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    • 1. 发明申请
    • Water-soluble complex dye, recording fluid and recording method
    • 水溶性复合染料,记录液和记录方法
    • US20050081747A1
    • 2005-04-21
    • US11005021
    • 2004-12-07
    • Wataru ShimizuMio IshidaHideo SanoYukichi Murata
    • Wataru ShimizuMio IshidaHideo SanoYukichi Murata
    • C09B45/18C09B45/22C09B45/24C09B45/34C09B67/44C09D11/00C09B45/00
    • C09D11/32C09B45/18C09B45/22C09B45/24C09B45/34C09B67/0083C09D11/328C09D11/40
    • A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented. A water-soluble complex dye comprising an azo compound represented by the following formula (1) or its tautomer, and transition metal ions; a water-based recording fluid, particularly an ink jet recording fluid, containing such a dye; and an ink jet recording method employing such a recording fluid. In the formula (1), A1 is a 5- to 7-membered hetero monocyclic group or a fused polycyclic group containing such a hetero monocyclic group and may have an optional substituent, but it represents a group which does not have a hydroxyl group at a position adjacent to the carbon bonded to the azo group; ring X1 represents a monocyclic hetero ring constituted by six atoms, bonded to the azo group and may have an optional substituent; and each of R1 and R2 which are independent of each other, is a hydrogen atom or a monovalent substituent.
    • 能够形成具有耐光性,耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液,特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。 包含由下式(1)表示的偶氮化合物或其互变异构体和过渡金属离子的水溶性复合染料; 含有这种染料的水性记录液,特别是喷墨记录液; 以及采用这种记录液的喷墨记录方法。 在式(1)中,A 1是5至7元杂单环基团或含有这种杂单环基团的稠合多环基团,并且可以具有任选的取代基,但它代表基团 在与偶氮基结合的碳相邻的位置上不具有羟基; 环X 1表示由六个原子构成的单环杂环,键合到偶氮基并且可以具有任选的取代基; 且彼此独立的R 1和R 2各自为氢原子或一价取代基。
    • 4. 发明授权
    • Thermal transfer recording material and thermal transfer recording
method using same
    • 热转印记录材料和热转印记录方法使用相同
    • US5618337A
    • 1997-04-08
    • US614136
    • 1996-03-11
    • Kenji ShinozakiHideki HiranoYukichi MurataMio Ishida
    • Kenji ShinozakiHideki HiranoYukichi MurataMio Ishida
    • B41M5/385B41J2/05B41M5/388B41M5/39C09D11/02
    • B41M5/3854
    • A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation such as vaporization or droplet formation by heating, and then transferred to a recording medium disposed opposed to the transfer section, comprising:a dye having a melting point of 115.degree. C. or lower and represented by the general formula (I): ##STR1## where A is a substituted or unsubstituted p-phenylene group, R.sup.1 and R.sup.2 are individually a hydrogen atom, a substituted or unsubstituted alkyl or alkenyl group, a cycloalkyl group or a substituted or unsubstituted phenyl group; and R.sup.1 may constitute a heterocyclic group composed of a five- or six-member ring in combination with said p-phenylene group A and a nitrogen atom adjacent to the p-phenytene group A, or another heterocyclic group composed of a five- or six-member ring in combination with R.sup.2 and the nitrogen atom adjacent to the p-phenylene group A.
    • 一种用于记录装置的热转印记录材料,其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中,经受诸如通过加热蒸发或液滴形成的状态转变,然后 转移到与转印部分相对设置的记录介质中,包括:熔点为115℃或更低并由通式(I)表示的染料:其中A是取代或未取代的 对亚苯基,R1和R2分别为氢原子,取代或未取代的烷基或链烯基,环烷基或取代或未取代的苯基; 并且R 1可以构成由与所述对亚苯基A和毗邻对苯基A相邻的氮原子组合的五元或六元环的杂环基或由五或六元组成的另一杂环基 - 与R2和与对亚苯基A相邻的氮原子的组合环。
    • 10. 发明授权
    • Recording liquid
    • 记录液体
    • US5713992A
    • 1998-02-03
    • US732451
    • 1997-01-13
    • Nobuyoshi SatohTakashi HirasaYukichi Murata
    • Nobuyoshi SatohTakashi HirasaYukichi Murata
    • C09B29/30C09B43/16C09D11/00C09D11/16C09D11/02
    • C09D11/32C09B29/30C09B43/16C09D11/17C09D11/328
    • The present invention relates to a recording liquid characterized by comprising an aqueous medium and at least one monoazo dye selected from dyes, the free acid forms of which are represented by general formula {I}: ##STR1## (wherein R.sub.1, R.sub.2, and R.sub.3 each independently represents a substituted or unsubstituted alkyl group having 1 to 9 carbon atoms, an alkoxy group having 1 to 9 carbon atoms, a halogen atom, a hydrogen atom, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a sulfonyl group, a COOH group, or a carboxylic ester group; m represents a number of 0, 1, or 2; and R.sub.4, R.sub.5, R.sub.6, and R.sub.7 each independently represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, an alicyclic group, or a heterocyclic group, and each may have a substituent when not representing a hydrogen atom, provided that at least one of R.sub.4, R.sub.5, R.sub.6, and R.sub.7 represents a group having a COOH group as a substituent).
    • PCT No.PCT / JP95 / 00336 Sec。 371日期1997年1月13日 102(e)日期1997年1月13日PCT提交1995年3月2日PCT公布。 公开号WO96 / 26985 PCT 日本1996年9月6日本发明涉及一种记录液,其特征在于包含水性介质和选自染料的至少一种单偶氮染料,其游离酸形式由通式{I}表示: (其中R 1,R 2和R 3各自独立地表示取代或未取代的碳原子数1〜9的烷基,碳原子数1〜9的烷氧基,卤素原子,氢原子,羟基,取代或未取代的 氨基甲酰基,取代或未取代的氨磺酰基,取代或未取代的氨基,硝基,磺酸酯基,磺酰基,COOH基或羧酸酯基; m表示0,1或 2; R 4,R 5,R 6和R 7各自独立地表示氢原子,碳原子数1〜18的烷基,碳原子数1〜18的烯基,芳基,芳烷基,脂环族基, 或杂环基,并且各自可以具有 当不表示氢原子时,取代基,只要R4,R5,R6和R7中的至少一个表示具有COOH基作为取代基的基团)。