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1. 发明授权

US5641879A Phthalocyanines substituted by phosphorus-containing groups 失效
标题翻译：由含磷基团取代的酞菁
公开(公告)号：US5641879A
公开(公告)日：1997-06-24
申请号：US530971
申请日：1995-09-20
申请人： Heinz Wolleb , Hanspeter Preiswerk , Beat Schmidhalter , Heinz Spahni
发明人： Heinz Wolleb , Hanspeter Preiswerk , Beat Schmidhalter , Heinz Spahni
IPC分类号： B41M5/26 , C07D487/22 , C09B47/04 , C09B47/10 , G11B7/244
CPC分类号： C07D487/22 , C09B47/10
摘要： The invention relates to phthalocyanines and metal complexes thereof with divalent metals or divalent oxo metals, which contain at least one phosphorus-containing substituent bonded to the peripheral carbon skeleton via the phosphorus atom.The compounds preferably conform to the general structural formula (G).sub.k -A-(Q).sub.l, in which A is a phthalocyanine or metal complex thereof with a divalent metal or a divalent oxo metal, G is a phosphorus-containing substituent, Q is a further substituent as defined below, the index k is a number from 1 to 16, and l, independently thereof, is 0 or a number from 1 to 15, with the proviso that the sum of k and l is a number less than or equal to 16.The invention also relates to a material for the optical recording and storage of information, in which at least one storage layer (2) of a novel phthalocyanine compound or a metal complex thereof has been applied to a transparent, dielectric carrier material (1).
摘要翻译：本发明涉及酞菁及其与二价金属或二价氧代金属的金属络合物，其含有至少一个通过磷原子与外围碳骨架结合的含磷取代基。化合物优选符合通式结构式（G）kA-（Q）1，其中A是与二价金属或二价氧代金属的酞菁或其金属络合物，G是含磷取代基，Q是另外的取代基如下所定义，索引k为1至16的数字，且l独立地为0或1至15的数，条件是k和l的和小于或等于本发明还涉及一种用于光学记录和存储信息的材料，其中至少一个新的酞菁化合物或其金属络合物的存储层（2）已经被施加到透明的介电载体材料（ 1）。

2. 发明申请

US20080130474A1 Optical Recording Materials Having High Stroage Density 审中-公开
标题翻译：具有高剧烈密度的光学记录材料
公开(公告)号：US20080130474A1
公开(公告)日：2008-06-05
申请号：US10561392
申请日：2004-06-25
申请人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
发明人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
IPC分类号： G11B7/24 , B32B3/02
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光记录介质，其包括基底，记录层和任选的一个或多个反射层，其中记录层包含式（I）的化合物。关于进一步取代基的详细定义，参见说明书。特别是在300〜500nm的波长下进行记录和回放，例如使用蓝色激光。录音和播放质量极佳，即使在高速下也能保持较高的存储密度。

3. 发明申请

US20070172624A1 Optical recording materials writable using blue lasers 审中-公开
标题翻译：光学记录材料可使用蓝色激光器写入
公开(公告)号：US20070172624A1
公开(公告)日：2007-07-26
申请号：US10590021
申请日：2005-02-16
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2492 , C09B47/045 , G11B7/2472 , G11B7/2475 , G11B7/2478 , G11B7/248 , G11B7/2534 , G11B7/259 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I) or a tautomeric or mesomeric form thereof, wherein G1 and G2 are each independently of the other C(R5) or N; M1 is a lanthanide or transition metal of groups 4 to 10; P is a phthalocyanino diradical; and R1 to R5 are substituents as defined in the description and the claims. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
摘要翻译：本发明涉及一种包括基底，记录层和任选的一个或多个反射层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或介导体形式，其中G 1， / SUB和G 2各自独立地为C（R 5 N）或N; M 1是第4至10族的镧系元素或过渡金属; P是酞菁双基; 和R 1至R 5是如说明书和权利要求书中所定义的取代基。记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，可以保持较高的存储密度。

4. 发明申请

US20050250942A1 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US20050250942A1
公开(公告)日：2005-11-10
申请号：US11169126
申请日：2005-06-28
申请人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： B41M5/26 , C09B47/12 , C09B47/18 , C09B47/24 , C09B67/22 , G11B7/244 , G11B7/248 , G11B7/26 , C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

