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    • 2. 发明授权
    • Inorganic particles comprising an organic coating that can be hydrophilically/hydrophobically temperature controlled
    • 包含能够亲水/疏水控制温度的有机涂层的无机颗粒
    • US08434623B2
    • 2013-05-07
    • US13054702
    • 2009-07-17
    • Imme DomkeAlexej MichailovskiNorbert MrongaHartmut HibstJuergen TropschSusanne Stutz
    • Imme DomkeAlexej MichailovskiNorbert MrongaHartmut HibstJuergen TropschSusanne Stutz
    • B03D3/00
    • H01F1/44B03C1/015H01F1/0054
    • The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the following steps: (A) contacting of the mixture comprising the at least one first material and at least one second material with at least one selective hydrophobicizing agent in the presence of a suspension medium so that an adduct is formed from the at least one hydrophobicizing agent and the at least one first material but not with the at least one second material, (B) contacting of the adduct from step (A) with at least one magnetic particle which is functionalized on the surface with at least one polymeric compound having a transition temperature LCST (lower critical solution temperature) at a temperature at which the polymeric compound has hydrophobic character so that the adduct from step (A) and the at least one functionalized magnetic particle agglomerate, (C) if appropriate addition of further suspension medium to the mixture obtained in step (B), (D) separation of the agglomerate present in the suspension from step (B) or (C) from the suspension by application of a magnetic field, (E) dissociation of the agglomerate separated off in step (D) by setting of a temperature at which the polymeric compound has hydrophilic character in order to obtain the at least one first material.
    • 本发明涉及从包含该至少一种第一材料和至少一种第二材料的混合物中分离出至少一种第一材料的方法,其包括以下步骤:(A)使包含至少一种第一材料和/ 材料和至少一种第二材料与至少一种选择性疏水剂在悬浮介质的存在下进行,使得加合物由至少一种疏水剂和至少一种第一材料形成,但不与至少一种第二材料形成 ,(B)将来自步骤(A)的加合物与至少一种在表面上官能化的磁性颗粒与至少一种具有转变温度LCST(较低临界溶解温度)的聚合化合物在聚合物 具有疏水性,使得步骤(A)和至少一种官能化磁性颗粒附聚物的加合物,(C)如果适当添加 的另外的悬浮介质加入到步骤(B)中获得的混合物中,(D)通过施加磁场从悬浮液中分离存在于步骤(B)或(C)的悬浮液中的附聚物,(E) 在步骤(D)中通过设定聚合物具有亲水特性的温度来分离聚集体,以获得至少一种第一材料。
    • 4. 发明申请
    • SELECTIVE MATERIALS SEPARATION USING MODIFIED MAGNETIC PARTICLES
    • 使用改性磁性颗粒的选择性材料分离
    • US20110120954A1
    • 2011-05-26
    • US13054713
    • 2009-07-15
    • Imme DomkeAlexej MichailovskiNorbert MrongaHartmut HibstJuergen TropschSusanne Stutz
    • Imme DomkeAlexej MichailovskiNorbert MrongaHartmut HibstJuergen TropschSusanne Stutz
    • B03C1/01B01D39/00
    • H01F1/44B03C1/015B82Y25/00H01F1/0045
    • The present invention relates to a process of the invention for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) Contacting of at least one magnetic particle and at least one bifunctional molecule or an adduct of the two with the mixture comprising the at least one first material and at least one second material so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first material, (B) suspension of the adduct obtained in step (A) in a suitable suspension medium, (C) separation of the adduct present in the suspension from step (B) from the suspension by application of a magnetic field, (D) if appropriate, dissociation of the adduct separated off in step (C) in order to obtain the at least one first material. a corresponding adduct and the use of such an adduct for the separation of mixtures of materials.
