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1. 发明授权

US4956174A Compositions for coloring the skin based on indole derivatives 失效
标题翻译：基于吲哚衍生物着色皮肤的组合物
公开(公告)号：US4956174A
公开(公告)日：1990-09-11
申请号：US21931
申请日：1987-03-05
申请人： Gerard Lang , Herve Richard , Madeleine Leduc , Alex Junino
发明人： Gerard Lang , Herve Richard , Madeleine Leduc , Alex Junino
IPC分类号： A61K8/00 , A61K8/34 , A61K8/46 , A61K8/49 , A61K8/58 , A61K8/86 , A61K8/92 , A61Q1/02 , A61Q19/04
CPC分类号： A61Q19/04 , A61K8/492
摘要： Cosmetic composition designed to impart to the skin a coloring which is substantially similar to the pigmentation resulting from natural tanning, characterized in that it contains, in a cosmetically acceptable medium suitable for topical application, at least one compound of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom, a lower alkyl group or a residue --SiR.sub.9 R.sub.10 R.sub.11, R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ; R.sub.4 and R.sub.5 which may be identical or different, denote a hydrogen atom, a linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group R.sub.6 OSO.sub.2 --, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or an aralkyl group, or alternatively R.sub.4 and R.sub.5, with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group when at least one of the groups, R.sub.1, R.sub.2 or R.sub.3 is other than hydrogen or alternatively a thiocarbonyl group, a residue >P(O)OR.sub.6, a group >CR.sub.7 R.sub.8 or a methylene group, R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, R.sub.8 denoting a lower alkoxy group or a mono- or dialkylamino group and R.sub.9, R.sub.10 or R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 being other than hydrogen; and the corresponding salts with alkali metals, alkaline earth metals, ammonium or amines.
摘要翻译：化妆品组合物被设计成赋予皮肤一种基本上类似于由天然鞣制引起的色素沉着的着色，其特征在于其在适合局部应用的化妆品可接受的介质中包含至少一种下式的化合物： I），其中R 1表示氢原子，低级烷基或残基-SiR 9 R 10 R 11，R 2和R 3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或一组-COOSiR9R10R11; 可以相同或不同的R 4和R 5表示氢原子，直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基，基团R6OSO2-，基团-SiR9R10R11，基团-P（O）（OR6）2或芳烷基，或者R4和R5与它们所连接的氧原子形成任选含有羰基的环， R 1，R 2或R 3中的至少一个不是氢或硫代羰基，残基> P（O）OR 6，基团> CR 7 R 8或亚甲基，R 6表示氢原子或低级烷基，R7表示氢原子或低级烷基，R8表示低级烷氧基或单或二烷基氨基，R9，R10或R11可以相同或不同，表示直链或支链的低级烷基，至少一个的取代基R 1，R 2，R 3，R 4和R 5不是氢; 和与碱金属，碱土金属，铵或胺的相应的盐。

