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    • 2. 发明授权
    • Liquid developer for development of electrostatic images comprising
onium salt polymer and an anion
    • 用于开发包含鎓盐聚合物和阴离子的静电图像的液体显影剂
    • US4525446A
    • 1985-06-25
    • US563561
    • 1983-12-20
    • Herman J. UytterhoevenYvan K. GilliamsWalter F. De WinterAugust M. MarienNoel J. De Volder
    • Herman J. UytterhoevenYvan K. GilliamsWalter F. De WinterAugust M. MarienNoel J. De Volder
    • G03G9/10G03G9/08G03G9/12G03G9/13G03G9/135
    • G03G9/122G03G9/131G03G9/1355
    • A liquid developer composition for rendering visible electrostatically charged areas. The composition contains in an electrically insulating non-polar carrier liquid having a volume resistivity of at least 10.sup.9 ohm.cm and a dielectric constant less than 3, dispersed coloring matter acting as toner particles and at least one onium salt polymer including recurring units incorporating an onium group together with an anion. The anion has at least one of the following characteristics:(1) contains a negatively charged atom or group of atoms which is sterically embraced by at least two non-ionic substituents containing at least 4 C atoms;(2) contains a negatively charged atom which is sterically embraced by at least 4 atoms selected from the group consisting of oxygen and halogen;(3) contains a negatively charged atom or group of atoms the negative charge of which is delocalized over other atoms linked to said atom or group of atoms;(4) is a radical anion,whereby the onium salt polymer is adsorbed with a net positive charge on the toner particles. An illustrative onium salt polymer species is a copolymer of isobutyl methacrylate, stearyl methacrylate and dimethylaminoethyl methacrylate that has been quaternized with methyl iodide and of which the iodide anions have been replaced by tetraphenyl boride anions.
    • 一种用于形成可见的静电电荷区域的液体显影剂组合物。 该组合物含有体积电阻率为至少109欧姆·厘米且介电常数小于3的电绝缘非极性载体液体,作为调色剂颗粒的分散着色剂和至少一种鎓盐聚合物,其包括含有 鎓基和阴离子。 阴离子具有以下特征中的至少一个:(1)含有带负电荷的原子或原子团,其被包含至少4个C原子的至少两个非离子取代基空间包围; (2)含有空位包含至少4个选自氧和卤素的原子的带负电荷的原子; (3)包含负电荷的原子或原子组,其负电荷与连接到所述原子或原子团的其它原子离域; (4)是自由基阴离子,其中鎓盐聚合物被吸附在调色剂颗粒上的净正电荷。 一种说明性的鎓盐聚合物物质是甲基丙烯酸异丁酯,甲基丙烯酸硬脂酯和甲基丙烯酸二甲氨基乙酯的共聚物,其已用甲基碘季铵化,其中碘化物阴离子被四苯基硼化物阴离子代替。
    • 6. 发明授权
    • Liquid electrophoretic developer composition
    • 液体电泳显影剂组合物
    • US4663265A
    • 1987-05-05
    • US889383
    • 1986-07-25
    • Herman J. UytterhoevenAugust M. MarienWalter F. De Winter
    • Herman J. UytterhoevenAugust M. MarienWalter F. De Winter
    • G03G9/12G03G9/13
    • G03G9/133Y10T428/2998
    • A liquid electrophoretic developer composition for developing electrostatic latent images, wherein pigment particles for obtaining improved dispersion stability in association with at least two polymers are dispersed in an electrically insulating non-polar carrier liquid having a volume resistivity of at least 10.sup.9 ohm.cm and a dielectric constant less than 3, characterized in that the composition comprises at least one polymer (hereafter called "polymer A") which forms a coating on the pigment particles and has a poor solubility in said liquid as determined by Test A herein described, and at least one polymer (hereafter called "polymer B") being chemically linked to the pre-coated polymer A, said polymer B having a good solubility in said liquid as determined by Test B herein described.
    • 一种用于显影静电潜像的液体电泳显影剂组合物,其中用于获得与至少两种聚合物相关联的改善的分散稳定性的颜料颗粒分散在体积电阻率为至少109欧姆·厘米的电绝缘非极性载体液体中, 介电常数小于3,其特征在于组合物包含至少一种聚合物(以下称为“聚合物A”),其在颜料颗粒上形成涂层,并且在所述液体中的溶解度差,如本文所述的测试A所确定,并且在 至少一种聚合物(以下称为“聚合物B”)与预包被的聚合物A化学连接,所述聚合物B在所述液体中具有良好的溶解度,如本文所述的测试B所确定。
    • 7. 发明授权
    • Liquid developer for development of electrostatic images
    • 用于静电图像显影的液体显影剂
    • US4606989A
    • 1986-08-19
    • US776860
    • 1985-09-18
    • Herman J. UytterhoevenAugust M. MarienWalter F. De Winter
    • Herman J. UytterhoevenAugust M. MarienWalter F. De Winter
    • G03G9/12G03G9/13G03G9/135
    • G03G9/1355G03G9/131
    • A liquid developer composition that is suitable for rendering visible electrostatically charged areas which composition contains in an electrically insulating non-polar carrier liquid having a volume resistivity of at least 10.sup.9 ohm.cm and a dielectric constant less than 3, dispersed coloring matter acting as toner particles and at least one anionic polymer that includes recurring units incorporating an anionic group together with a non-polymeric counter cation, characterized in that the cation is a selected from the group consisting of:(1) a cationic group which is a protonated tertiary amine group,(2) a quaternary ammonium group, a phosphonium group or a sulphonium group, and(3) a cationic group containing at least one carbon chain residue comprising at least 6 carbon atoms,whereby the anionic polymer is adsorbed with a net negative charge on the toner particles.
    • 一种液体显影剂组合物,其适用于使可见的静电电荷区域,该组合物含有体积电阻率为至少109欧姆·厘米且介电常数小于3的电绝缘非极性载体液体,作为调色剂的分散着色剂 颗粒和至少一种阴离子聚合物,其包括与非聚合抗衡阳离子一起结合阴离子基团的重复单元,其特征在于阳离子选自:(1)阳离子基团,其为质子化叔胺 基团,(2)季铵基,鏻基或锍基,和(3)含有至少一个包含至少6个碳原子的碳链残基的阳离子基团,由此阴离子聚合物被吸附净负电荷 在调色剂颗粒上。