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1. 发明授权

US07429550B2 Hydrogenation catalyst for hydrocarbon oil and process for hydrogenation using the catalyst 有权
标题翻译：用于烃油的氢化催化剂和使用该催化剂的氢化方法
公开(公告)号：US07429550B2
公开(公告)日：2008-09-30
申请号：US11567374
申请日：2006-12-06
申请人： Hideshi Iki , Kazuaki Hayasaka , Kazuo Fukazawa
发明人： Hideshi Iki , Kazuaki Hayasaka , Kazuo Fukazawa
IPC分类号： B01J21/12 , B01J27/18 , C10G47/18 , C10G47/20 , C10G45/12
CPC分类号： C10G49/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J27/182 , B01J27/19 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/0009 , B01J37/0203 , B01J37/03 , C10G49/08
摘要： A hydrogenation catalyst for a hydrocarbon oil, includes an inorganic porous support composed of at least the oxides of aluminum, phosphorus, and silicon, and supporting at least one active metal selected from the metals of Group 8 of the periodic table, at least one active metal selected from the metals of Group 6 of the periodic table, and phosphorus, the phosphorus chemical shift value of the inorganic support determined by 31P-CPMAS-NMR having the peak within the range of 0 to −20 ppm. The catalyst can achieve an extremely high level of hydrogenation wherein the hydrocarbon is decreased in sulfur content to 10 ppm by mass or less and in nitrogen content to 3 ppm by mass or less.
摘要翻译：用于烃油的氢化催化剂包括至少由铝，磷和硅的氧化物组成的无机多孔载体，并且支持选自元素周期表第8族金属中的至少一种活性金属，至少一种活性选自元素周期表第6族金属的金属和磷，由POD-NMR-NMR确定的无机载体的磷化学位移值，峰值在0至 - 20 ppm。催化剂可以实现极高的氢化水平，其中烃的含量降低到10质量ppm以下，氮含量降低到3质量ppm以下。

2. 发明申请

US20120217186A1 METHOD FOR PRODUCING LUBRICANT BASE OIL 有权
标题翻译：生产润滑油基油的方法
公开(公告)号：US20120217186A1
公开(公告)日：2012-08-30
申请号：US13391067
申请日：2010-08-06
申请人： Kazuaki Hayasaka , Hideki Ono , Yoshiyuki Nagayasu , Masahiro Taguchi , Hideshi Iki
发明人： Kazuaki Hayasaka , Hideki Ono , Yoshiyuki Nagayasu , Masahiro Taguchi , Hideshi Iki
IPC分类号： C10G73/38
CPC分类号： C10G65/02 , B01J21/066 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J29/7484 , B01J35/002 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02 , C10M2203/1025 , C10M2205/173 , C10N2220/026 , C10N2220/027 , C10N2220/028 , C10N2220/031 , C10N2230/02 , C10N2230/10 , C10N2230/43 , C10N2240/10 , C10N2270/00 , C10N2220/022
摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要翻译：一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触存在分子氢以获得第二产生的油。第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

3. 发明申请

US20120216449A1 METHOD FOR PRODUCING AVIATION FUEL OIL BASE AND AVIATION FUEL OIL COMPOSITION 有权
标题翻译：制造航空燃油油基和航空燃料油组合物的方法
公开(公告)号：US20120216449A1
公开(公告)日：2012-08-30
申请号：US13391727
申请日：2010-08-30
申请人： Kazuaki Hayasaka , Hideki Ono , Akira Koyama , Hideshi Iki
发明人： Kazuaki Hayasaka , Hideki Ono , Akira Koyama , Hideshi Iki
IPC分类号： C10L1/188
CPC分类号： B01J29/7484 , B01J23/85 , B01J23/883 , B01J29/7461 , B01J29/7492 , B01J29/85 , C10G3/46 , C10G3/49 , C10G3/50 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： A method for producing an aviation fuel oil base includes obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6A of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.
摘要翻译：一种航空燃料油基料的制造方法，其特征在于，通过使来自动物或植物油脂的含氧烃化合物的原料与第一双官能催化剂接触而进行加氢处理，得到第一产生油，脱氢和氢化功能，其包括周期表第6A族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触来获得包含航空燃料油基的第二产生的油，该第二双功能催化剂包括周期性的第8族金属表和结晶固体酸性物质，在氢的存在下。