5. 发明授权

US07378221B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07378221B2
公开(公告)日：2008-05-27
申请号：US11169126
申请日：2005-06-28
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

6. 发明授权

US07034148B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07034148B2
公开(公告)日：2006-04-25
申请号：US10474634
申请日：2002-04-09
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , C09B67/00 , C07D487/22
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines (I) and (II) with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media
摘要翻译：通过在催化剂存在下使包含两种酞菁（I）和（II）的混合物A与金属茂衍生物反应而获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质

7. 发明授权

US06849315B2 Fast-writable and precision-writable high-capacity optical storage media 失效
标题翻译：快速写入和精确写入的大容量光存储介质
公开(公告)号：US06849315B2
公开(公告)日：2005-02-01
申请号：US10483130
申请日：2002-07-04
申请人： Urs Lehmann , Peter Aeschlimann , Peter Sutter , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Urs Lehmann , Peter Aeschlimann , Peter Sutter , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B41M5/26 , C09B11/00 , C09B11/02 , C09B11/20 , C09B11/28 , C09B45/14 , C09B45/20 , C09B55/00 , C09B69/02 , G11B7/004 , G11B7/24 , G11B7/244 , G11B7/246 , G11B7/2467 , G11B7/249 , G11B7/253 , G11B7/254 , G11B7/2542 , G11B7/258 , G11B7/259 , G11B7/26 , B32B3/02
CPC分类号： G11B7/244 , C09B11/28 , G11B7/2467 , G11B7/249 , G11B7/253 , G11B7/2542 , G11B7/259 , Y10T428/21
摘要： The invention relates to an optical recording medium, comprising a substrate and a recording layer, wherein the recording layer comprises a compound of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are each independently of the others hydrogen, G1 or C1-C24alkyl, C2-C24alkenyl, C2-C24alkynyl, C3-C24cycloalkyl, C3-C24cycloalkenyl, C7-C24aralkyl, C6-C24aryl, C4-C12heteroaryl or C1-C12heterocycloalkyl, each unsubstituted or substituted by one or more identical or different substituents G1, wherein R1 and R2, R1 and R13, R2 and R3, R3 and R4, R4 and R5, R5 and R6, R6 and R7, R7 and R8, R8 and R9, R9 and R10, R10 and R11, R11 and R12 and/or R12 and R13 can independently of one another be bonded to one another in pairs separately or, when they contain substitutable sites, via a direct bond or via a —CH2—, —O—, —S—, —NH— or —NC1-C24alkyl-bridge in such a manner that, together with the atoms and bonds indicated in formula (I), five- or six-membered, saturated, unsaturated or aromatic, unsubstituted or G1-substituted rings are formed, G1 is any desired substituent,? xm- is an inorganic, organic organometallic anion, Yn+ is a proton or a metal, ammonium or phosphonium cation, and m and n are each independently of the other a number from 1 to 5, and p and q are each independently of the other O or a number from 0.2 to 6, the ratio of p and q to one another, depending upon m and n and, as applicable, the number of charged G1, being such that in formula (I) there is no excess positive or negative charge. Generally the optical recording medium according to the invention additionally comprises a reflecting layer. The recording media according to the invention exhibit high sensitivity and good playback characteristics, especially at high recording and playback speeds. The light stability is also excellent.
摘要翻译：本发明涉及一种光记录介质，包括基片和记录层，其中记录层包括式（I）化合物，其中R1，R2，R3，R4，R5，R6，R7，R8，R9，R10 ，R11，R12和R13各自独立地为氢，G1或C1-C24烷基，C2-C24链烯基，C2-C24炔基，C3-C24环烷基，C3-C24环烯基，C7-C24芳烷基，C6-C24芳基，C4-C12杂芳基或C1- C 1 -C 6杂环烷基，每个未取代或被一个或多个相同或不同的取代基G1取代，其中R1和R2，R1和R13，R2和R3，R3和R4，R4和R5，R5和R6，R6和R7，R7和R8，R8 并且R 9，R 9和R 10，R 10和R 11，R 11和R 12和/或R 12和R 13可以彼此独立地彼此相互键合，或者当它们含有可取代的位置时，经由直接键或通过-CH 2 - ，-O - ， - S - ， - NH-或-NCl-C24烷基 - 桥，其与式（I）中所示的原子和键一起为五或六元饱和，形成不饱和或芳族，未取代或者G1取代的环，G1是a

