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1. 发明授权

US07776784B2 Hydrodesulfurization catalyst and hydrodesulfurization process for gasoline fractions 有权
$Hydrodesulfurization catalyst and hydrodesulfurization process for gasoline fractions$
标题翻译：汽油馏分的加氢脱硫催化剂和加氢脱硫工艺
公开(公告)号：US07776784B2
公开(公告)日：2010-08-17
申请号：US10888972
申请日：2004-07-13
申请人： Hideshi Iki , Shigeto Hatanaka , Eitaro Morita , Shinya Takahashi
发明人： Hideshi Iki , Shigeto Hatanaka , Eitaro Morita , Shinya Takahashi
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00 , B01J29/00
CPC分类号： B01J37/0009 , B01J23/88 , B01J23/885 , B01J23/8871 , B01J23/8873 , B01J35/1019 , B01J35/1038 , B01J37/0207 , B01J37/20 , C10G45/08
摘要： A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.
摘要翻译：用于催化裂化汽油加氢脱硫的加氢脱硫催化剂包括主要由氧化物组成的载体，该氧化铝用选自铁，铬，钴，镍，铜，锌，钇，钪和镧系元素中的至少一种金属的氧化物，具有至少一种选自负载作为活性金属的6A族和第8族金属的金属在载体上。作为汽油的重要成分基的催化裂化汽油馏分的加氢脱硫期间作为副产物生成的烯烃的氢化可以充分地抑制维持辛烷值，同时充分降低加氢脱硫催化裂化汽油馏分的硫含量。

2. 发明申请

US20050023192A1 Hydrodesulfurization catalyst and hydrodesulfurization process for gasoline fractions 有权
$Hydrodesulfurization catalyst and hydrodesulfurization process for gasoline fractions$
标题翻译：汽油馏分的加氢脱硫催化剂和加氢脱硫工艺
公开(公告)号：US20050023192A1
公开(公告)日：2005-02-03
申请号：US10888972
申请日：2004-07-13
申请人： Hideshi Iki , Shigeto Hatanaka , Eitaro Morita , Shinya Takahashi
发明人： Hideshi Iki , Shigeto Hatanaka , Eitaro Morita , Shinya Takahashi
IPC分类号： B01J23/88 , B01J23/885 , B01J23/887 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/20 , C10G45/08 , C10G45/04
CPC分类号： B01J37/0009 , B01J23/88 , B01J23/885 , B01J23/8871 , B01J23/8873 , B01J35/1019 , B01J35/1038 , B01J37/0207 , B01J37/20 , C10G45/08
摘要： A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.
摘要翻译：用于催化裂化汽油加氢脱硫的加氢脱硫催化剂包括主要由氧化物组成的载体，该氧化铝用至少一种选自铁，铬，钴，镍，铜，锌，钇，钪和镧系元素的金属的氧化物，具有至少一种选自负载作为活性金属的6A族和第8族金属的金属在载体上。作为汽油的重要成分基的催化裂化汽油馏分的加氢脱硫期间作为副产物生成的烯烃的氢化可以充分地抑制维持辛烷值，同时充分降低加氢脱硫催化裂化汽油馏分的硫含量。

3. 发明授权

US06251262B1 Process for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺
公开(公告)号：US06251262B1
公开(公告)日：2001-06-26
申请号：US09377087
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6504
CPC分类号： C10G65/04 , C10G2400/04
摘要： Diesel gas oil feedstock with 1-3 wt % sulfur can be hydrodesulfurized to a diesel gas oil with 0.05 wt % or less sulfur and a Saybolt color of +20 or higher, by defining a hydrogenation region in a fixed bed reactor with a first hydrogenation zone for dibenzothiophene, 1-, 2- and 3-methyldibenzothiophenes, a second hydrogenation zone for 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene and a third hydrogenation zone for thiols, sulfides and other sulfur-containing substances.
摘要翻译：通过在具有第一氢化的固定床反应器中限定氢化区域，可以将具有1-3重量％硫的柴油瓦斯油原料加氢脱硫至具有0.05重量％或更少硫并且Saybolt颜色为+ 20以上的柴油瓦斯油二苯并噻吩，1-，2-和3-甲基二苯并噻吩的区域，4-甲基二苯并噻吩和4,6-二甲基二苯并噻吩的第二氢化区和用于硫醇，硫化物和其它含硫物质的第三氢化区。