2. 发明授权

US4822375A Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds 失效
标题翻译：基于吲哚衍生物的角质纤维染色组合物和新化合物
公开(公告)号：US4822375A
公开(公告)日：1989-04-18
申请号：US21932
申请日：1987-03-05
申请人： Gerard Lang , Herve Richard , Madeleine Leduc , Alex Junino
发明人： Gerard Lang , Herve Richard , Madeleine Leduc , Alex Junino
IPC分类号： A61K8/00 , A61K8/34 , A61K8/37 , A61K8/41 , A61K8/49 , A61K8/92 , A61Q5/10 , C07D209/08 , C07D209/12 , C07D209/42 , C07D491/04 , C07D491/056 , C07F7/18 , C07F9/572 , C09B53/00 , C09B53/02 , C09B57/00 , C09B69/00 , D06P3/08 , A61K7/13 , C07D209/30 , C07F9/12
CPC分类号： C07D491/04 , A61K8/492 , A61Q5/10 , C07D209/08 , C07F7/1856 , C07F9/5728 , C09B69/007 , C09B69/008
摘要： Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds.Dyeing composition for keratinous fibres, and especially human hair, characterized in that it contains, in a cosmetically acceptable medium suitable for dyeing these fibres, at least one dye corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a lower alkyl group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group -COOSiR.sub.9 - R.sub.10 R.sub.11 ; and R.sub.5, which may be identical or different, denote at least one linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, the other group R.sub.4 or R.sub.5 being able to be a hydrogen atom, R.sub.4 and R.sub.5 are not simultaneously acetyl, or alternatively R.sub.4 and R.sub.5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a thiocarbonyl group, a group>P(O)OR.sub.6 or>CR.sub.7 R.sub.8 ;R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, and R.sub.8 denotes a lower alkoxy group or a mono- or dialkylamino group, R.sub.9, R.sub.10 and R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, and the cosmetically acceptable salts of alkali metals, alkaline earth metal metals, ammonia or amines.
摘要翻译：基于吲哚衍生物的角质纤维染色组合物和新化合物。用于角质纤维，特别是人类头发的染色组合物，其特征在于，其在适合于染色这些纤维的化妆品可接受的培养基中含有至少一种对应于下式的染料：其中R 1表示氢原子或低级烷基或-SiR 9 R 10 R 11基团; R2和R3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或基团-COOSiR9-R10R11; 和R 5可以相同或不同，表示至少一个直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， SiR 9 R 10 R 11，基团-P（O）（OR 6）2或基团R 6 OSO 2 - ，另一基团R 4或R 5可以是氢原子，R 4和R 5不同时为乙酰基，或者R4和R5连同形成任选地含有羰基，硫代羰基，基团> P（O）OR 6或> CR 7 R 8的环的氧原子。 R6表示氢原子或低级烷基，R7表示氢原子或低级烷基，R8表示低级烷氧基或一或二烷基氨基，R9，R10和R11可相同或不同，表示直链或支链的低级烷基，以及碱金属，碱土金属金属，氨或胺的美容上可接受的盐。

3. 发明授权

US5252323A s-Triazine compounds substituted by benzylidenecamphor substituents and cosmetic compositions containing the s-triazine compounds 失效
标题翻译：被亚苄基樟脑取代基取代的三嗪化合物和含有三嗪化合物的化妆品组合物
公开(公告)号：US5252323A
公开(公告)日：1993-10-12
申请号：US862356
申请日：1992-04-02
申请人： Herve Richard , Madeleine Leduc , Alex Junino
发明人： Herve Richard , Madeleine Leduc , Alex Junino
IPC分类号： A61K8/00 , A61K8/04 , A61K8/11 , A61K8/34 , A61K8/49 , A61K8/92 , A61Q1/00 , A61Q1/02 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/08 , A61Q5/10 , A61Q5/12 , A61Q7/00 , A61Q17/04 , A61Q19/00 , C07D251/52 , C07D251/70 , A61K7/42 , A61K7/44 , A61K7/48 , C07D251/54
CPC分类号： C07D251/70 , A61K8/4966 , A61Q17/04 , C07D251/52 , Y10S514/844 , Y10S514/845 , Y10S514/846 , Y10S514/847 , Y10S514/848
摘要： Compound of formula: ##STR1## in which R.sub.1 is of the formula: ##STR2## and R.sub.2 is a C.sub.8 -C.sub.20 alkoxy or mono- or dialkylamino or is of the formula: ##STR3## where n=0 or 1; R.sub.4 denotes H, OH or C.sub.1 -C.sub.6 alkoxy; R.sub.5 denoted H or COOR.sub.3 and R.sub.3 is a C.sub.4 -C.sub.20 alkyl.Application of these compounds for the protection of the skin and hair against ultraviolet radiation.
摘要翻译：（Ⅰ）化合物，其中R 1具有下式：其中R 2是C 8 -C 20烷氧基或一或二烷基氨基或具有下式：其中 n = 0或1; R4表示H，OH或C1-C6烷氧基; R5表示H或COOR3，R3表示C4〜C20烷基。这些化合物用于保护皮肤和头发免受紫外线辐射的应用。

