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1. 发明授权

US5478384A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5478384A
公开(公告)日：1995-12-26
申请号：US238734
申请日：1994-05-05
申请人： Hiroshi Takimoto , Tomio Yoneyama , Hideo Sano , Yukichi Murata , Masahiro Yamada
发明人： Hiroshi Takimoto , Tomio Yoneyama , Hideo Sano , Yukichi Murata , Masahiro Yamada
IPC分类号： C09B31/08 , C09B31/18 , C09D11/00 , C09D11/02
CPC分类号： C09D11/32 , C09B31/08 , C09B31/18 , C09D11/328
摘要： A recording liquid excellent in print quality, light resistance, and water resistance which is characterized in that it contains an aqueous medium and at least one dye selected from the dyes represented by general formulae [I] to [V]: ##STR1## (wherein R.sub.1 and R.sub.2 each represents H, CH.sub.3, or OCH.sub.3 ; R.sub.3 represents H, Cl,CH.sub.3, or OCH.sub.3 ; R.sub.4 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, a tolyl group, or an anisyl group; R.sub.5 represents H, a phenyl group which may be substituted with a COOM group, or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; R.sub.6 represents H or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; X represents SO.sub.3 M or COOM; Y represents --CO-- or --SO.sub.2 --; m represents 1 or 2; n represents 0 or 1; A represents a phenylene group which may have one or more members selected from the group consisting of an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, an amino group, a --COOM group, a hydroxyl group, an --SO.sub.3 M group, and a halogen atom; and M represents an alkali metal, an ammonium group, or an organic amine salt.)
摘要翻译：印刷质量，耐光性和耐水性优异的记录液，其特征在于，其含有水性介质和选自通式[I]〜[V]表示的染料中的至少一种染料：（IV）其中R 1和R 2各自表示H，CH 3或OCH 3; R 3表示H，Cl，CH 3或 OCH 3; R 4表示碳原子数1〜6的烷基，苯基，甲苯基或茴香基; R 5表示H，可以被COOM基取代的苯基或具有1〜被COOM基团取代的3个碳原子; R6表示H或被COOM基团取代的具有1至3个碳原子的烷基; X表示SO 3 M或COOM; Y表示-CO-或-SO 2 - ; m表示 1或2; n表示0或1; A表示可以具有一个或多个选自具有1至4个碳的烷基的一个或多个的亚苯基具有1至4个碳原子的烷氧基，氨基，-COOM基，羟基，-SO 3 M基和卤素原子; M表示碱金属，铵基或有机胺盐。

2. 发明授权

US5437716A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5437716A
公开(公告)日：1995-08-01
申请号：US242627
申请日：1994-05-13
申请人： Hideo Sano , Tomio Yoneyama , Yukichi Murata , Masahiro Yamada
发明人： Hideo Sano , Tomio Yoneyama , Yukichi Murata , Masahiro Yamada
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： A recording liquid comprising an aqueous medium and at least one dye selected from dyes, free acid forms of which are represented by formulae (I) and (II): ##STR1## The symbols in formulae (I) and (II) are defined in the specification.
摘要翻译：一种包含水性介质和至少一种选自染料（其游离酸形式由式（I）和（II）表示）的染料的记录液：（I）式（I） I）和（II）在本说明书中定义。

3. 发明授权

US5480478A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5480478A
公开(公告)日：1996-01-02
申请号：US350077
申请日：1994-11-29
申请人： Hideo Sano , Yukichi Murata , Toru Nishimura , Masahiro Yamada , Hiroshi Takimoto , Nobuyoshi Satoh
发明人： Hideo Sano , Yukichi Murata , Toru Nishimura , Masahiro Yamada , Hiroshi Takimoto , Nobuyoshi Satoh
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： A recording liquid comprising an aqueous medium and at least one dye selected from dyes, a free acid form of which is represented by formula (I), (II), (III) or (VI), the symbols in the formulae being defined in the specification: ##STR1##
摘要翻译：一种包含水性介质和选自染料的至少一种染料的记录液体，其游离酸形式由式（I），（II），（III）或（VI）表示，式中的符号定义在规格：（I）（II）

4. 发明授权

US07025815B2 Water-soluble complex dye, recording fluid and recording method 有权
标题翻译：水溶性复合染料，记录液和记录方法
公开(公告)号：US07025815B2
公开(公告)日：2006-04-11
申请号：US11005021
申请日：2004-12-07
申请人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
发明人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
IPC分类号： C09D11/02 , C09B45/00
CPC分类号： C09D11/32 , C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/0083 , C09D11/328 , C09D11/40
摘要： A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented.
摘要翻译：能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。