4. 发明申请

US20100219102A1 PROCESS FOR PRODUCING GASOLINE BASE AND GASOLINE 有权
标题翻译：生产汽油基和汽油的方法
公开(公告)号：US20100219102A1
公开(公告)日：2010-09-02
申请号：US12681787
申请日：2008-10-06
申请人： Shigeto Hatanaka , Koji Shimada , Hideshi Iki
发明人： Shigeto Hatanaka , Koji Shimada , Hideshi Iki
IPC分类号： C10G69/02
CPC分类号： C10G11/00 , C10G45/02 , C10G45/04 , C10G65/04 , C10G69/04 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/02 , C10L1/06
摘要： The production process of the invention comprises a first step of hydrodesulfurizing of catalytically-cracked gasoline so as to result in an olefin hydrogenation rate of no greater than 25 mol % in the catalytically-cracked gasoline, a total sulfur content of no greater than 20 ppm by weight based on the product oil weight, a sulfur content derived from thiophenes and benzothiophenes of no greater than 5 ppm by weight and a sulfur content derived from thiacyclopentanes of no greater than 0.1 ppm by weight, and a second step of further hydrodesulfurizing of the product oil obtained by the first step so as to result in a total of no greater than 30 mol % for the olefin hydrogenation rate in the first step and the olefin hydrogenation rate in the second step, a total sulfur content of no greater than 10 ppm by weight based on the product oil weight, and a sulfur content derived from thiols of no greater than 5 ppm by weight.
摘要翻译：本发明的制造方法包括催化裂化汽油的加氢脱硫的第一步骤，使催化裂化汽油中的烯烃氢化率不大于25mol％，总硫含量不大于20ppm 基于产品油重量，来自噻吩和苯并噻吩的硫含量不大于5ppm重量，硫代环戊烷的硫含量不大于0.1ppm重量，第二步是进一步加氢脱硫通过第一步获得的产物油，以使第一步中的烯烃氢化速率和第二步中的烯烃氢化速率总共不大于30mol％，总硫含量不大于10ppm 基于产品油重量，和硫醇的硫含量不大于5重量ppm。

5. 发明授权

US08303805B2 Process for producing gasoline base and gasoline 有权
标题翻译：生产汽油基油和汽油的工艺
公开(公告)号：US08303805B2
公开(公告)日：2012-11-06
申请号：US12681787
申请日：2008-10-06
申请人： Shigeto Hatanaka , Koji Shimada , Hideshi Iki
发明人： Shigeto Hatanaka , Koji Shimada , Hideshi Iki
IPC分类号： C10G45/06 , C10G45/08 , C10G65/02
CPC分类号： C10G11/00 , C10G45/02 , C10G45/04 , C10G65/04 , C10G69/04 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/02 , C10L1/06
摘要： The production process of the invention comprises a first step of hydrodesulfurizing of catalytically-cracked gasoline so as to result in an olefin hydrogenation rate of no greater than 25 mol % in the catalytically-cracked gasoline, a total sulfur content of no greater than 20 ppm by weight based on the product oil weight, a sulfur content derived from thiophenes and benzothiophenes of no greater than 5 ppm by weight and a sulfur content derived from thiacyclopentanes of no greater than 0.1 ppm by weight, and a second step of further hydrodesulfurizing of the product oil obtained by the first step so as to result in a total of no greater than 30 mol % for the olefin hydrogenation rate in the first step and the olefin hydrogenation rate in the second step, a total sulfur content of no greater than 10 ppm by weight based on the product oil weight, and a sulfur content derived from thiols of no greater than 5 ppm by weight.
摘要翻译：本发明的制造方法包括催化裂化汽油的加氢脱硫的第一步骤，使催化裂化汽油中的烯烃氢化率不大于25mol％，总硫含量不大于20ppm 基于产品油重量，来自噻吩和苯并噻吩的硫含量不大于5ppm重量，硫代环戊烷的硫含量不大于0.1ppm重量，第二步是进一步加氢脱硫通过第一步获得的产物油，以使第一步中的烯烃氢化速率和第二步中的烯烃氢化速率总共不大于30mol％，总硫含量不大于10ppm 基于产品油重量，和硫醇的硫含量不大于5重量ppm。

