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    • 1. 发明申请
    • HIGHLY DAMPING EXPANDABLE MATERIAL AND DEVICES
    • 高阻尼可膨胀材料和器件
    • WO2009036784A1
    • 2009-03-26
    • PCT/EP2007/008141
    • 2007-09-19
    • HENKEL AG & CO. KGAALECLERC, DelphineMERLETTE, NicolasWOJTOWICKI, Jean-Luc
    • LECLERC, DelphineMERLETTE, NicolasWOJTOWICKI, Jean-Luc
    • C08J9/06C08L23/02G10K11/16
    • G10K11/162B62D29/002C08K3/013C08K3/06C08K3/26C08K5/0025C08K5/21C08L23/02C08L23/0853C08L53/02C08L53/025C08L2205/02C08L2205/03C08L2312/00Y10T29/49826C08L2666/04C08L2666/02C08L2666/14
    • A thermally expandable material comprising: a) from 3 to 40 % by weight of a first thermoplastic elastomer having a first glass transition temperature, b) from 3 to 40 % by weight of a second thermoplastic elastomer having a second glass transition temperature, wherein the first and the second glass transition temperature differ by at least 10 °C c) from 5 to 50 % by weight of at least one thermoplastic polymer selected from the group consisting of polymers and copolymers with at least one polymerizable C = C double bond, d) from 0 to 30% by weight of at least one tackifying resin, e) at least one latent chemical blowing agent in an amount effective to cause the expandable material to expand at least 50 % in volume when heated at a temperature of 150 °C for at least 20 minutes, wherein the sum of components a) to e) is less than 100 % by weight, and the remainder to 100 % by weight is made up of further components or adjuvants. Preferably, the material comprises: a first thermoplastic elastomer which has a glass transition temperature in the range from -25 to 0.0 °C, a second thermoplastic elastomer which has a glass transition temperature in the range from 0.1 to 30 °C, at least one thermoplastic polymer c) selected from the group consisting of ethylene/vinyl acetate copolymers and ethylene/methyl acrylate copolymers, at least one latent chemical blowing agent, at least one curing agent based on sulfur and/or sulfur compounds. The material can be used for various sound-dampening applications like dissipative vibratory wave barriers, sound dampening of automotive closure panel assemblies, cavity filler inserts, and constrained layer damping structures.
    • 一种热可膨胀材料,其包含:a)3至40重量%的具有第一玻璃化转变温度的第一热塑性弹性体,b)3至40重量%的具有第二玻璃化转变温度的第二热塑性弹性体,其中 第一和第二玻璃化转变温度相差至少10℃c)5至50重量%的至少一种选自具有至少一个可聚合C = C双键的聚合物和共聚物的热塑性聚合物,d )0至30重量%的至少一种增粘树脂,e)至少一种潜在的化学发泡剂,其有效量使得可膨胀材料在150℃的温度下加热时体积膨胀至少50% 至少20分钟,其中组分a)至e)的总和小于100重量%,其余至100重量%由其它组分或佐剂组成。 优选地,该材料包括:玻璃化转变温度为-25至0.0℃的第一热塑性弹性体,玻璃化转变温度为0.1-30℃的第二热塑性弹性体,至少一种 选自乙烯/乙酸乙烯酯共聚物和乙烯/丙烯酸甲酯共​​聚物的至少一种潜热化学发泡剂,至少一种基于硫和/或硫化合物的固化剂的热塑性聚合物c)。 该材料可用于各种声音衰减应用,如耗散振动波屏障,汽车闭合面板组件的声音衰减,腔体填充插入物和约束层阻尼结构。