4. 发明授权

US5236698A S-triazine derivatives carrying benzalmalonate substituents, and cosmetic UV screening compositions 失效
标题翻译：携带苯二甲酸替代物的S-TRIAZINE衍生物和化妆品紫外线筛选组合物
公开(公告)号：US5236698A
公开(公告)日：1993-08-17
申请号：US862378
申请日：1993-04-02
申请人： Herve Richard , Madeleine Leduc , Alex Junino
发明人： Herve Richard , Madeleine Leduc , Alex Junino
IPC分类号： A61K8/00 , A61K8/04 , A61K8/11 , A61K8/34 , A61K8/49 , A61K8/92 , A61Q1/00 , A61Q1/02 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/08 , A61Q5/10 , A61Q5/12 , A61Q7/00 , A61Q17/04 , A61Q19/00 , C07D251/50 , C07D251/52 , C07D251/70
CPC分类号： A61K8/4966 , A61Q17/04 , C07D251/52 , C07D251/70 , Y10S424/01 , Y10S424/05 , Y10S514/844 , Y10S514/845 , Y10S514/846 , Y10S514/847 , Y10S514/938 , Y10S514/944
摘要： The invention relates to a compound of formula: ##STR1## where R.sub.1 is of the formula: ##STR2## where R.sub.3 represents a linear or branched C.sub.1 -C.sub.20 alkyl; R.sub.2 is identical to R.sub.1 or is a halogen or a linear or branched C.sub.1 -C.sub.20 alkoxy or mono- or dialkylamino or is of the formulae (III) or (IV): ##STR3## where R.sub.5 is a linear or branched C.sub.1 -C.sub.20 alkyl and n=0 or 1;R.sub.4 denotes H, OH or C.sub.1 -C.sub.5 alkoxy; ##STR4## Application of these compounds to the protection of the skin and hair against ultraviolet radiation.
摘要翻译：本发明涉及下式的化合物：其中R 1具有下式：其中R 3表示直链或支链C 1 -C 20烷基; R 2与R 1相同或为卤素或直链或支链C 1 -C 20烷氧基或单 - 或二烷基氨基或具有式（III）或（IV）：其中R 5为直链或支链C 1 -C 20烷基和n = 0或1; R4表示H，OH或C1-C5烷氧基; （四）这些化合物应用于保护皮肤和毛发免受紫外线辐射。

5. 发明授权

US5906812A Silicone-containing derivatives of salicylic acid which have desquamating properties 失效
标题翻译：具有脱屑性能的含水杨酸的衍生物
公开(公告)号：US5906812A
公开(公告)日：1999-05-25
申请号：US134433
申请日：1998-08-14
申请人： Herve Richard , Madeleine LeDuc , Alain LaGrange
发明人： Herve Richard , Madeleine LeDuc , Alain LaGrange
IPC分类号： A61K8/55 , A61K8/58 , A61K8/72 , A61K8/89 , A61K8/891 , A61K31/00 , A61K31/695 , A61K31/80 , A61P17/00 , A61P29/00 , A61P31/04 , A61P43/00 , C07F7/08 , C07F7/21 , C08G77/38 , C08L83/05 , C08L83/08 , A61K7/00 , A61K7/44 , A61K31/60 , A61K31/74
CPC分类号： A61K8/585 , A61Q19/08 , C07F7/0812 , C07F7/0852 , C07F7/21 , C08G77/38 , Y10S514/944 , Y10S514/945
摘要： The invention relates to novel compounds of the organosiloxane and organosilane type, bearing at least one function derived from salicylic acid. These novel products have, in particular, desquamating and/or anti-aging properties and may be used in topical application.
摘要翻译：本发明涉及有机硅氧烷和有机硅烷型的新化合物，其具有至少一种衍生自水杨酸的功能。这些新颖的产品特别具有脱屑和/或抗老化特性，可用于局部应用。