6. 发明授权

US06251263B1 Process and apparatus for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺及装置
公开(公告)号：US06251263B1
公开(公告)日：2001-06-26
申请号：US09377089
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6504
CPC分类号： B01J35/0006 , B01J8/04 , B01J23/88 , B01J23/888 , B01J2208/00371 , C10G2400/04
摘要： A hydrogenation region in a fixed bed reactor is defined with a first, a second and a third hydrogenation zones sequentially from the entrance of the reactor, and a sulfur-containing diesel gas oil feedstock is passed through the first, second and third hydrogenation zones sequentially under conditions of a temperature of 320 to 420° C., a pressure of 5 to 15 MPa, an LHSV of 0.5 to 3 h−1 and a hydrogen/oil ratio of 1000 to 5000 scfb, wherein (a) a catalyst consisting essentially of cobalt and molybdenum on a porous carrier containing alumina as a main ingredient is loaded in the first hydrogenation zone in an amount of 20 to 60 vol %, (b) a catalyst consisting essentially of nickel and tungsten on a porous carrier containing 85 to 99 wt % of alumina or amorphous silica-alumina and 1 to 15 wt % of zeolite is loaded in the second hydrogenation zone in an amount of 20 to 60 vol % and (c) a catalyst consisting essentially of cobalt and/or nickel and molybdenum on a porous carrier containing alumina as a main ingredient is loaded in the third hydrogenation zone in an amount of 10 to 30 vol %.
摘要翻译：固定床反应器中的氢化区域从反应器的入口顺序地由第一，第二和第三加氢区定义，并且含硫柴油原料按顺序通过第一，第二和第三加氢区在温度为320〜420℃，压力为5〜15MPa，LHSV为0.5〜3h -1，氢/油比为1000〜5000scfb的条件下，（a）基本上由在含有氧化铝作为主要成分的多孔载体上的钴和钼以20至60体积％的量装载在第一氢化区中，（b）主要由镍和钨组成的催化剂在含有85至99的多孔载体上氧化铝或无定形二氧化硅 - 氧化铝的重量％和1至15重量％的沸石以20至60体积％的量装载在第二氢化区中，和（c）基本上由钴和/或镍和钼组成的催化剂多孔载体包含以氧化铝为主要成分，以10〜30体积％的量负载在第3氢化区中。

7. 发明授权

US06217748B1 Process for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺
公开(公告)号：US06217748B1
公开(公告)日：2001-04-17
申请号：US09378001
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6502
CPC分类号： C10G65/00 , C10G2400/04
摘要： A process for hydrodesulfurization of a sulfur-containing petroleum hydrocarbon diesel gas oil comprising; hydrodesulfurizing a sulfur-containing petroleum hydrocarbon diesel gas oil feedstock, separating the hydrodesulfurized diesel gas oil feedstock into light and heavy fractions by distillation, hydrodesulfurizing further the separated heavy fraction, and mixing the further hydrodesulfurized heavy fraction and the separated light fraction into the hydrocarbon diesel gas oil.
摘要翻译：一种含硫石油烃柴油瓦斯油的加氢脱硫方法，包括：加氢脱硫含硫石油烃柴油瓦斯油原料，通过蒸馏将加氢脱硫柴油机原料分离成轻馏分，再加氢脱硫分离的重馏分，再将加氢脱硫重馏分与分离的轻馏分混合成烃柴油瓦斯油。

