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1. 发明授权

US5804656A Compositions of the ABS type for processing by extrusion and deep drawing 失效
标题翻译：用于挤出和深冲加工的ABS类型的组合物
公开(公告)号：US5804656A
公开(公告)日：1998-09-08
申请号：US778845
申请日：1997-01-06
申请人： Herbert Eichenauer , Peter Kruger , Harry Staratschek , Edgar Leitz , Dieter Wittman , Karl-Erwin Piejko , Jurgen Ramthun
发明人： Herbert Eichenauer , Peter Kruger , Harry Staratschek , Edgar Leitz , Dieter Wittman , Karl-Erwin Piejko , Jurgen Ramthun
IPC分类号： B29C47/00 , B29C55/02 , B29L7/00 , C08F297/04 , C08L25/12 , C08L53/02 , C08L55/02 , C08L9/00
CPC分类号： C08L25/12 , C08L55/02
摘要： Compositions of the ABS type containing A) one or more graft rubbers of A.1) from 10 to 60 parts by weight of one or more monomers on A.2) from 40 to 90 parts by weight of one or more rubber backbones having glass transition temperatures
摘要翻译：含A）的组合物，A）一种或多种A.1的接枝橡胶）10至60重量份的A.2上的一种或多种单体）40至90份重量的一种或多种具有玻璃的橡胶主链转变温度<0℃，B）至少一种通过树脂形成单体的自由基聚合获得的无橡胶的热塑性树脂，其中橡胶主链A.2）的平均粒径（d50值）为0.20-0.35μm m和接枝橡胶A）通过使用包含有机氢过氧化物和有机还原剂的引发剂体系通过自由基乳液接枝聚合制备，以及其用于通过深冲制备模制品的用途。

2. 发明授权

US5708079A Thermoplastic ABS moulding compositions 失效
标题翻译：热塑性ABS模塑组合物
公开(公告)号：US5708079A
公开(公告)日：1998-01-13
申请号：US642913
申请日：1996-05-06
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Peter Kruger
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Peter Kruger
IPC分类号： C08L51/04 , C08F2/26 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02 , C08L101/00
CPC分类号： C08L55/02
摘要： Thermoplastic moulding compositions containing A) 5 to 95 parts by wt of at least one particle-shaped graft rubber polymer of the ABS type manufactured by emulsion polymerization, in which the graft rubber particles have such a structure detectable by transmission electron microscope photographs, in which the individual particles contain irregular cell-shaped inclusions of resin-forming polymer and the surface of the particles shows such an irregular toothed structure, that for every particle imaged 5 to 30 of such teeth are present, which are distinguished from an idealized round particle (with a diameter d) by a diameter d+d/x with x=3 to 15, B) 95 to 5 parts by wt of at least one particle-shaped graft rubber polymer of the ABS type manufactured by emulsion polymerization, in which the graft rubber particles have such a structure detectable by transmission electron microscope photographs, in which the individual particles do not have a pronounced inner structure as in A) and possess a round particle shape with completely tooth-free surface and optionally C) 0 to 300 parts by wt of at least one thermoplastic rubber-free resin.
摘要翻译：含有A）5〜95重量份的通过乳液聚合制造的ABS型的至少一种颗粒状接枝橡胶聚合物，其中接枝橡胶颗粒具有通过透射电子显微镜照片可检测的结构，其中单个颗粒含有不规则的形成树脂的聚合物的细胞形夹杂物，并且颗粒的表面显示出这种不规则的齿状结构，对于存在这种齿的5至30个的每个颗粒，其与理想化的圆形颗粒直径d）直径d + d / x，x = 3〜15，B）95〜5重量份的通过乳液聚合制造的ABS型的至少一种颗粒状接枝橡胶聚合物，其中接枝橡胶颗粒具有通过透射电子显微镜照片可检测的结构，其中单个颗粒不具有如A）中明显的内部结构，并具有具有完全无牙表面的圆形颗粒形状和任选的C）0至300重量份的至少一种不含热塑性橡胶的树脂。

3. 发明授权

US5420181A Composition of polycarbonate, ABS, a basic additive and a carboxylic and compound 失效
标题翻译：聚碳酸酯，ABS，碱性添加剂和羧酸和化合物的组成
公开(公告)号：US5420181A
公开(公告)日：1995-05-30
申请号：US320115
申请日：1994-10-07
申请人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08G64/06 , C08G64/00 , C08K5/00 , C08K5/09 , C08L55/00 , C08L55/02 , C08L69/00 , C08L101/00 , C08K5/092
CPC分类号： C08K5/0008 , C08L55/02 , C08L69/00
摘要： Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.
摘要翻译：含有A）ABS型树脂，B）芳香族聚碳酸酯树脂的热塑性成型组合物，C）具有若干羧基的化合物或其混合物和任选的D）另外的聚合物树脂，其特征在于具有至少一种基本上作用的添加剂的ABS树脂是作为组分A，组分C选自分子中具有至少两个羧基（-COOH）的分子量为150至260的化合物，并且基本上作用的添加剂在A中的羧基中的重量比为从5：1到1：1。

