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1. 发明授权

US08697785B2 N-allyl carbamate compounds and use thereof, in particular in radiation-curing coatings 有权
标题翻译： N-烯丙基氨基甲酸酯化合物及其用途，特别是辐射固化涂料
公开(公告)号：US08697785B2
公开(公告)日：2014-04-15
申请号：US13483918
申请日：2012-05-30
申请人： Heinz Greisiger , Marc Entenmann , Thadeus Schauer
发明人： Heinz Greisiger , Marc Entenmann , Thadeus Schauer
IPC分类号： C08K5/34 , D21H21/16
CPC分类号： C07C271/12 , C08G18/8108 , C08G18/8166 , C08K5/205 , C09D7/63 , C09D11/101 , C09D175/04
摘要： An N-allyl carbamate compound which is suitable as an additive is proposed, the chemical main body thereof allowing modifications of the overall structure of the compound in order to ensure sufficiently high compatibility with as many binder systems as possible, wherein the UV-crosslinkable double bond is designed to be as sterically undemanding as possible, linked via flexible bonds, and highly reactive. In the N-allyl carbamate compound of general formula (A) according to the invention, the radical R1 is selected from straight-chain, branched, or cyclic substituted aliphatic hydrocarbon radicals and heterocyclic radicals, wherein the radical R1 includes at least one ethylenically unsaturated bond, wherein R2, R3, and R4 are selected from hydrogen and hydrocarbon radicals, wherein R5 represents hydrogen or an allyl group, and wherein c is an integer of 1 or greater.
摘要翻译：提出适合作为添加剂的N-烯丙基氨基甲酸酯化合物，其化学主体允许改变化合物的总体结构，以确保与尽可能多的粘合剂体系足够高的相容性，其中UV可交联的双债券被设计为尽可能的空间不高，通过柔性债券连接，并且反应性高。在根据本发明的通式（A）的N-烯丙基氨基甲酸酯化合物中，基团R1选自直链，支链或环状取代的脂族烃基和杂环基，其中基团R1包括至少一个烯属不饱和键，其中R 2，R 3和R 4选自氢和烃基，其中R 5表示氢或烯丙基，并且其中c为1或更大的整数。

2. 发明申请

US20120296021A1 N-ALLYL CARBAMATE COMPOUNDS AND USE THEREOF, IN PARTICULAR IN RADIATION-CURING COATINGS 有权
标题翻译： N-甲基碳酸酯化合物及其用途，特别是辐射固化涂料
公开(公告)号：US20120296021A1
公开(公告)日：2012-11-22
申请号：US13483918
申请日：2012-05-30
申请人： Heinz Greisiger , Marc Entenmann , Thadeus Schauer
发明人： Heinz Greisiger , Marc Entenmann , Thadeus Schauer
IPC分类号： C07C271/12 , C08L39/04 , C09D139/04 , C09D175/04 , C09D167/00 , C08K5/20 , C09D133/06
CPC分类号： C07C271/12 , C08G18/8108 , C08G18/8166 , C08K5/205 , C09D7/63 , C09D11/101 , C09D175/04
摘要： An N-allyl carbamate compound which is suitable as an additive is proposed, the chemical main body thereof allowing modifications of the overall structure of the compound in order to ensure sufficiently high compatibility with as many binder systems as possible, wherein the UV-crosslinkable double bond is designed to be as sterically undemanding as possible, linked via flexible bonds, and highly reactive. In the N-allyl carbamate compound of general formula (A) according to the invention, the radical R1 is selected from straight-chain, branched, or cyclic substituted aliphatic hydrocarbon radicals and heterocyclic radicals, wherein the radical R1 includes at least one ethylenically unsaturated bond, wherein R2, R3, and R4 are selected from hydrogen and hydrocarbon radicals, wherein R5 represents hydrogen or an allyl group, and wherein c is an integer of 1 or greater.
摘要翻译：提出适合作为添加剂的N-烯丙基氨基甲酸酯化合物，其化学主体允许改变化合物的总体结构，以确保与尽可能多的粘合剂体系足够高的相容性，其中UV可交联的双债券被设计为尽可能的空间不高，通过柔性债券连接，并且反应性高。在根据本发明的通式（A）的N-烯丙基氨基甲酸酯化合物中，基团R1选自直链，支链或环状取代的脂族烃基和杂环基，其中基团R1包括至少一个烯属不饱和键，其中R 2，R 3和R 4选自氢和烃基，其中R 5表示氢或烯丙基，并且其中c为1或更大的整数。