8. 发明申请

US20050008974A1 Writable high-capacity optical storage media containing metal complexes 审中-公开
标题翻译：包含金属络合物的可写入大容量光存储介质
公开(公告)号：US20050008974A1
公开(公告)日：2005-01-13
申请号：US10495678
申请日：2002-11-07
申请人： Colin Morton , Taher Yousaf , Jean-Luc Budry , Beat Schmidhalter , Heinz Spahni
发明人： Colin Morton , Taher Yousaf , Jean-Luc Budry , Beat Schmidhalter , Heinz Spahni
IPC分类号： B41M5/26 , C07D487/22 , C07F15/02 , G11B7/004 , G11B7/24 , G11B7/244 , G11B7/248 , G11B7/253 , G11B7/26 , C09B47/04
CPC分类号： C07D487/22 , G11B7/248
摘要： The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.
摘要翻译：本发明涉及一种包括基材和记录层的光学记录介质，其中记录层包含式（I）的配合物，或其中Q 2是式（II）的配体或其互变异构体，和 R1，R2，R3，R4，R5，R6，R7和R8各自独立地为H，卤素，氰基，COOR9，CONHR9，CONR9R10，R9，OR9，SR9，NHR9或NR9R10，其中R9和R10各自独立于其它C 6 -C 10芳基，C 4 -C 9杂芳基或直链或支链C 1 -C 24烷基，C 3 -C 24环烯基，C 2 -C 24烯基，C 3 -C 24环烯基，C 2 -C 24炔基，C 1 -C 12杂环烷基，未取代或取代的C 1 -C 12杂环烯基， R 1和R 2，R 3和R 4，R 5和R 6以及R 7和R 8彼此独立地可以通过直接键合或通过桥O或S键合，M m是具有5个碳原子的过渡金属阳离子或6个电子，L1是具有子结构NC，PC或As-C，L2的配体，独立于L1，是另一个配体c 保持至少一个杂原子N，P，As，O，S，Se或Te，L3 - 是CN - ，SCN - ，NCS - ，OCN - ，NCO - ， - N3-，L1-O - ，L1-S-，L

9. 发明申请

US20070042152A1 High-capacity optical storage media 审中-公开
标题翻译：大容量光存储介质
公开(公告)号：US20070042152A1
公开(公告)日：2007-02-22
申请号：US10551318
申请日：2004-02-25
申请人： Jean-Marie Adam , Peter Aeschlimann , Jean-Pierre Bacher , Jean-Luc Budry , Urs Lehmann , Colin Morton , Beat Schmidhalter , Heinz Spahni
发明人： Jean-Marie Adam , Peter Aeschlimann , Jean-Pierre Bacher , Jean-Luc Budry , Urs Lehmann , Colin Morton , Beat Schmidhalter , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2472 , C09B45/20 , C09B45/22 , C09B56/00 , G11B7/246 , G11B7/2467 , G11B7/2478 , G11B7/248 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2498 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2535 , G11B7/256 , G11B7/2575 , G11B7/259 , G11B2007/24612 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715 , G11B2007/25716 , Y10T428/21
摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula [L1Mr-4L-2]o [Am]p [Zn+q(I), [L1Mr−3L−3]0 [Am]P[Zn+]q(II) or [L3Mr−2L4]0 [Am]p[Zn+]q (III), or where applicable a mesomeric or tautomeric form thereof, wherein L1 and L2 are each independently of the other and L3 and L4 are each independently of the other wherein Q1 is CR1 or N, Q2 is O, S, NR10 or Q5═Q8, Q3 is CR3 or N, Q4 is O, S, NR10 or Q7═Q8, Q5 is CR5 or N, Q6 is CR6 or N, Q7 is CR7 or N, Q8 is CR8 or N, and Q9 is 0, S, NR10 or Q6═Q8; Mr, Am−, Zn+, R2, R9 are as defined in the claims.
摘要翻译：本发明涉及一种包括基底，反射层和记录层的光学记录介质，其中记录层包含式[L1Mr-4L-2]的化合物[A] （I），[L 1] M（R） -3 N （II）或[L 3] M-r-2 L _{（III），或其中（a）和（c）适用其互变异构体或其互变异构体形式，其中L 1和L 2各自独立地为另一个，L 3和L 4 其中Q 1是CR 1或N，Q 2是O，S，NR _{是CR 5或N，Q 6是CR 6 或者N，Q 7是CR 7或N，Q 8是CR 8或N 并且Q 9是0，S，NR 10或Q 6 -Q 8; M ，Z-N +，R 2，R 9，如权利要求中所定义。}}