4. 发明授权

US5674939A ABS moulding compounds with novel morphology 失效
标题翻译： ABS模塑料具有新颖的形态
公开(公告)号：US5674939A
公开(公告)日：1997-10-07
申请号：US557359
申请日：1995-11-13
申请人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08L51/04 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02
CPC分类号： C08L55/02 , C08F279/04
摘要： Moulding compounds the ABS type consisting of at least one resin matrix and a particulate graft-rubber polymer distributed therein and produced by emulsion polymerisation, wherein at least 70% of the graft-rubber particles (number) exhibit a structure of the rubber phase which can be detected by photographs taken with the aid of a transmission electron microscope and in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles exhibits an irregularly jagged structure such that, for each particle illustrated, 5 to 30 of such jagged projections are present which differ from an idealised round particle (with a diameter d) by virtue of a diameter d+d/x with x=3 to 15, as well as a process for the manufacture of said moulding compounds.
摘要翻译：成型化合物由至少一种树脂基质和分散在其中的颗粒状接枝橡胶聚合物组成的ABS类型，通过乳液聚合制备，其中至少70％的接枝橡胶颗粒（数量）表现出橡胶相的结构，其可以通过借助透射电子显微镜拍摄的照片进行检测，其中各个颗粒含有不规则的树脂形成性聚合物的细胞夹杂物，并且颗粒的表面呈现不规则的锯齿状结构，使得对于所示的每个颗粒为5〜30 存在这样的锯齿形突起，其与理想化的圆形颗粒（直径d）不同，其直径d = + d / x，x = 3〜15，以及制造所述模塑料的方法。

5. 发明授权

US5605963A ABS polymer compositions having a uniform matt surface 失效
标题翻译： ABS聚合物组合物具有均匀的无光泽表面
公开(公告)号：US5605963A
公开(公告)日：1997-02-25
申请号：US383832
申请日：1995-02-06
申请人： Edgar Leitz , Herbert Eichenauer , Karl-Erwin Piejko , Dieter Wittmann , Ekkehard Frohberg
发明人： Edgar Leitz , Herbert Eichenauer , Karl-Erwin Piejko , Dieter Wittmann , Ekkehard Frohberg
IPC分类号： C08L9/00 , C08L21/00 , C08L55/00 , C08L55/02 , C08L51/04
CPC分类号： C08L55/02
摘要： ABS polymer compositions consisting ofA) 5 to 80 parts by weight of at least one ABS polymer prepared by mass polymerization or solution polymerization, having rubber particles with an average particle diameter of from 800 to 15,000 nm and a rubber content of from 1 to 20% by weight,B) 1 to 50 parts by weight of at least one ABS polymer prepared by emulsion polymerization, having an average particle diameter of from 50 to 500 nm and a rubber content of from 20 to 80% by weight,C) 0 to 70 parts by weight of at least one thermoplastic vinyl resin prepared by radical polymerization of at least two monomer components selected from styrene, .alpha.-methylstyrene, methyl methacrylate, acrylonitrile, N-phenylmaleimide andD) 0.5 to 10 parts by weight of at least one polybutadiene prepared by emulsion polymerization, having an average particle diameter d.sub.50 in the latex form of from 80 to 500 nm and a gel content of from 10 to 95% by weight.
摘要翻译： ABS聚合物组合物，由A）5-80重量份的至少一种通过大量聚合或溶液聚合制备的ABS聚合物，具有平均粒径为800至15,000nm的橡胶颗粒和橡胶含量为1至20 B）1〜50重量份的通过乳液聚合制备的至少一种ABS聚合物，平均粒径为50〜500nm，橡胶含量为20〜80重量％，C）0 至70重量份的至少一种通过自由基聚合至少两种选自苯乙烯，α-甲基苯乙烯，甲基丙烯酸甲酯，丙烯腈，N-苯基马来酰亚胺和D）的单体组分制备的热塑性乙烯基树脂，D）至少0.5至10重量份一种通过乳液聚合制备的聚丁二烯，其胶乳形式的平均粒径d50为80-500nm，凝胶含量为10-95重量％。