5. 发明申请

US20050081747A1 Water-soluble complex dye, recording fluid and recording method 有权
标题翻译：水溶性复合染料，记录液和记录方法
公开(公告)号：US20050081747A1
公开(公告)日：2005-04-21
申请号：US11005021
申请日：2004-12-07
申请人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
发明人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
IPC分类号： C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/44 , C09D11/00 , C09B45/00
CPC分类号： C09D11/32 , C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/0083 , C09D11/328 , C09D11/40
摘要： A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented. A water-soluble complex dye comprising an azo compound represented by the following formula (1) or its tautomer, and transition metal ions; a water-based recording fluid, particularly an ink jet recording fluid, containing such a dye; and an ink jet recording method employing such a recording fluid. In the formula (1), A1 is a 5- to 7-membered hetero monocyclic group or a fused polycyclic group containing such a hetero monocyclic group and may have an optional substituent, but it represents a group which does not have a hydroxyl group at a position adjacent to the carbon bonded to the azo group; ring X1 represents a monocyclic hetero ring constituted by six atoms, bonded to the azo group and may have an optional substituent; and each of R1 and R2 which are independent of each other, is a hydrogen atom or a monovalent substituent.
摘要翻译：能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。包含由下式（1）表示的偶氮化合物或其互变异构体和过渡金属离子的水溶性复合染料; 含有这种染料的水性记录液，特别是喷墨记录液; 以及采用这种记录液的喷墨记录方法。在式（1）中，A 1是5至7元杂单环基团或含有这种杂单环基团的稠合多环基团，并且可以具有任选的取代基，但它代表基团在与偶氮基结合的碳相邻的位置上不具有羟基; 环X 1表示由六个原子构成的单环杂环，键合到偶氮基并且可以具有任选的取代基; 且彼此独立的R 1和R 2各自为氢原子或一价取代基。

6. 发明授权

US5599386A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5599386A
公开(公告)日：1997-02-04
申请号：US445797
申请日：1995-05-04
申请人： Hideo Sano , Yukichi Murata , Hiroshi Takimoto
发明人： Hideo Sano , Yukichi Murata , Hiroshi Takimoto
IPC分类号： C09B29/30 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B29/30
摘要： A recording liquid comprising an aqueous medium and at least one selected from the compounds whose free acid form is represented by the formula {1}: ##STR1## wherein, R.sup.1, R.sup.2 and R.sup.3 each independently represent a substituted or unsubstituted C.sub.1-9 alkyl group, a C.sub.1-9 alkoxy group, a halogen, hydrogen, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a C.sub.1-9 alkyl- or C.sub.6-15 aryl-sulfonyl group, a COOH group or a carboxylic ester group;m is a number of 0, 1 or 2; andR.sup.4, R.sup.5 and R.sup.6 each independently represent hydrogen, a C.sub.1-18 alkyl group, a C.sub.2-18 alkenyl group, an aryl group, an aralkyl group, an alicyclic group or a heterocyclic group, any of which groups except hydrogen may have a substituent.
摘要翻译：包含水性介质和选自游离酸形式的由式{1}表示的化合物中的至少一种的记录液体：其代表取代或未取代的C1-9烷基，C1-9烷氧基，卤素，氢，羟基，取代或未取代的氨基甲酰基，取代或未取代的氨磺酰基，取代或未取代的氨基，硝基，磺酸酯基，C1-9烷基或C6-15芳基 - 磺酰基，COOH基或羧酸酯基; m是0，1或2的数字; R 4，R 5和R 6各自独立地表示氢，C 1-18烷基，C 2-18烯基，芳基，芳烷基，脂环族基或杂环基，除氢以外的基团可以具有取代基。

7. 发明授权

US4816435A Transfer sheet for thermal transfer recording 失效
标题翻译：热转印记录转印纸
公开(公告)号：US4816435A
公开(公告)日：1989-03-28
申请号：US54606
申请日：1987-05-27
申请人： Yukichi Murata , Shuichi Maeda
发明人： Yukichi Murata , Shuichi Maeda
IPC分类号： B41M5/035 , B41M5/26 , B41M5/385 , B41M5/39
CPC分类号： B41M5/3858 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914 , Y10T428/24975 , Y10T428/264 , Y10T428/265 , Y10T428/31721 , Y10T428/31786
摘要： A transfer sheet for thermal transfer recording system having a color material layer containing sublimable dyes on one surface of a base film, and said color material layer is a black color material layer containing sublimable dyes represented by following formulae (I), (II) and (III); ##STR1## in the above formulae, X and Y represent a hydrogen atom or a methyl group; --A-- represents --CO--, --COO--, or --SO.sub.2 --; and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7 represent a hydrogen atom or a substituted or unsubstituted alkyl group.
摘要翻译：一种用于热转印记录系统的转印片，其具有在基膜的一个表面上含有可升华的染料的着色材料层，并且所述着色层是含有下式（I），（II）和（三）; （I）（II）在上式中，X和Y表示氢原子或甲基; -A-表示-CO-，-COO-或-SO 2 - ; 并且R 1，R 2，R 3，R 4，R 5，R 6和R 7表示氢原子或取代或未取代的烷基。

