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1. 发明授权

US06806318B2 ABS molding materials with enhanced working properties 有权
标题翻译： ABS成型材料具有增强的工作性能
公开(公告)号：US06806318B2
公开(公告)日：2004-10-19
申请号：US09975277
申请日：2001-10-10
申请人： Herbert Eichenauer , Peter Krüger , Edgar Leitz , Harry Staratschek
发明人： Herbert Eichenauer , Peter Krüger , Edgar Leitz , Harry Staratschek
IPC分类号： C08F25500
CPC分类号： C08L51/04 , C08L51/08 , C08L55/02 , C08L2666/04
摘要： Thermoplastic molding composition characterized in that the polymer proportion soluble in dichloromethane has a c50 value of acrylonitrile of ≧28 wt. % and a chemical distribution (c90−c10 value) of the acrylonitrile of ≧5 wt. % is disclosed. The composition is characterized by its improved processability by extrusion and thermoforming.
摘要翻译：热塑性模塑组合物的特征在于可溶于二氯甲烷的聚合物比例具有≥28重量％的丙烯腈的c50值。％和丙烯腈的化学分布（c90-c10值）> = 5wt。％披露。该组合物的特征在于其通过挤出和热成型提高了加工性能。

2. 发明授权

US5804656A Compositions of the ABS type for processing by extrusion and deep drawing 失效
标题翻译：用于挤出和深冲加工的ABS类型的组合物
公开(公告)号：US5804656A
公开(公告)日：1998-09-08
申请号：US778845
申请日：1997-01-06
申请人： Herbert Eichenauer , Peter Kruger , Harry Staratschek , Edgar Leitz , Dieter Wittman , Karl-Erwin Piejko , Jurgen Ramthun
发明人： Herbert Eichenauer , Peter Kruger , Harry Staratschek , Edgar Leitz , Dieter Wittman , Karl-Erwin Piejko , Jurgen Ramthun
IPC分类号： B29C47/00 , B29C55/02 , B29L7/00 , C08F297/04 , C08L25/12 , C08L53/02 , C08L55/02 , C08L9/00
CPC分类号： C08L25/12 , C08L55/02
摘要： Compositions of the ABS type containing A) one or more graft rubbers of A.1) from 10 to 60 parts by weight of one or more monomers on A.2) from 40 to 90 parts by weight of one or more rubber backbones having glass transition temperatures
摘要翻译：含A）的组合物，A）一种或多种A.1的接枝橡胶）10至60重量份的A.2上的一种或多种单体）40至90份重量的一种或多种具有玻璃的橡胶主链转变温度<0℃，B）至少一种通过树脂形成单体的自由基聚合获得的无橡胶的热塑性树脂，其中橡胶主链A.2）的平均粒径（d50值）为0.20-0.35μm m和接枝橡胶A）通过使用包含有机氢过氧化物和有机还原剂的引发剂体系通过自由基乳液接枝聚合制备，以及其用于通过深冲制备模制品的用途。

3. 发明授权

US06297307B1 ABS moulding compositions having improved odor characteristics 失效
标题翻译：具有改善的气味特征的ABS模塑组合物
公开(公告)号：US06297307B1
公开(公告)日：2001-10-02
申请号：US08987567
申请日：1997-12-11
申请人： Herbert Eichenauer , Harry Staratschek
发明人： Herbert Eichenauer , Harry Staratschek
IPC分类号： C08K318
CPC分类号： C08K3/22 , C08K5/1515 , C08K2003/222 , C08K2003/2296 , C08L55/02
摘要： Thermoplastic moulding compositions prepared from an ABS polymer and 0.05 to 5 wt. % (relative to ABS polymer) of a combination of zinc oxide and/or magnesium oxide and at least one compound containing epoxy groups.
摘要翻译：由ABS聚合物制备的热塑性模塑组合物和0.05至5wt。氧化锌和/或氧化镁和至少一种含环氧基的化合物的组合的％（相对于ABS聚合物）。

4. 发明授权

US5420181A Composition of polycarbonate, ABS, a basic additive and a carboxylic and compound 失效
标题翻译：聚碳酸酯，ABS，碱性添加剂和羧酸和化合物的组成
公开(公告)号：US5420181A
公开(公告)日：1995-05-30
申请号：US320115
申请日：1994-10-07
申请人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Karl-Heinz Ott , Alfred Pischtschan , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08G64/06 , C08G64/00 , C08K5/00 , C08K5/09 , C08L55/00 , C08L55/02 , C08L69/00 , C08L101/00 , C08K5/092
CPC分类号： C08K5/0008 , C08L55/02 , C08L69/00
摘要： Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.
摘要翻译：含有A）ABS型树脂，B）芳香族聚碳酸酯树脂的热塑性成型组合物，C）具有若干羧基的化合物或其混合物和任选的D）另外的聚合物树脂，其特征在于具有至少一种基本上作用的添加剂的ABS树脂是作为组分A，组分C选自分子中具有至少两个羧基（-COOH）的分子量为150至260的化合物，并且基本上作用的添加剂在A中的羧基中的重量比为从5：1到1：1。