6. 发明授权

US5741853A ABS moulding compositions with improved properties 失效
标题翻译：具有改进性能的ABS模塑组合物
公开(公告)号：US5741853A
公开(公告)日：1998-04-21
申请号：US651454
申请日：1996-05-22
申请人： Herbert Eichenauer , Ulrich Jansen , Karl-Erwin Piejko , Edgar Leitz
发明人： Herbert Eichenauer , Ulrich Jansen , Karl-Erwin Piejko , Edgar Leitz
IPC分类号： C08L25/12 , C08F279/02 , C08F279/04 , C08L51/00 , C08L51/04 , C08L55/02
CPC分类号： C08L51/04 , C08F279/02 , C08F279/04 , C08L55/02
摘要： Thermoplastic moulding compositions of the ABS type of I) at least one graft copolymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, in the presence of at least two butadiene polymer latices of types (A) and (B), which each contain, copolymerized, 0 to 50 wt. % of a further vinyl monomer, and wherein the weight ratio of monomers used to butadiene polymers used is 25:75 to 70:30, and II) at least one copolymer of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, characterized in that the butadiene polymer latex (A) has a particle diameter d.sub.50 .ltoreq.320 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 30 to 100 nm, and a gel content.ltoreq.70 wt. % and the butadiene polymer latex (B) has a particle diameter d.sub.50 .gtoreq.370 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 50 to 500 nm and a gel content.gtoreq.70 wt. %.
摘要翻译： ABS型I型热塑性成型组合物）至少一种接枝共聚物，其可通过苯乙烯和丙烯腈的重量比90:10至50:50的乳液聚合获得，其中苯乙烯和/或丙烯腈可以完全或部分地被 α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺，在至少两种类型（A）和（B）的丁二烯聚合物胶乳的存在下，它们各自含有0至50wt。％的另外的乙烯基单体，并且其中使用的单体与丁二烯聚合物的重量比为25:75至70:30，和II）至少一种苯乙烯和丙烯腈的共聚物，其重量比为90:10至50:50 其中苯乙烯和/或丙烯腈可以被α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺完全或部分替代，其特征在于丁二烯聚合物胶乳（A）的粒径d50 <320nm，粒度分布（从整体粒度分布以d90-d10测量）为30至100nm，凝胶含量为70wt。％，丁二烯聚合物胶乳（B）的粒径d50≥370nm，粒度分布的宽度（以积分粒度分布测定为d90-d10）为50〜500nm，凝胶含量> / = 70wt。％。

7. 发明授权

US5696204A Thermoplastic moulding compositions of the ABS type 失效
标题翻译： ABS型热塑性成型组合物
公开(公告)号：US5696204A
公开(公告)日：1997-12-09
申请号：US609163
申请日：1996-02-26
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Heinrich Alberts
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Heinrich Alberts
IPC分类号： C08L33/20 , C08L33/18 , C08L51/04 , C08L55/00 , C08L55/02 , C08L69/00 , C08F279/00
CPC分类号： C08L55/02
摘要： Thermoplastic moulding compositions comprising A) 1 to 60 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by emulsion polymerisation, in which at least 50% of the graft rubber particles (number) have a structure detectable via transmission electron microscopy photographs in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles has an irregular jagged structure such that 5 to 30 of such peaks are present per depicted particle, which particles differ from an idealised round particle (having a diameter d) by a diameter d+d/x, where x=3 to 15, B) 40 to 99 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by solution or bulk polymerisation and which has the morphology which is characteristic of bulk types of ABS, and optionally C) 0 to 200 parts by weight of at least one thermoplastic, rubber-free resin.
摘要翻译：包含A）1至60重量份的至少一种由乳液聚合制备的至少一种ABS型颗粒接枝橡胶聚合物，其中至少50％的接枝橡胶颗粒（数量）具有可检测的结构透射电子显微镜照片，其中单个颗粒含有形成树脂的聚合物的不规则细胞夹杂物，并且颗粒表面具有不规则的锯齿状结构，使得每个所述颗粒存在5至30个这样的峰，该颗粒与理想化圆颗粒（直径d）直径d + d / x，其中x = 3至15，B）40至99重量份的由溶液或体积产生的ABS型的至少一种颗粒接枝橡胶聚合物聚合并且其具有ABS的主体类型特征的形态，并且任选地C）0至200重量份的至少一种热塑性橡胶树脂。