8. 发明申请

US20070175797A1 Hydrodesulfurization Catalyst for Petroleum Hydrocarbons and Process for Hydrodesulfurization Using the Same 审中-公开
标题翻译：石油烃加氢脱硫催化剂及其加氢脱硫方法
公开(公告)号：US20070175797A1
公开(公告)日：2007-08-02
申请号：US11626074
申请日：2007-01-23
申请人： Hideshi Iki , Kazuaki Hayasaka , Shinya Takahashi
发明人： Hideshi Iki , Kazuaki Hayasaka , Shinya Takahashi
IPC分类号： C10G45/04 , C10G45/60 , B01J27/00 , B01J27/188 , B01J27/19 , B01J27/182
CPC分类号： C10G45/08 , B01J27/19
摘要： The present invention provides a hydrodesulfurization that can attain an extremely high depth of desulfurization to a sulfur content of 10 ppm by mass and maintain such a high desulfurization activity for a long period of time. The catalyst comprises an inorganic porous support containing alumina and phosphorus, at least one active metal selected from the metals of Group 8 of the periodic table, and at least one metal selected from the metals of Group 6A of the periodic table, the Group 8 metal and the Group 6A metal being contained in a molar ratio defined by (oxide of the Group 8 metal)/(oxide of the Group 6A metal) ranging from 0.055 to 0.150, and the content of the Group 6A metal in terms of oxide being in the range of 30 to 40 percent by mass based on the mass of the catalyst.
摘要翻译：本发明提供一种能够达到非常高的脱硫深度至硫酸含量为10质量ppm的加氢脱硫，并且长期保持如此高的脱硫活性。催化剂包括含有氧化铝和磷的无机多孔载体，选自元素周期表第8族金属的至少一种活性金属和选自元素周期表第6A族金属中的至少一种金属，第8族金属并且6A族金属以（由第8族金属的氧化物）/（6A族金属的氧化物）定义的摩尔比包含在0.055〜0.150的范围内，6A族金属的含量以氧化物为单位相对于催化剂的质量为30〜40质量％的范围。

9. 发明申请

US20060211900A1 Method of hydrotreating gas oil fraction 审中-公开
$Method of hydrotreating gas oil fraction$
标题翻译：加氢处理瓦斯油馏分的方法
公开(公告)号：US20060211900A1
公开(公告)日：2006-09-21
申请号：US10548313
申请日：2004-03-05
申请人： Hideshi Iki , Yukihiro Sugiura , Yuichi Tanaka , Shinya Takahashi
发明人： Hideshi Iki , Yukihiro Sugiura , Yuichi Tanaka , Shinya Takahashi
IPC分类号： C07C1/00
CPC分类号： B01J23/85 , B01J23/883 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/20 , C10G2400/06
摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a gas oil fraction with a sulfur content of 0.8-2% by mass and a total aromatic content of 20-35% by volume as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst comprising at least one metal from among Group 6A metals and at least one metal from among Group 8 metals as active metals, and under reaction conditions with a reaction temperature of 330-390° C., a hydrogen partial pressure of 12-20 MPa and a liquid hourly space velocity of 0.1-1 h−1, to obtain an ultralow sulfur and low- aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.
摘要翻译：本发明的粗柴油馏分加氢处理方法的特征在于，使用硫含量为0.8〜2质量％，总芳烃含量为20〜35体积％的粗柴油馏分作为原料油，在包含至少一种金属的6A族金属和至少一种金属作为活性金属的第8族金属中进行加氢处理，在反应温度为330-390℃的反应条件下，加氢处理 12-20MPa的分压和0.1-1小时-1的液时空速，得到硫含量不大于1ppm的超低硫和低芳烃瓦斯油馏分并且总芳族含量不大于1体积％。该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

10. 发明申请

US20060260983A1 Method of hydrotreating gas oil fraction 审中-公开
$Method of hydrotreating gas oil fraction$
标题翻译：加氢处理瓦斯油馏分的方法
公开(公告)号：US20060260983A1
公开(公告)日：2006-11-23
申请号：US10548315
申请日：2004-03-05
申请人： Hideshi Iki , Yukihiro Sugiura , Yuichi Tanaka
发明人： Hideshi Iki , Yukihiro Sugiura , Yuichi Tanaka
IPC分类号： C07C37/00 , C10G45/04 , C10G25/00 , C10G45/60
CPC分类号： C10G45/44 , B01J29/126 , C10G2300/1059 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/06
摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a hydrorefined petroleum-based hydrocarbon oil with a sulfur content of 5-15 ppm by mass, a total aromatic content of 10-25% by volume and a boiling point range of 150-380° C. as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst to obtain an ultralow sulfur and low aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.
摘要翻译：本发明的粗柴油馏分加氢处理方法的特征在于使用硫含量为5〜15质量ppm的加氢精制石油基烃油，总芳族化合物含量为10〜25体积％，沸点范围为150 -380℃作为原料油，并在进料油在氢化催化剂存在下进行加氢处理，得到硫含量不大于1质量ppm的超低硫和低芳烃馏分，总芳烃含量不超过1％（体积）。该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

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