10. 发明授权

US06245403B1 Writable and erasable high-density optical storage media 失效
标题翻译：可写和可擦除的高密度光存储介质
公开(公告)号：US06245403B1
公开(公告)日：2001-06-12
申请号：US09069266
申请日：1998-04-29
申请人： Heinz Spahni , Jin Mizuguchi , Beat Schmidhalter , Annemarie Wolleb , Jean-Luc Budry , Gérald Giller
发明人： Heinz Spahni , Jin Mizuguchi , Beat Schmidhalter , Annemarie Wolleb , Jean-Luc Budry , Gérald Giller
IPC分类号： B32B302
CPC分类号： C07D471/06 , C09B5/62 , G11B7/00455 , G11B7/0052 , G11B7/00552 , G11B7/006 , G11B7/244 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要： The invention relates to an optical storage medium comprising a substrate and a storage layer, wherein the storage layer comprises a compound of the formula (I) or (II) in which A and A′, independently of one another, are unsubstituted or mono- or di-halo-, -hydroxy-, —C1-C6alkyl-, —C1-C6alkoxy-, -cyano- or -nitro-substituted phenyl, pyridyl, pyrrolyl, imidazolyl, furyl or thienyl, which can, if desired, be fused to a benzene ring, are halide, tetrafluoroborate or unsubstituted or with one or more halogen substituted C1-C6alkane-sulfonate, benzenesulfonate, C1-C6alkylbenzenesulfonate, C1-C6alkylsulfate or di-C1-C6alkyl-phosphonate of N—C1-C6alkyl-pyridiniumyl, or are unsubstituted or mono- or di-hydroxy-substituted C2-C6alkyl or C2-C6alkenyl, whose chain may be uninterrupted or interrupted by one or two oxygen atoms, B and B′, independently of one another, are 2 H, S, S2 or SO2, and n and n′, independently of one another, are each a number from 1 to 4. The invention also relates to a process for the optical writing, storage, reading, modification or erasing of data at a wavelength of from 400 to 700 nm using a novel recording medium, to an optical recorder for the optical writing, modification or erasing of data using only continuous laser radiation or only modulated laser radiation, to a process for converting a compound of the formula (I) or (II) from a black form into a red form by mechanical force, and to new compounds of the formula (I) or (II).
摘要翻译：本发明涉及一种包括基材和存储层的光学存储介质，其中该储存层包含式（I）或（II）的化合物，其中A和A'彼此独立地为未取代的或单 - 或二卤代 - ， - 羟基 - ，-C 1 -C 6烷基 - ， - C 1 -C 6烷氧基 - ， - 氰基 - 或 - 硝基取代的苯基，吡啶基，吡咯基，咪唑基，呋喃基或噻吩基，如果需要，苯基环，卤素取代的C 1 -C 6烷基磺酸酯，苯磺酸酯，C 1 -C 6烷基苯磺酸酯，C 1 -C 6烷基硫酸酯或N-C 1 -C 6烷基 - 吡啶鎓基的二-C 1 -C 6烷基 - 膦酸酯，或未被取代的单或二羟基取代的C 2 -C 6烷基或C 2 -C 6烯基，其链可以不间断或被一个或两个氧原子间隔，B和B'彼此独立地为2 H，S， S2或SO2，n和n'彼此独立地为1至4的数。本发明还涉及一种pr 用于使用新颖的记录介质将波长为400至700nm的数据的光学写入，存储，读取，修改或擦除的光学记录到用于仅使用连续激光辐射的光学写入，修改或擦除数据的光学记录器，通过机械力将式（I）或（II）的化合物从黑色形式转化成红色的方法，以及式（I）或（II）的新化合物的方法。

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