5. 发明授权

US4965300A Sequential copolymers based on cyclic carbonates and esters 失效
标题翻译：基于环状碳酸酯和酯的顺序共聚物
公开(公告)号：US4965300A
公开(公告)日：1990-10-23
申请号：US443041
申请日：1989-11-27
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott
IPC分类号： C08G63/64 , C08G64/00 , C08G64/18
CPC分类号： C08G64/18
摘要： Polymers having a sequential structure of the following formula--A--X--B].sub.r (I)with r=1 to 20, in which --A-- is a polymer of a cyclic carbonate, --B-- is a polymer of a lactone and --X-- is a link, with a decreasing concentration of residues of the cyclic carbonate in the --B-- direction and a decreasing concentration of residues of the lactone in the --A-- direction, and the use of the these products as molding compositions.
摘要翻译：具有以下式的顺序结构的聚合物-AXB] r（I），其中r = 1至20，其中-A-是环状碳酸酯的聚合物，-B-是内酯的聚合物，-X-是一个环节，环状碳酸酯在-B-方向的残留浓度降低，内酯残留在-A-方向上的浓度降低，以及这些产物用作模塑组合物。

6. 发明授权

US4960822A Thermoplastic moulding compounds with good processing properties and great toughness 失效
标题翻译：热塑性成型料具有良好的加工性能和较好的韧性
公开(公告)号：US4960822A
公开(公告)日：1990-10-02
申请号：US319275
申请日：1989-03-06
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott , Alfred Pischtschan
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott , Alfred Pischtschan
IPC分类号： C08L25/04 , C08L7/00 , C08L25/12 , C08L33/00 , C08L33/04 , C08L51/04 , C08L55/00 , C08L55/02 , C08L67/00 , C08L67/04 , C08L69/00
CPC分类号： C08L25/12 , C08L51/04 , C08L69/005 , C08L69/00
摘要： Thermoplastic moulding compounds containing(A) from 5 to 90 parts by weight of one or more thermoplastic polymers,(B) from 5 to 90 parts by weight of one or more graft polymers and(C) from 0.25 to 40 parts by weight of a copolymer having a sequential structure corresponding to the idealized formula (I)(A-X-B).sub.n (I)whereinA=a polymer of a cyclic carbonate,B=a polymer of another cyclic ester andX=a middle member containing both partial structures of A and B.
摘要翻译：含有（A）5至90重量份的一种或多种热塑性聚合物的热塑性模塑料，（B）5至90重量份的一种或多种接枝聚合物和（C）0.25至40重量份的共聚物，其具有对应于理想化的式（I）（AXB）n（I）的顺序结构，其中A =环状碳酸酯的聚合物，B =另一种环状酯的聚合物，X =含有两种部分结构的中间构件和B.

7. 发明授权

US4908416A Mixtures of aromatic polycarbonates and/or aromatic polyesters with special copolymers 失效
标题翻译：具有特殊共聚物的芳族聚碳酸酯和/或芳族聚酯的混合物
公开(公告)号：US4908416A
公开(公告)日：1990-03-13
申请号：US318975
申请日：1989-03-06
申请人： Edgar Leitz , Herbert Eichenauer , Karl-Heinz Ott
发明人： Edgar Leitz , Herbert Eichenauer , Karl-Heinz Ott
IPC分类号： C08L67/02 , C08L67/00 , C08L69/00
CPC分类号： C08L69/00 , C08L67/00 , C08L69/005
摘要： The invention relates to mixtures containing1. thermoplastic, aromatic polycarbonates and/or thermoplastic, aromatic polyesters and2. copolymers corresponding to formula (Ia)--A--X--.sub.r (Ia) and, optionally, stabilizers, pigments, mold release agents, flameproofing agents and/or antistatic agents. The invention also relates to a process for the production of the mixtures.
摘要翻译：本发明涉及含有热塑性，芳族聚碳酸酯和/或热塑性芳族聚酯的共混物和2.对应于式（Ia）+ TI，-AXr（Ia）和任选的稳定剂，颜料，脱模剂，隔爆剂药剂和/或抗静电剂。本发明还涉及制备混合物的方法。

8. 发明授权

US06639000B2 ABS molding compositions having improved processability 失效
标题翻译： ABS成型组合物具有改善的加工性能
公开(公告)号：US06639000B2
公开(公告)日：2003-10-28
申请号：US09955890
申请日：2001-09-18
申请人： Wolfgang Siebourg , Edgar Leitz , Herbert Eichenauer
发明人： Wolfgang Siebourg , Edgar Leitz , Herbert Eichenauer
IPC分类号： C08K520
CPC分类号： C08L25/02 , C08F285/00 , C08K5/103 , C08K5/20 , C08L51/04 , C08L55/02 , C08L2666/24 , C08L2666/14 , C08L2666/04
摘要： An additive mixture containing a dibenzoate and either or both of a compound containing at least one structural unit and a compound containing at least one structural unit is disclosed. The additive combination enhances the processability of a thermoplastic molding composition that contains a (co)polymer of styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride and N-substituted maleimide and a graft copolymer.
摘要翻译：公开了含有二苯甲酸酯和含有至少一个结构单元的化合物和包含至少一种结构单元的化合物中的一种或两种的添加剂混合物。添加剂组合增强了含有苯乙烯，甲基丙烯酸甲酯，丙烯腈，甲基丙烯腈，马来酸酐和N-取代的马来酰亚胺的共聚合物和接枝共聚物的热塑性模塑组合物的加工性能。