8. 发明授权

US06806318B2 ABS molding materials with enhanced working properties 有权
标题翻译： ABS成型材料具有增强的工作性能
公开(公告)号：US06806318B2
公开(公告)日：2004-10-19
申请号：US09975277
申请日：2001-10-10
申请人： Herbert Eichenauer , Peter Krüger , Edgar Leitz , Harry Staratschek
发明人： Herbert Eichenauer , Peter Krüger , Edgar Leitz , Harry Staratschek
IPC分类号： C08F25500
CPC分类号： C08L51/04 , C08L51/08 , C08L55/02 , C08L2666/04
摘要： Thermoplastic molding composition characterized in that the polymer proportion soluble in dichloromethane has a c50 value of acrylonitrile of ≧28 wt. % and a chemical distribution (c90−c10 value) of the acrylonitrile of ≧5 wt. % is disclosed. The composition is characterized by its improved processability by extrusion and thermoforming.
摘要翻译：热塑性模塑组合物的特征在于可溶于二氯甲烷的聚合物比例具有≥28重量％的丙烯腈的c50值。％和丙烯腈的化学分布（c90-c10值）> = 5wt。％披露。该组合物的特征在于其通过挤出和热成型提高了加工性能。

9. 发明授权

US5104935A Polymer mixture 失效
标题翻译：聚合物混合物
公开(公告)号：US5104935A
公开(公告)日：1992-04-14
申请号：US447300
申请日：1989-12-06
申请人： Edgar Leitz , Karl-Erwin Piejko , Christian Lindner , Karl-Heinz Ott , Hans-Eberhard Braese
发明人： Edgar Leitz , Karl-Erwin Piejko , Christian Lindner , Karl-Heinz Ott , Hans-Eberhard Braese
IPC分类号： C08L25/06 , C08L33/00 , C08L33/04 , C08L33/06 , C08L33/08 , C08L51/00 , C08L51/04 , C08L51/06 , C08L67/04
CPC分类号： C08L33/08 , C08L51/04 , C08L51/003 , C08L67/04
摘要： Polymer mixtures ofa. 10 to 60 parts by weight of a graft polymer,b. 10 to 50 parts by weight of a partially cross-linked, rubber like copolymer of from 5 to 40% by weight of acrylonitrile, styrene, alkyl methacrylate or mixtures thereof and from 95 to 60% by weight of alkyl acrylate having a gel content of from 20 to 99% by weight,c. 5 to 40 parts by weight of an uncross-linked polymer of styrenes, .alpha.-methyl styrenes, acrylonitrile, methacrylonitrile, esters of acrylic acid or methacrylic acid, vinyl C.sub.1 to C.sub.4 carboxylic acids or mixtures of these monomers having Staudinger Indices (.eta.) (determined in dimethyl formamide at 23.degree. C.) of from 0.3 to 1.5 dl/g andd. 1 to 45 parts by weight of a polymer of a cyclic aliphatic ester or of an aliphatic cyclic ester and an aliphatic cyclic carbonate.
摘要翻译：聚合物混合物 10〜60重量份的接枝聚合物，b。 10至50重量份的5-40重量％的丙烯腈，苯乙烯，甲基丙烯酸烷基酯或其混合物的部分交联的橡胶状共聚物和95至60重量％的具有凝胶含量的丙烯酸烷基酯 20至99重量％，c。 5至40重量份苯乙烯，α-甲基苯乙烯，丙烯腈，甲基丙烯腈，丙烯酸或甲基丙烯酸的酯，乙烯基C1至C4羧酸或具有Staudinger指数（eta）的这些单体的混合物的未交联聚合物在23℃的二甲基甲酰胺中测定）为0.3〜1.5dl / g，d。 1至45重量份的环状脂族酯或脂族环酯和脂族环状碳酸酯的聚合物。

10. 发明申请

US20060116472A1 Compositions comprising graft polymer for extrusion processing 审中-公开
标题翻译：包含用于挤出加工的接枝聚合物的组合物
公开(公告)号：US20060116472A1
公开(公告)日：2006-06-01
申请号：US11128711
申请日：2005-05-13
申请人： Harry Staratschek , Hertber Eichenauer , Edgar Leitz
发明人： Harry Staratschek , Hertber Eichenauer , Edgar Leitz
IPC分类号： C08L51/00
CPC分类号： C08L55/02 , C08F279/02 , C08F279/04 , C08K3/22 , C08L23/30 , C08L25/00 , C08L25/12 , C08L31/00 , C08L33/00 , C08L51/00 , C08L51/04 , C08L2205/03 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to molding compositions comprising graft polymer and featuring very good processability via extrusion without the occurrence of certain surface defects.
摘要翻译：本发明涉及包含接枝聚合物的成型组合物，并且通过挤出而具有非常好的可加工性，而不会发生某些表面缺陷。

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