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    • 1. 发明授权
    • Barrier layer deposition using HDP-CVD
    • 使用HDP-CVD进行阻挡层沉积
    • US06399489B1
    • 2002-06-04
    • US09431411
    • 1999-11-01
    • Hichem M'SaadSeon Mee ChoDana Tribula
    • Hichem M'SaadSeon Mee ChoDana Tribula
    • C23C16/50C23C16/32H01L21/205H01L21/314H01L21/316H01L21/768H01L23/522H01L21/44
    • C23C16/325H01L21/314H01L21/3146Y10S438/931
    • A method of depositing a film, such as a barrier layer, on a substrate using a gaseous mixture including a hydrocarbon-containing gas and a silicon-containing gas. Suitable hydrocarbon-containing gases include alkanes such as methane (CH4), ethane (C2H6), butane (C3H8), propane (C4H10), etc. Suitable silicon-containing gases include silanes such as monosilane (SiH4). The method generally comprises providing a suitable gaseous mixture to the chamber, generating a plasma from the gaseous mixture, and depositing a film onto the substrate using the plasma. In a preferred embodiment, the film is deposited in a high-density plasma chemical vapor deposition (HDP-CVD) system. The gaseous mixture typically includes a silicon containing gas, such as an alkane, and a hydrocarbon containing gas, such as a silane. Embodiments of the method of the present invention can integrated stack structures having overall dielectric constant of about 4.0 or less. Such a structure may include a barrier layer having a dielectric constant of 4.5 or less.
    • 使用包含含烃气体和含硅气体的气体混合物在衬底上沉积诸如阻挡层的膜的方法。 合适的含烃气体包括烷烃如甲烷(CH4),乙烷(C2H6),丁烷(C3H8),丙烷(C​​4H10)等。合适的含硅气体包括硅烷如硅烷(SiH 4)。 该方法通常包括向腔室提供合适的气体混合物,从气体混合物产生等离子体,以及使用等离子体将膜沉积到衬底上。 在优选的实施方案中,膜以高密度等离子体化学气相沉积(HDP-CVD)系统沉积。 气态混合物通常包括含硅气体,例如烷烃,和含烃气体,例如硅烷。 本发明方法的实施方案可以具有总体介电常数为约4.0或更小的堆叠结构。 这种结构可以包括介电常数为4.5或更小的阻挡层。
    • 4. 发明授权
    • Method for improving barrier layer adhesion to HDP-FSG thin films
    • 改善与HDP-FSG薄膜的隔离层粘附性的方法
    • US06410457B1
    • 2002-06-25
    • US09569744
    • 2000-05-11
    • Hichem M'SaadDana TribulaManoj VellaikalFarhad MoghadamSameer Desai
    • Hichem M'SaadDana TribulaManoj VellaikalFarhad MoghadamSameer Desai
    • H01L2131
    • H01L21/02131C23C16/401H01L21/02211H01L21/02274H01L21/02304H01L21/02362H01L21/31629
    • A method of formation of a damascene FSG film with good adhesion to silicon nitride in an HDP-CVD system. Silane (SiH4), silicon tetrafluoride (SiF4), oxygen (O2) and argon (Ar) are used as the reactant gases. SiH4, SiF4, and O2 react to form the FSG. Ar is introduced to promote gas dissociation. All four gases are used for depositing most of the FSG film. SiH4 is not used during deposition of the interfacial part of the FSG film. The interfacial part of the FSG film refers either to the topmost portion, if silicon nitride is to be deposited on top of the FSG or the bottom portion if the FSG is to be deposited on top of silicon nitride. Using SiH4 with the SiF4 tends to mitigate the destructive effects of SiF4 throughout most of the deposition. By removing the SiH4 from the deposition of the interfacial part of the FSG film less hydrogen is incorporated into the film in the interfacial region and adhesion to overlying or underlying silicon nitride is improved.
    • 在HDP-CVD系统中形成对氮化硅具有良好粘附性的镶嵌FSG膜的方法。 使用硅烷(SiH 4),四氟化硅(SiF 4),氧(O 2)和氩(Ar)作为反应气体。 SiH4,SiF4和O2反应形成FSG。 引入Ar来促进气体分解。 所有四种气体都用于沉积大部分FSG膜。 在沉积FSG膜的界面部分期间不使用SiH4。 如果要将FSG沉积在氮化硅的顶部,则FSG膜的界面部分指的是最高部分,如果氮化硅沉积在FSG或底部的顶部。 SiF4与SiF4的共同作用倾向于减少SiF4在大部分沉积过程中的破坏作用。 通过从FSG膜的界面部分的沉积中除去SiH 4,在界面区域中较少的氢被引入到膜中,并且改善了覆盖或下面的氮化硅的粘合性。
    • 5. 发明授权
    • Apparatus for improving barrier layer adhesion to HDP-FSG thin films
    • 用于改善与HDP-FSG薄膜的屏障层粘附性的装置
    • US06803325B2
    • 2004-10-12
    • US10120713
    • 2002-04-10
    • Hichem M'SaadDana TribulaManoj VellaikalFarhad MoghadamSameer Desai
    • Hichem M'SaadDana TribulaManoj VellaikalFarhad MoghadamSameer Desai
    • H01L2131
    • H01L21/02131C23C16/401H01L21/02211H01L21/02274H01L21/02304H01L21/02362H01L21/31629
    • A method of formation of a damascene FSG film with good adhesion to silicon nitride in an HDP-CVD system. Silane (SiH4), silicon tetrafluoride (SiF4), oxygen (O2) and argon (Ar) are used as the reactant gases. SiH4, SiF4, and O2 react to form the FSG. Ar is introduced to promote gas dissociation. All four gases are used for depositing most of the FSG film. SiH4 is not used during deposition of the interfacial part of the FSG film. The interfacial part of the FSG film refers either to the topmost portion, if silicon nitride is to be deposited on top of the FSG or the bottom portion if the FSG is to be deposited on top of silicon nitride. Using SiH4 with the SiF4 tends to mitigate the destructive effects of SiF4 throughout most of the deposition. By removing the SiH4 from the deposition of the interfacial part of the FSG film less hydrogen is incorporated into the film in the interfacial region and adhesion to overlying or underlying silicon nitride is improved.
    • 在HDP-CVD系统中形成对氮化硅具有良好粘附性的镶嵌FSG膜的方法。 使用硅烷(SiH 4),四氟化硅(SiF 4),氧(O 2)和氩(Ar)作为反应气体。 SiH4,SiF4和O2反应形成FSG。 引入Ar来促进气体分解。 所有四种气体都用于沉积大部分FSG膜。 在沉积FSG膜的界面部分期间不使用SiH4。 如果要将FSG沉积在氮化硅的顶部,则FSG膜的界面部分指的是最高部分,如果氮化硅沉积在FSG或底部的顶部。 SiF4与SiF4的共同作用倾向于减少SiF4在大部分沉积过程中的破坏作用。 通过从FSG膜的界面部分的沉积中除去SiH 4,在界面区域中较少的氢被引入到膜中,并且改善了覆盖或下面的氮化硅的粘合性。