4. 发明申请

US20070175797A1 Hydrodesulfurization Catalyst for Petroleum Hydrocarbons and Process for Hydrodesulfurization Using the Same 审中-公开
标题翻译：石油烃加氢脱硫催化剂及其加氢脱硫方法
公开(公告)号：US20070175797A1
公开(公告)日：2007-08-02
申请号：US11626074
申请日：2007-01-23
申请人： Hideshi Iki , Kazuaki Hayasaka , Shinya Takahashi
发明人： Hideshi Iki , Kazuaki Hayasaka , Shinya Takahashi
IPC分类号： C10G45/04 , C10G45/60 , B01J27/00 , B01J27/188 , B01J27/19 , B01J27/182
CPC分类号： C10G45/08 , B01J27/19
摘要： The present invention provides a hydrodesulfurization that can attain an extremely high depth of desulfurization to a sulfur content of 10 ppm by mass and maintain such a high desulfurization activity for a long period of time. The catalyst comprises an inorganic porous support containing alumina and phosphorus, at least one active metal selected from the metals of Group 8 of the periodic table, and at least one metal selected from the metals of Group 6A of the periodic table, the Group 8 metal and the Group 6A metal being contained in a molar ratio defined by (oxide of the Group 8 metal)/(oxide of the Group 6A metal) ranging from 0.055 to 0.150, and the content of the Group 6A metal in terms of oxide being in the range of 30 to 40 percent by mass based on the mass of the catalyst.
摘要翻译：本发明提供一种能够达到非常高的脱硫深度至硫酸含量为10质量ppm的加氢脱硫，并且长期保持如此高的脱硫活性。催化剂包括含有氧化铝和磷的无机多孔载体，选自元素周期表第8族金属的至少一种活性金属和选自元素周期表第6A族金属中的至少一种金属，第8族金属并且6A族金属以（由第8族金属的氧化物）/（6A族金属的氧化物）定义的摩尔比包含在0.055〜0.150的范围内，6A族金属的含量以氧化物为单位相对于催化剂的质量为30〜40质量％的范围。

5. 发明授权

US09283552B2 Method for producing aviation fuel oil base and aviation fuel oil composition 有权
标题翻译：制造航空燃油基地和航空燃油组合物的方法
公开(公告)号：US09283552B2
公开(公告)日：2016-03-15
申请号：US13391727
申请日：2010-08-30
申请人： Kazuaki Hayasaka , Hideki Ono , Akira Koyama , Hideshi Iki
发明人： Kazuaki Hayasaka , Hideki Ono , Akira Koyama , Hideshi Iki
IPC分类号： C07C1/00 , B01J29/74 , B01J23/883 , C10G3/00 , C10G45/64 , C10L1/04 , B01J23/85 , B01J29/85
CPC分类号： B01J29/7484 , B01J23/85 , B01J23/883 , B01J29/7461 , B01J29/7492 , B01J29/85 , C10G3/46 , C10G3/49 , C10G3/50 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： A method for producing an aviation fuel oil base, including: a first step of obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6B of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and a second step of obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.
摘要翻译：一种生产航空燃料油基料的方法，包括：第一步骤，通过将包含来源于动物或植物油脂的含氧烃化合物的原料与一种原料接触而将原料加氢处理获得第一产生的油具有脱氢和氢化功能的第一双官能催化剂，其包含周期表第6B族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及第二步骤，通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触，并且包括该组的金属，获得包含航空燃料油基的第二产生的油， 8和结晶固体酸性物质，在氢的存在下。

6. 发明授权

US09057026B2 Method for producing lubricant base oil 有权
标题翻译：润滑油基础油生产方法
公开(公告)号：US09057026B2
公开(公告)日：2015-06-16
申请号：US13391067
申请日：2010-08-06
申请人： Kazuaki Hayasaka , Hideki Ono , Yoshiyuki Nagayasu , Masahiro Taguchi , Hideshi Iki
发明人： Kazuaki Hayasaka , Hideki Ono , Yoshiyuki Nagayasu , Masahiro Taguchi , Hideshi Iki
IPC分类号： C10G73/38 , C10G65/02 , B01J21/06 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/04 , C10G73/00 , C10M101/02 , B01J29/74
CPC分类号： C10G65/02 , B01J21/066 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J29/7484 , B01J35/002 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02 , C10M2203/1025 , C10M2205/173 , C10N2220/026 , C10N2220/027 , C10N2220/028 , C10N2220/031 , C10N2230/02 , C10N2230/10 , C10N2230/43 , C10N2240/10 , C10N2270/00 , C10N2220/022
摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要翻译：一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触存在分子氢以获得第二产生的油。第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

7. 发明申请

US20060260983A1 Method of hydrotreating gas oil fraction 审中-公开
$Method of hydrotreating gas oil fraction$
标题翻译：加氢处理瓦斯油馏分的方法
公开(公告)号：US20060260983A1
公开(公告)日：2006-11-23
申请号：US10548315
申请日：2004-03-05
申请人： Hideshi Iki , Yukihiro Sugiura , Yuichi Tanaka
发明人： Hideshi Iki , Yukihiro Sugiura , Yuichi Tanaka
IPC分类号： C07C37/00 , C10G45/04 , C10G25/00 , C10G45/60
CPC分类号： C10G45/44 , B01J29/126 , C10G2300/1059 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/06
摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a hydrorefined petroleum-based hydrocarbon oil with a sulfur content of 5-15 ppm by mass, a total aromatic content of 10-25% by volume and a boiling point range of 150-380° C. as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst to obtain an ultralow sulfur and low aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.
摘要翻译：本发明的粗柴油馏分加氢处理方法的特征在于使用硫含量为5〜15质量ppm的加氢精制石油基烃油，总芳族化合物含量为10〜25体积％，沸点范围为150 -380℃作为原料油，并在进料油在氢化催化剂存在下进行加氢处理，得到硫含量不大于1质量ppm的超低硫和低芳烃馏分，总芳烃含量不超过1％（体积）。该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