    • 本发明涉及一种本发明的方法,用于从包含该至少一种第一材料和至少一种第二材料的混合物中分离至少一种第一材料,其包括以下步骤:(A)接触至少一种磁性颗粒和 至少一种双功能分子或两者的加合物与混合物包含至少一种第一材料和至少一种第二材料,使得加合物由至少一个磁性颗粒形成,通式(I)的双官能化合物 )和所述至少一种第一材料,(B)步骤(A)中获得的加合物的悬浮液在合适的悬浮介质中,(C)通过施用将来自步骤(B)的悬浮液中存在的加合物与悬浮液 (D)如果合适,在步骤(C)中分离的加合物的解离以获得至少一种第一材料。 相应的加合物和这种加合物用于分离材料混合物的用途。
    • 5. 发明申请
    • MAGNETIC SEPARATION OF SUBSTANCES ON THE BASIS OF THE DIFFERENT SURFACE CHARGES THEREOF
    • 基于不同表面电荷的物质的磁性分离
    • US20100307982A1
    • 2010-12-09
    • US12743655
    • 2008-11-17
    • Imme DomkeAlexej MichailovskiNorbert MrongaHartmut Hibst
    • Imme DomkeAlexej MichailovskiNorbert MrongaHartmut Hibst
    • B03C1/023
    • B03C1/015B03C1/32B03C2201/18
    • The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) production of a suspension of the mixture comprising at least one first material and at least one second material and at least one magnetic particle in a suitable suspension medium, (B) setting of the pH of the suspension obtained in step (A) to a value at which the at least one first material and the at least one magnetic particle bear opposite surface charges so that these agglomerate, (C) separation of the agglomerate obtained in step (B) from the suspension by application of a magnetic field and (D) dissociation of the agglomerate separated off in step (C) by setting of the pH to a value at which the at least one first material and the at least one magnetic particle bear the same surface charges in order to obtain the at least one first material.
    • 本发明涉及从包含这种至少一种第一材料和至少一种第二材料的混合物中分离出至少一种第一材料的方法,其包括以下步骤:(A)制备混合物的悬浮液,其包含至少一种 第一材料和至少一种第二材料和至少一种在适合的悬浮介质中的磁性颗粒,(B)将步骤(A)中获得的悬浮液的pH设定为至少一种第一材料和第 至少一个磁性颗粒承受相反的表面电荷,使得这些附聚物,(C)通过施加磁场将步骤(B)中获得的附聚物与悬浮液分离,并且(D)在步骤(C)中分离的附聚物的解离, 通过将pH设定为至少一个第一材料和至少一个磁性颗粒承载相同表面电荷的值,以获得至少一种第一材料。
    • 8. 发明授权
    • Preparation of acyloxyalkoxysilanes
    • 酰氧基烷氧基硅烷的制备
    • US5817853A
    • 1998-10-06
    • US909941
    • 1997-08-12
    • Holger FriedrichBernd LeutnerNorbert MrongaRaimund Schmid
    • Holger FriedrichBernd LeutnerNorbert MrongaRaimund Schmid
    • C07F7/04C07F7/08C07F7/12
    • C07F7/045
    • A process for preparing a silane of the formula I R.sup.1.sub.n SiR.sup.2.sub.m (I) where R.sup.1 is --O--Y, n is an integer from 1 to 3, R.sup.2 is ##STR1## m is an integer from 1 to 3 and n+m=4, and Y and Z are each, independently of one another, unsubstituted or mono- or polyhalo-substituted C.sub.1 --C.sub.20 -alkyl, C.sub.2 --C.sub.20 -alkenyl, C.sub.2 --C.sub.20 -alkynyl and --(CH.sub.2).sub.p --A, where p is an integer from 0 to 6 and A, which is unsubstituted or substituted by one or more C.sub.1 -C.sub.6 -alkyls, is a 3- to 20-membered hydrocarbon ring entails reacting a halosilicon compound of the formula II SiX.sub.4 (II) where X is fluorine, chlorine, bromine and iodine, with compounds of the formula III and IV, or with an anhydride of the formula V and the compound of the formula IV ##STR2## where R.sup.1 and R.sup.2, and Z have the above meanings, M is a metal of main group one and two.
    • 制备式I的硅烷的方法R1nSiR2m(Ⅰ)其中R1为-OY,n为1至3的整数,R2为1至3的整数,n + m = 4,以及 Y和Z各自独立地为未取代的或单取代或多卤取代的C 1 -C 20 - 烷基,C 2 -C 20 - 烯基,C 2 -C 20 - 炔基和 - (CH 2)p A,其中p是0的整数 至6和A,其是未取代的或被一个或多个C 1 -C 6烷基取代的是3至20元烃环,其中使X为氟,氯, 溴和碘与式III和IV的化合物或与式V的酸酐和式IV的化合物MR2(III)的化合物HR1(IV)其中R1和R2以及Z具有 在上述含义中,M为主要组1和2的金属。