3. 发明申请

US20050119442A1 Copolymers containing aminoplast units and use thereof as a dispersing agent or stabilizers 失效
标题翻译：含有氨基塑料单元的共聚物及其作为分散剂或稳定剂的用途
公开(公告)号：US20050119442A1
公开(公告)日：2005-06-02
申请号：US10500059
申请日：2002-12-17
申请人： Klause Dziwok , Inge Kramer , Norbert Schall , Helmut Coutelle , Sabine Huth , Alan Steinmetz , Thadeus Schauer , Heinz Greisiger , Mark Entenmann
发明人： Klause Dziwok , Inge Kramer , Norbert Schall , Helmut Coutelle , Sabine Huth , Alan Steinmetz , Thadeus Schauer , Heinz Greisiger , Mark Entenmann
IPC分类号： C08G12/42 , C09B67/46 , C09D7/45 , C09D17/00 , C09D133/06 , C09D161/20 , C08G2/00 , C08G73/06
CPC分类号： C08G12/424 , C08G12/42 , C09B67/0085 , C09D7/45 , C09D17/001
摘要： A description is given of water-soluble aminoplast ether copolymers of the following structural type: where Z is an aminoplast unit based on a glycoluril which is unsubstituted or substituted by a reactive OR group (where R is an alkyl, alkylene, alkyl ether or alkyl ester group, preferably a lower alkyl group, e.g., a methyl or ethyl group); B is the radical of an essentially water-insoluble polymer selected from poly-n-butyl acrylate, poly-n-butyl methacrylate, polyethyl acrylate, polytetrahydrofuran, polyethyl methacrylate, polymethyl acrylate, polymethyl methacrylate, a predominantly aliphatic polycarbonate or a predominantly aromatic polycarbonate, and more preferably from a poly-n-butyl methacrylate or a predominantly aliphatic or aromatic polycarbonate having at least two functional groups which are able to react with the OR function of the aminoplast unit, preferably having a hydroxyl function; R1 is the radical of a hydrophilic organic compound containing at least one functional group which is able to react with the OR function of the aminoplast unit to form an ether bond, preferably having a hydroxyl function, and a is at least 1. A description is additionally given of a process for preparing the above aminoplast ether copolymers and also of their use as dispersants and stabilizers.
摘要翻译：给出以下结构类型的水溶性氨基塑料醚共聚物的描述：其中Z是基于甘脲的氨基塑料单元，其未被取代或被反应性OR基团取代（其中R是烷基，亚烷基，烷基醚或烷基酯基，优选低级烷基，例如甲基或乙基）; B是基本上不溶于水的聚合物的基团，其选自聚丙烯酸正丁酯，聚甲基丙烯酸正丁酯，聚丙烯酸乙酯，聚四氢呋喃，聚甲基丙烯酸乙酯，聚丙烯酸甲酯，聚甲基丙烯酸甲酯，主要是脂族聚碳酸酯或主要是芳族聚碳酸酯，更优选由具有至少两个能够与氨基塑料单元的OR功能反应的至少两个官能团的优选具有羟基官能团的聚甲基丙烯酸甲酯或主要是脂族或芳族聚碳酸酯; R1是含有至少一个官能团的基团，其能够与氨基塑料单元的OR功能反应形成醚键，优选具有羟基官能团，并且a至少为1.描述为另外给出了制备上述氨基塑料醚共聚物的方法，以及它们作为分散剂和稳定剂的用途。