6. 发明授权

US6027537A Use of silicon compounds to dye human keratin fibres; novel compounds and compositions containing them 失效
标题翻译：使用硅化合物染色人角蛋白纤维; 含有它们的新化合物和组合物
公开(公告)号：US6027537A
公开(公告)日：2000-02-22
申请号：US961261
申请日：1997-10-30
申请人： Madeleine Leduc , Herve Richard , Alain Lagrange
发明人： Madeleine Leduc , Herve Richard , Alain Lagrange
IPC分类号： A61K8/00 , A61K8/35 , A61K8/40 , A61K8/58 , A61K8/89 , A61K8/893 , A61K8/895 , A61K8/896 , A61K8/898 , A61Q5/06 , A61Q5/10 , C07F7/08 , C07F7/10 , C07F7/18 , C07F7/21 , C08G77/04 , C08G77/14 , C08G77/26 , C08L83/06 , C08L83/08 , A61K7/13
CPC分类号： C07F7/21 , A61K8/585 , A61K8/893 , A61K8/898 , A61Q5/065 , C07F7/0818 , C07F7/0854 , A61K2800/57 , Y10S8/01 , Y10S8/916
摘要： The use of linear or cyclic silicon compounds containing at least one chromophoric group of quinone or azo type as direct dyes in dye compositions intended for dyeing human keratin fibres and in particular the hair. The invention also relates to novel silicon compounds and dye compositions containing them, as well as to the corresponding direct dyeing process.
摘要翻译：含有醌或偶氮类型的至少一种发色基团的直链或环状硅化合物作为用于染色人角蛋白纤维，特别是毛发的染料组合物中的直接染料的使用。本发明还涉及含有它们的新型硅化合物和染料组合物以及相应的直接染色方法。

7. 发明授权

US5976558A Silicone-containing derivatives of salicylic acid which have desquamating properties 失效
公开(公告)号：US5976558A
公开(公告)日：1999-11-02
申请号：US4303
申请日：1998-01-08
申请人： Herve Richard , Madeleine LeDuc , Alain LaGrange
发明人： Herve Richard , Madeleine LeDuc , Alain LaGrange
IPC分类号： A61K8/55 , A61K8/58 , A61K8/72 , A61K8/89 , A61K8/891 , A61K31/00 , A61K31/695 , A61K31/80 , A61P17/00 , A61P29/00 , A61P31/04 , A61P43/00 , C07F7/08 , C07F7/21 , C08G77/38 , C08L83/05 , C08L83/08 , A61K7/00 , A61K7/44
CPC分类号： A61K8/585 , A61Q19/08 , C07F7/0812 , C07F7/0852 , C07F7/21 , C08G77/38 , Y10S514/944 , Y10S514/945
摘要： The invention relates to novel compounds of the organosiloxane and organosilane type, bearing at least one function derived from salicylic acid. These novel products have, in particular, desquamating and/or anti-aging properties and may be used in topical application.