8. 发明授权

US06866706B2 Ink for thermal transfer, sheet for thermal transfer, and thermal transfer recording method using the same 有权
标题翻译：用于热转印的油墨，用于热转印的纸和使用其的热转印记录方法
公开(公告)号：US06866706B2
公开(公告)日：2005-03-15
申请号：US10287487
申请日：2002-11-05
申请人： Mio Ishida , Yukichi Murata
发明人： Mio Ishida , Yukichi Murata
IPC分类号： B41M5/34 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , C09B23/00 , C09B25/00 , C09B29/48 , C09B67/22 , C09D11/02 , C09D11/033 , C09D11/00 , B05D1/26 , B32B27/14
CPC分类号： B41M5/385 , B41M5/345 , B41M5/3852 , B41M5/3854 , B41M5/3858 , B41M5/388 , B41M5/39
摘要： A thermal transfer ink is provided, which includes: at least one dye (a); at least one dye selected from the group including dye (b), dye (c) and a mixture thereof; and a medium; wherein (a) is a dye having a pyrazolone methine skeleton, (b) is a dye having a quinophthalone skeleton, and (c) is a dye having an aminopyrazole azo skeleton.
摘要翻译：提供一种热转印油墨，其包括：至少一种染料（a）;选自染料（b），染料（c）及其混合物的至少一种染料; 和中等; 其中（a）是具有吡唑啉酮次甲骨架的染料，（b）是具有喹酞酮骨架的染料，（c）是具有氨基吡唑偶氮骨架的染料。

9. 发明授权

US5935901A Thermal transfer recording material and thermal transfer recording method using same 失效
标题翻译：热转印记录材料和热转印记录方法使用相同
公开(公告)号：US5935901A
公开(公告)日：1999-08-10
申请号：US614135
申请日：1996-03-11
申请人： Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida , Miyuki Kuromiya
发明人： Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida , Miyuki Kuromiya
IPC分类号： B41M5/035 , B41M5/382 , B41M5/385 , B41M5/38
CPC分类号： B41M5/38207 , B41M5/3852 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation by heating, and then transferred to a recording medium disposed in an opposed relation to the transfer section, comprising:a dye represented by the general formula (I): ##STR1## where R.sup.1 and R.sup.2 are individually a substituted or unsubstituted alkyl or alkenyl group, or a cycloalkyl group, and when both R.sup.1 and R.sup.2 are unsubstituted alkyl groups, at least one of R.sup.1 and R.sup.2 is a branched alkyl group.
摘要翻译：一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，通过加热进行状态变换，然后转印到设置的记录介质上与所述转移部分相对，包括：由通式（I）表示的染料：其中R 1和R 2各自为取代或未取代的烷基或烯基或环烷基，并且当R 1和R 2均未被取代时烷基，R 1和R 2中的至少一个是支链烷基。

10. 发明授权

US5618337A Thermal transfer recording material and thermal transfer recording method using same 失效
标题翻译：热转印记录材料和热转印记录方法使用相同
公开(公告)号：US5618337A
公开(公告)日：1997-04-08
申请号：US614136
申请日：1996-03-11
申请人： Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida
发明人： Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida
IPC分类号： B41M5/385 , B41J2/05 , B41M5/388 , B41M5/39 , C09D11/02
CPC分类号： B41M5/3854
摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation such as vaporization or droplet formation by heating, and then transferred to a recording medium disposed opposed to the transfer section, comprising:a dye having a melting point of 115.degree. C. or lower and represented by the general formula (I): ##STR1## where A is a substituted or unsubstituted p-phenylene group, R.sup.1 and R.sup.2 are individually a hydrogen atom, a substituted or unsubstituted alkyl or alkenyl group, a cycloalkyl group or a substituted or unsubstituted phenyl group; and R.sup.1 may constitute a heterocyclic group composed of a five- or six-member ring in combination with said p-phenylene group A and a nitrogen atom adjacent to the p-phenytene group A, or another heterocyclic group composed of a five- or six-member ring in combination with R.sup.2 and the nitrogen atom adjacent to the p-phenylene group A.
摘要翻译：一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，经受诸如通过加热蒸发或液滴形成的状态转变，然后转移到与转印部分相对设置的记录介质中，包括：熔点为115℃或更低并由通式（I）表示的染料：其中A是取代或未取代的对亚苯基，R1和R2分别为氢原子，取代或未取代的烷基或链烯基，环烷基或取代或未取代的苯基; 并且R 1可以构成由与所述对亚苯基A和毗邻对苯基A相邻的氮原子组合的五元或六元环的杂环基或由五或六元组成的另一杂环基 - 与R2和与对亚苯基A相邻的氮原子的组合环。

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