4. 发明授权

US07335699B2 Copolymers containing aminoplast units and use thereof as a dispersing agent or stabilizers 失效
标题翻译：含有氨基塑料单元的共聚物及其作为分散剂或稳定剂的用途
公开(公告)号：US07335699B2
公开(公告)日：2008-02-26
申请号：US10500059
申请日：2002-12-17
申请人： Klaus Dziwok , Inge Krämer , Norbert Schall , Helmut Coutelle , Sabine Huth , Alan Steinmetz , Thadeus Schauer , Heinz Greisiger , Mark Entenmann
发明人： Klaus Dziwok , Inge Krämer , Norbert Schall , Helmut Coutelle , Sabine Huth , Alan Steinmetz , Thadeus Schauer , Heinz Greisiger , Mark Entenmann
IPC分类号： C08G73/06 , C08G12/42
CPC分类号： C08G12/424 , C08G12/42 , C09B67/0085 , C09D7/45 , C09D17/001
摘要： A description is given of water-soluble aminoplast ether copolymers of the following structural type: wherein Z is a glycoluril central unit, B is a radical of an essentially water-insoluble polymer and R1 is a radical of a hydrophilic organic compound. The ratio R1:B is selected within a range of about 1.5 to 4:1 and the overall mass of the water-soluble aminoplast ether copolymer is from about 2000 to 50 000 g/mol such that the copolymer is soluble in water and may be used as a dispersant for e.g. pigments in polar solvents, e.g. water.
摘要翻译：给出以下结构类型的水溶性氨基塑料醚共聚物的描述：其中Z是甘脲中心单元，B是基本上不溶于水的聚合物的基团，R 1是亲水性有机化合物的基团。比例R1：B选择在约1.5至4：1的范围内，并且水溶性氨基塑料醚共聚物的总质量为约2000至50 000g / mol，使得共聚物可溶于水，并且可以是用作例如的分散剂极性溶剂中的颜料，例如水。

5. 发明授权

US07875112B2 Effect pigments that are surface-modified with LCST and/or UCST polymers 有权
标题翻译：用LCST和/或UCST聚合物进行表面改性的效果颜料
公开(公告)号：US07875112B2
公开(公告)日：2011-01-25
申请号：US12406457
申请日：2009-03-18
申请人： Adalbert Huber , Marc Entenmann , Thadeus Schauer
发明人： Adalbert Huber , Marc Entenmann , Thadeus Schauer
IPC分类号： C09C1/00 , B32B5/16 , B32B9/00
CPC分类号： C09C1/644 , C01P2004/20 , C09C1/0015 , C09C3/10 , C09C3/12 , C09C2200/1004 , C09C2200/102 , C09C2200/307 , C09C2200/405 , C09C2200/505 , Y10T428/2911 , Y10T428/2991 , Y10T428/2993 , Y10T428/2996 , Y10T428/2998
摘要： The present invention relates to surface-modified effect pigments based on flake-form substrates which are distinguished by the fact that they are sheathed with one or more layers of immobilised LCST and/or UCST polymers. The invention furthermore relates to a process for the production of the surface-modified effect pigments and to the use thereof in surface coatings, water-borne coatings, powder coatings, paints, printing inks, security printing inks, plastics, concrete, in cosmetic formulations, in agricultural sheeting and tarpaulins, for the laser marking of papers and plastics, as light protection, as pigment for corrosion protection and for the preparation of pigment compositions and dry preparations.
摘要翻译：本发明涉及基于片状基材的表面改性效果颜料，其特征在于它们被一层或多层固定化LCST和/或UCST聚合物包覆。本发明还涉及一种生产表面改性效果颜料的方法及其在表面涂料，水性涂料，粉末涂料，油漆，印刷油墨，安全印刷油墨，塑料，混凝土，化妆品配方中的应用，用于农用片材和防水油布，用于纸张和塑料的激光打标，作为防光剂，作为防腐颜料和颜料组合物和干燥制剂的制备。