8. 发明授权

US06251262B1 Process for hydrodesulfurization of diesel gas oil 有权
标题翻译：柴油机加氢脱硫工艺
公开(公告)号：US06251262B1
公开(公告)日：2001-06-26
申请号：US09377087
申请日：1999-08-19
申请人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
发明人： Shigeto Hatanaka , Osamu Sadakane , Hideshi Iki
IPC分类号： C10G6504
CPC分类号： C10G65/04 , C10G2400/04
摘要： Diesel gas oil feedstock with 1-3 wt % sulfur can be hydrodesulfurized to a diesel gas oil with 0.05 wt % or less sulfur and a Saybolt color of +20 or higher, by defining a hydrogenation region in a fixed bed reactor with a first hydrogenation zone for dibenzothiophene, 1-, 2- and 3-methyldibenzothiophenes, a second hydrogenation zone for 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene and a third hydrogenation zone for thiols, sulfides and other sulfur-containing substances.
摘要翻译：通过在具有第一氢化的固定床反应器中限定氢化区域，可以将具有1-3重量％硫的柴油瓦斯油原料加氢脱硫至具有0.05重量％或更少硫并且Saybolt颜色为+ 20以上的柴油瓦斯油二苯并噻吩，1-，2-和3-甲基二苯并噻吩的区域，4-甲基二苯并噻吩和4,6-二甲基二苯并噻吩的第二氢化区和用于硫醇，硫化物和其它含硫物质的第三氢化区。

9. 发明授权

US09447333B2 Aviation fuel base oil and aviation fuel composition 有权
标题翻译：航空燃料基础油和航空燃料组成
公开(公告)号：US09447333B2
公开(公告)日：2016-09-20
申请号：US13130155
申请日：2009-11-19
申请人： Akira Koyama , Tatsuo Hamamatsu , Yasutoshi Iguchi , Hideshi Iki
发明人： Akira Koyama , Tatsuo Hamamatsu , Yasutoshi Iguchi , Hideshi Iki
IPC分类号： C10L1/24 , C10L1/26 , C10G3/00 , C10L1/04
CPC分类号： C10G3/44 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： The present invention provides an environment friendly aviation fuel base oil having combustibility, oxidation stability and excellent life cycle characteristics and contributing to diversification of primary energy, which is produced by hydrotreating a feedstock comprising a mixed oil of an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat and a sulfur-containing hydrocarbon compound or a feedstock comprising said mixed oil and a petroleum base oil produced by refining crude oil and an aviation fuel composition comprising the aviation fuel base oil, and an aviation fuel composition containing such an aviation fuel base oil.
摘要翻译：本发明提供一种具有可燃性，氧化稳定性和优异的寿命周期特性的环境友好的航空燃料基础油，并且有助于一次能量的多样化，其通过加氢处理包含源自动物或植物脂肪和含硫烃化合物或包含所述混合油的原料和通过精炼原油生产的石油基础油和包含航空燃料基础油的航空燃料组合物，以及含有这种航空燃料的航空燃料组合物基础油

10. 发明授权

US07914593B2 Fuel composition 有权
标题翻译：燃油组成
公开(公告)号：US07914593B2
公开(公告)日：2011-03-29
申请号：US12294110
申请日：2007-02-22
申请人： Masanori Hirose , Hideshi Iki
发明人： Masanori Hirose , Hideshi Iki
IPC分类号： C10L1/10
CPC分类号： C10G47/16 , C10G2/00 , C10G45/08 , C10G65/14 , C10G69/04 , C10G2300/1022 , C10G2300/1096 , C10G2300/301 , C10L1/04
摘要： The present invention provides a fuel composition capable of suppressing reduction of fuel consumption, maintaining the excellent exhaust gas properties of a Fischer-Tropsch synthetic oil. The fuel composition comprises a Fischer-Tropsch synthetic oil and a petroleum-based hydrocarbon mixture A having the following properties (1) to (5) in an amount of 10 to 30 percent by volume on the basis of the total mass of the composition: (1) 15° C. density: 800 Kg/cm3 or greater and 900 Kg/m3 or less; (2) 10 volume % distillation temperature (T10): 150° C. or higher and 200° C. or lower; (3) 97 volume % distillation temperature (T97): 270° C. or lower; (4) aromatic content: 40 percent by volume or more and 70 percent by volume or less; and (5) sulfur content: 30 ppm by mass or less.
摘要翻译：本发明提供能够抑制燃料消耗的降低，维持费 - 托合成油优异的废气性能的燃料组合物。燃料组合物包含基于组合物的总质量的10至30体积％的具有以下性质（1）至（5）的费 - 托合成油和石油基烃混合物A：（1）15℃密度：800Kg / cm 3以上900kg / m 3以下; （2）10体积％蒸馏温度（T10）：150℃以上且200℃以下; （3）97体积％蒸馏温度（T97）：270℃以下; （4）芳香族含量：40体积％以上且70体积％以下; 和（5）硫含量：30质量ppm以下。

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