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    • 1. 发明授权
    • Thermostable bismuth vanadate/molybdate pigments
    • 耐热稳定的钒酸铋/钼酸盐颜料
    • US4851049A
    • 1989-07-25
    • US130652
    • 1987-12-09
    • Henning WienandWerner OstertagChristoph SchwidetzkyHelmut Knittel
    • Henning WienandWerner OstertagChristoph SchwidetzkyHelmut Knittel
    • C08K9/04C09C1/00C09C3/00C09D7/12
    • C09C1/0006C09C3/006C01P2004/84
    • Thermostable bismuth vanadate/molybdate pigments are prepared by precipitating onto a pigment, obtained by calcination, of the formulaBi VO.sub.4 .cndot.Bi.sub.2 Mo O.sub.6where n is 0.2-2.5, in aqueous suspension at 70.degree.-100.degree. C. within the pH range from 4 to 9.5 a first SiO.sub.2 -containing layer using an alkali metal silicate solution of a magnesium hexafluorosilicate solution, maintaining the suspension at 70.degree.-100.degree. C. for not less than 1 hour, producing a thick coating on the precoated pigment by adding further alkali metal silicate solution, magnesium hexafluorosilicate solution or a mixture of the two within the pH range from 4 to 9.5, and finally depositing wax on the SiO.sub.2 -containing layer by means of a waxing emulsion/dispersion, the products showing, compared with the starting pigment, an appreciably improved thermal stability in plastics.
    • 热稳定的钒酸铋/钼酸盐颜料通过在pH为4范围内,在70℃-100℃的水悬浮液中沉淀到通过煅烧获得的式Bi VO 4 .Bi 2 MoO 6(其中n为0.2-2.5)的颜料上制备 使用六氟硅酸镁溶液的碱金属硅酸盐溶液至9.5的第一含SiO 2层,将悬浮液保持在70℃-100℃下不少于1小时,通过加入另外的碱在预涂颜料上产生厚的涂层 金属硅酸盐溶液,六氟硅酸镁溶液或两者的混合物在pH范围为4至9.5之间,最后通过打蜡乳液/分散体将蜡沉积在含SiO 2的层上,与起始颜料相比,产物显示出来 ,塑料的热稳定性明显提高。