8. 发明授权

US5714134A Photoprotective/cosmetic compositions comprising benzotriazole-substituted polyorganosiloxanes/polyorganosilanes 失效
标题翻译：包含苯并三唑取代的聚有机硅氧烷/聚有机硅烷的光保护/化妆品组合物
公开(公告)号：US5714134A
公开(公告)日：1998-02-03
申请号：US758300
申请日：1996-12-03
申请人： Herve Richard , Madeleine Leduc , Alain Lagrange
发明人： Herve Richard , Madeleine Leduc , Alain Lagrange
IPC分类号： A61K8/60 , A61K8/00 , A61K8/06 , A61K8/58 , A61K8/72 , A61K8/89 , A61K8/891 , A61K8/896 , A61K8/898 , A61Q5/00 , A61Q17/04 , A61Q19/00 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/14 , C08G77/22 , C08G77/388 , C08L83/06 , A61K7/42
CPC分类号： A61K8/898 , A61K8/585 , A61Q17/04 , C07F7/0812 , C07F7/0854 , C07F7/21 , C08G77/388 , A61K2800/57
摘要： Topically applicable sunscreen/cosmetic compositions well suited for enhanced photoprotection of human skin and/or hair against the damaging effects of UV-A and UV-B irradiation, particularly solar radiation, comprise a photoprotecting effective amount of a novel benzotriazole-substituted polyorganosiloxane/polyorganosilane having one of the formulae (1) to (3): ##STR1## wherein A is a monovalent benzotriazole radical which comprises an acrylate or acrylamide functional group, which is bonded directly to a silicon atom, and which has the formula (4): ##STR2##
摘要翻译：特别适用于对人类皮肤和/或头发进行增强光保护以防UV-A和UV-B照射特别是太阳辐射的破坏性影响的局部适用的防晒/美容组合物包含光保护有效量的新型苯并三唑取代的聚有机硅氧烷/聚有机硅烷具有式（1）至（3）中的一个：其中A是包含丙烯酸酯或丙烯酰胺官能团的一价苯并三唑基团，其中A 1（R'）3（3）其直接与硅原子键合，并且具有式（4）：（4）

9. 发明授权

US5004594A Benzylidenecamphor sulphonamides derived from amino acids and their application in cosmetics, particularly as sunscreens 失效
标题翻译：衍生自氨基酸的亚苄基樟脑磺酰胺及其在化妆品中的应用，特别是作为防晒剂
公开(公告)号：US5004594A
公开(公告)日：1991-04-02
申请号：US287054
申请日：1988-12-21
申请人： Herve Richard , Madeleine Leduc , Serge Forestier , Gerard Lang
发明人： Herve Richard , Madeleine Leduc , Serge Forestier , Gerard Lang
IPC分类号： A61K8/00 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/37 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/92 , A61K8/97 , A61K31/18 , A61Q1/00 , A61Q5/00 , A61Q17/04 , C07C309/25 , C07C311/00 , C07C311/02 , C07C311/13 , C07C311/15 , C07C311/19 , C07C323/58 , C07C323/62 , C07D317/50 , C07D317/54 , C09K3/00
CPC分类号： A61Q17/04 , A61K8/466 , C07C311/13 , C07C311/19 , C07D317/54 , C07C2102/42 , Y10S424/05 , Y10S514/844 , Y10S514/845 , Y10S514/846 , Y10S514/847 , Y10S514/937 , Y10S514/938 , Y10S514/944
摘要： Cosmetic screening composition containing a benzylidene camphor sulphonamide and its use for the protection of human skin against ultraviolet radiation.
摘要翻译：含有亚苄基樟脑磺酰胺的化妆品筛选组合物及其用于保护人体皮肤免受紫外线辐射的用途。

10. 发明授权

US6080880A Silicone-substituted cinnamamide/malonamide/malonate compounds and photoprotective compositions comprised thereof 失效
公开(公告)号：US6080880A
公开(公告)日：2000-06-27
申请号：US980307
申请日：1997-11-28
申请人： Herve Richard , Madeleine Leduc
发明人： Herve Richard , Madeleine Leduc
IPC分类号： A61K8/58 , A61Q5/02 , A61Q5/04 , A61Q5/08 , A61Q5/10 , A61Q17/04 , C07F7/08 , C07F7/21 , C08G77/38 , C08G77/388 , C07F7/10
CPC分类号： A61Q5/04 , A61K8/58 , A61Q17/04 , A61Q5/02 , A61Q5/08 , A61Q5/10 , C07F7/0852 , C07F7/0854 , C07F7/21 , C08G77/38 , C08G77/388
摘要： Novel silicone-substituted cinnamamide/malonamide/malonate compounds having the structural formulae (1) and (2): ##STR1## in which A is a radical of formula (3): ##STR2## are well suited for the photoprotection of human skin and/or hair against the damaging effects of UV-A and UV-B irradiation, particularly solar radiation, and are also useful for photoprotecting such UV-sensitive substrates as plastics.

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