composed of an alkyl methacrylate having a C1-4 alkyl group and a poly-functional (meth)acrylate to give a polymerizable mixture, and a step of polymerizing said polymerizable mixture; an acrylic resin comprising 3 to 30 wt % of an alkyl methacrylate unit having a C8-20 alkyl group, 2 to 35 wt % of a mono-ethylenically unsaturated monomer unit containing an alkyl methacrylate unit having a C1-4 alkyl group and 35 to 95 wt % of a poly-functional (meth)acrylate unit; an acrylic resin plate made of the resin and production process the same, and a transparent electrode plate for touch panel and a touch panel having them.
    • 一种丙烯酸树脂板的制造方法,其特征在于,包括将0.001〜1重量份的10分钟半衰期为80℃以上的聚合引发剂和0.015〜0.2重量份的环己二烯或萜类系 将100重量份由具有C1-4烷基的甲基丙烯酸烷基酯和多官能(甲基)丙烯酸酯组成的混合物混合,得到可聚合的混合物,以及使所述可聚合混合物聚合的步骤; 包含3至30重量%的具有C8-20烷基的甲基丙烯酸烷基酯单元,2至35重量%的含有具有C 1-4烷基的甲基丙烯酸烷基酯单元的单烯属不饱和单体单元和35至 95重量%的多官能(甲基)丙烯酸酯单元; 由树脂制成的丙烯酸树脂板和制造方法相同,以及用于触摸面板的透明电极板和具有它们的触摸面板。
    • 4. 发明申请
    • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them
    • 丙烯酸树脂,树脂板,用于触摸面板的透明电极板,触摸面板及其制造方法
    • US20060041067A1
    • 2006-02-23
    • US10534525
    • 2003-11-10
    • Hideyuki SugamotoOsamu Kawai
    • Hideyuki SugamotoOsamu Kawai
    • C08L61/00C08K5/07
    • G06F3/045C08F220/18Y10T428/31855Y10T428/31909
    • A method of producing an acrylic resin plate, comprising a step of adding 0.001 to 1 part by weight of a polymerization initiator having 10 hours half life temperature of 80° C. or more and 0.015 to 0.2 parts by weight of cyclohexadiene or terpenoid-based compound into 100 parts by weight of a mixture composed of an alkyl methacrylate having a C1-4 alkyl group and a poly-functional (meth)acrylate to give a polymerizable mixture, and a step of polymerizing said polymerizable mixture; an acrylic resin comprising 3 to 30 wt % of an alkyl methacrylate unit having a C8-20 alkyl group, 2 to 35 wt % of a mono-ethylenically unsaturated monomer unit containing an alkyl methacrylate unit having a C1-4 alkyl group and 35 to 95 wt % of a poly-functional (meth)acrylate unit; an acrylic resin plate made of the resin and production process the same, and a transparent electrode plate for touch panel and a touch panel having them.
    • 一种丙烯酸树脂板的制造方法,其特征在于,包括将0.001〜1重量份的10分钟半衰期为80℃以上的聚合引发剂和0.015〜0.2重量份的环己二烯或萜类系 将100重量份由具有C1-4烷基的甲基丙烯酸烷基酯和多官能(甲基)丙烯酸酯组成的混合物混合,得到可聚合的混合物,以及使所述可聚合混合物聚合的步骤; 包含3至30重量%的具有C8-20烷基的甲基丙烯酸烷基酯单元,2至35重量%的含有具有C 1-4烷基的甲基丙烯酸烷基酯单元的单烯属不饱和单体单元和35至 95重量%的多官能(甲基)丙烯酸酯单元; 由树脂制成的丙烯酸树脂板和制造方法相同,以及用于触摸面板的透明电极板和具有它们的触摸面板。