9. 发明授权

US5708079A Thermoplastic ABS moulding compositions 失效
标题翻译：热塑性ABS模塑组合物
公开(公告)号：US5708079A
公开(公告)日：1998-01-13
申请号：US642913
申请日：1996-05-06
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Peter Kruger
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Erwin Piejko , Peter Kruger
IPC分类号： C08L51/04 , C08F2/26 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02 , C08L101/00
CPC分类号： C08L55/02
摘要： Thermoplastic moulding compositions containing A) 5 to 95 parts by wt of at least one particle-shaped graft rubber polymer of the ABS type manufactured by emulsion polymerization, in which the graft rubber particles have such a structure detectable by transmission electron microscope photographs, in which the individual particles contain irregular cell-shaped inclusions of resin-forming polymer and the surface of the particles shows such an irregular toothed structure, that for every particle imaged 5 to 30 of such teeth are present, which are distinguished from an idealized round particle (with a diameter d) by a diameter d+d/x with x=3 to 15, B) 95 to 5 parts by wt of at least one particle-shaped graft rubber polymer of the ABS type manufactured by emulsion polymerization, in which the graft rubber particles have such a structure detectable by transmission electron microscope photographs, in which the individual particles do not have a pronounced inner structure as in A) and possess a round particle shape with completely tooth-free surface and optionally C) 0 to 300 parts by wt of at least one thermoplastic rubber-free resin.
摘要翻译：含有A）5〜95重量份的通过乳液聚合制造的ABS型的至少一种颗粒状接枝橡胶聚合物，其中接枝橡胶颗粒具有通过透射电子显微镜照片可检测的结构，其中单个颗粒含有不规则的形成树脂的聚合物的细胞形夹杂物，并且颗粒的表面显示出这种不规则的齿状结构，对于存在这种齿的5至30个的每个颗粒，其与理想化的圆形颗粒直径d）直径d + d / x，x = 3〜15，B）95〜5重量份的通过乳液聚合制造的ABS型的至少一种颗粒状接枝橡胶聚合物，其中接枝橡胶颗粒具有通过透射电子显微镜照片可检测的结构，其中单个颗粒不具有如A）中明显的内部结构，并具有具有完全无牙表面的圆形颗粒形状和任选的C）0至300重量份的至少一种不含热塑性橡胶的树脂。

10. 发明授权

US5605963A ABS polymer compositions having a uniform matt surface 失效
标题翻译： ABS聚合物组合物具有均匀的无光泽表面
公开(公告)号：US5605963A
公开(公告)日：1997-02-25
申请号：US383832
申请日：1995-02-06
申请人： Edgar Leitz , Herbert Eichenauer , Karl-Erwin Piejko , Dieter Wittmann , Ekkehard Frohberg
发明人： Edgar Leitz , Herbert Eichenauer , Karl-Erwin Piejko , Dieter Wittmann , Ekkehard Frohberg
IPC分类号： C08L9/00 , C08L21/00 , C08L55/00 , C08L55/02 , C08L51/04
CPC分类号： C08L55/02
摘要： ABS polymer compositions consisting ofA) 5 to 80 parts by weight of at least one ABS polymer prepared by mass polymerization or solution polymerization, having rubber particles with an average particle diameter of from 800 to 15,000 nm and a rubber content of from 1 to 20% by weight,B) 1 to 50 parts by weight of at least one ABS polymer prepared by emulsion polymerization, having an average particle diameter of from 50 to 500 nm and a rubber content of from 20 to 80% by weight,C) 0 to 70 parts by weight of at least one thermoplastic vinyl resin prepared by radical polymerization of at least two monomer components selected from styrene, .alpha.-methylstyrene, methyl methacrylate, acrylonitrile, N-phenylmaleimide andD) 0.5 to 10 parts by weight of at least one polybutadiene prepared by emulsion polymerization, having an average particle diameter d.sub.50 in the latex form of from 80 to 500 nm and a gel content of from 10 to 95% by weight.
摘要翻译： ABS聚合物组合物，由A）5-80重量份的至少一种通过大量聚合或溶液聚合制备的ABS聚合物，具有平均粒径为800至15,000nm的橡胶颗粒和橡胶含量为1至20 B）1〜50重量份的通过乳液聚合制备的至少一种ABS聚合物，平均粒径为50〜500nm，橡胶含量为20〜80重量％，C）0 至70重量份的至少一种通过自由基聚合至少两种选自苯乙烯，α-甲基苯乙烯，甲基丙烯酸甲酯，丙烯腈，N-苯基马来酰亚胺和D）的单体组分制备的热塑性乙烯基树脂，D）至少0.5至10重量份一种通过乳液聚合制备的聚丁二烯，其胶乳形式的平均粒径d50为80-500nm，凝胶含量为10-95重量％。

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