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    • 3. 发明授权
    • Flameless atomizer
    • 无焰雾化器
    • US4202628A
    • 1980-05-13
    • US781938
    • 1977-03-28
    • Hideaki KoizumiKazuo Moriya
    • Hideaki KoizumiKazuo Moriya
    • G01N21/31G01N21/74G01J3/30
    • G01N21/74G01N2021/151
    • A cuvette used in a flameless atomizer is hollow and includes an opening at both ends and a hole in a radial direction substantially at its central portion. The cuvette is made of a conductive material and Joule-heated by currents flowing therethrough. The interior of the cuvette is divided substantially into three sections: a sample mount section at which a sample introduced through the hole of the cuvette is disposed; a light beam path section through which light incident from the opening at one end of the cuvette passes and goes out of the opening at the other end; and an absorption cell section at which the light beam path section intersects with atomic vapors generated from the sample disposed at the sample mount section. The electric resistance of the cuvette is made smaller at the sample mount section than at a portion near the absorption cell section. This allows the higher temperature of the portions near the absorption cell section than that of the sample mount section. Therefore, almost all of the atomic vapors in the cuvette exist at the absorption cell portion, and the application of a magnetic field to the absorption cell section allows a great improvement in analysis precision and sensitivity of the flameless atomizer for atomic absorption analysis using a Zeeman effect.
    • 在无焰雾化器中使用的比色杯是中空的,并且包括在两端的开口和在径向方向上的大致在其中心部分的孔。 试管由导电材料制成,并由流过其中的电流进行焦耳加热。 试管的内部基本上分为三个部分:样品安装部分,其中设置通过反应杯的孔引入的样品; 光束路径部分,通过所述光束路径部分从所述反应杯的一端处的所述开口入射的光在所述另一端通过并离开所述开口; 以及吸收单元部分,光束路径部分与从设置在样品安装部分处的样品产生的原子蒸汽相交。 在样品安装部分,反应杯的电阻比吸收单元部分附近的电阻小。 这允许吸收单元部分附近的部分的温度高于样品安装部分的温度。 因此,比色皿中的几乎所有的原子蒸汽都存在于吸收单元部分,并且向吸收单元部分施加磁场允许使用塞曼对无焰雾化器进行原子吸收分析的分析精度和灵敏度大大提高 影响。
    • 8. 发明授权
    • Mass spectrometer
    • 质谱仪
    • US06188065B1
    • 2001-02-13
    • US09260552
    • 1999-03-02
    • Yasuaki TakadaMinoru SakairiAtsumu HirabayashiHideaki Koizumi
    • Yasuaki TakadaMinoru SakairiAtsumu HirabayashiHideaki Koizumi
    • G01D5944
    • H01J49/145H01J49/0431H01J49/049H01J49/165H01J49/168
    • A mass spectrometer includes a sample supplier which supplies a sample solution, the sample solution including a solvent, ions, and a solute, the solute being a sample to be analyzed, an ion converter, disposed after the sample supplier, which converts the ions in the sample solution into gaseous ions, an ion source, disposed after the ion converter, which ionizes the sample in the sample solution, thereby producing sample ions, a mass analyzer which analyzes masses of the sample ions produced by the ion source, and an ion blocking electrode which prevents the gaseous ions produced by the ion converter from reaching the ion source, thereby preventing the mass analyzer from analyzing masses of the gaseous ions produced by the ion converter.
    • 质谱仪包括供样品溶液的样品供应商,包含溶剂的样品溶液,离子和溶质,作为待分析样品的溶质,设置在样品供应者之后的离子转化器,其将离子转化为 将样品溶液变成气态离子,离子源,设置在离子转换器之后,将样品溶液中的样品离子化,从而产生样品离子;分析质量分析器,其分析由离子源产生的样品离子的质量;以及离子 阻止由离子转换器产生的气体离子到达离子源的阻挡电极,从而防止质量分析器分析由离子转换器产生的气态离子的质量。