6. 发明授权

US07578879B2 Effect pigments that are surface-modified with LCST and/or UCST polymers 有权
标题翻译：用LCST和/或UCST聚合物进行表面改性的效果颜料
公开(公告)号：US07578879B2
公开(公告)日：2009-08-25
申请号：US10527980
申请日：2003-09-04
申请人： Adalbert Huber , Marc Entenmann , Thadeus Schauer
发明人： Adalbert Huber , Marc Entenmann , Thadeus Schauer
IPC分类号： C09C1/00 , C09C1/04 , C09C1/14 , C04B14/00 , C04B14/04 , C08K5/00
CPC分类号： C09C1/644 , C01P2004/20 , C09C1/0015 , C09C3/10 , C09C3/12 , C09C2200/1004 , C09C2200/102 , C09C2200/307 , C09C2200/405 , C09C2200/505 , Y10T428/2911 , Y10T428/2991 , Y10T428/2993 , Y10T428/2996 , Y10T428/2998
摘要： The present invention relates to surface-modified effect pigments based on flake-form substrates which are distinguished by the fact that they are sheathed with one or more layers of immobilized LCST and/or UCST polymers. The invention furthermore relates to a process for the production of the surface-modified effect pigments and to the use thereof in surface coatings, water-borne coatings, powder coatings, paints, printing inks, security printing inks, plastics, concrete, in cosmetic formulations, in agricultural sheeting and tarpaulins, for the laser marking of papers and plastics, as light protection, as pigment for corrosion protection and for the preparation of pigment compositions and dry preparations.
摘要翻译：本发明涉及基于片状基材的表面改性效果颜料，其特征在于它们被一层或多层固定化LCST和/或UCST聚合物包覆。本发明还涉及一种生产表面改性效果颜料的方法及其在表面涂料，水性涂料，粉末涂料，油漆，印刷油墨，安全印刷油墨，塑料，混凝土，化妆品配方中的用途，用于农用片材和防水油布，用于纸张和塑料的激光打标，作为防光剂，作为防腐颜料和颜料组合物和干燥制剂的制备。

7. 发明申请

US20060046057A1 Effect pigments that are surface-modified with lcst and/or ucst polymers 有权
标题翻译：用lcst和/或ucst聚合物进行表面改性的效果颜料
公开(公告)号：US20060046057A1
公开(公告)日：2006-03-02
申请号：US10527980
申请日：2003-09-04
申请人： Adalbert Huber , Marc Entenmann , Thadeus Schauer
发明人： Adalbert Huber , Marc Entenmann , Thadeus Schauer
IPC分类号： C09D11/00 , C09D11/14 , C09C1/62 , C09C1/00 , C04B14/20 , C04B14/00 , B32B15/02
CPC分类号： C09C1/644 , C01P2004/20 , C09C1/0015 , C09C3/10 , C09C3/12 , C09C2200/1004 , C09C2200/102 , C09C2200/307 , C09C2200/405 , C09C2200/505 , Y10T428/2911 , Y10T428/2991 , Y10T428/2993 , Y10T428/2996 , Y10T428/2998
摘要： The present invention relates to surface-modified effect pigments based on flake-form substrates which are distinguished by the fact that they are sheathed with one or more layers of immobilised LCST and/or UCST polymers. The invention furthermore relates to a process for the production of the surface-modified effect pigments and to the use thereof in surface coatings, water-borne coatings, powder coatings, paints, printing inks, security printing inks, plastics, concrete, in cosmetic formulations, in agricultural sheeting and tarpaulins, for the laser marking of papers and plastics, as light protection, as pigment for corrosion protection and for the preparation of pigment compositions and dry preparations.
摘要翻译：本发明涉及基于片状基材的表面改性效果颜料，其特征在于它们被一层或多层固定化LCST和/或UCST聚合物包覆。本发明还涉及一种生产表面改性效果颜料的方法及其在表面涂料，水性涂料，粉末涂料，油漆，印刷油墨，安全印刷油墨，塑料，混凝土，化妆品配方中的应用，用于农用片材和防水油布，用于纸张和塑料的激光打标，作为防光剂，作为防腐颜料和颜料组合物和干燥制剂的制备。

8. 发明申请

US20090176089A1 Effect Pigments That Are Surface-Modified With LCST And/Or UCST Polymers 有权
标题翻译：用LCST和/或UCST聚合物表面改性的效果颜料
公开(公告)号：US20090176089A1
公开(公告)日：2009-07-09
申请号：US12406457
申请日：2009-03-18
申请人： Adalbert HUBER , Marc Entenmann , Thadeus Schauer
发明人： Adalbert HUBER , Marc Entenmann , Thadeus Schauer
IPC分类号： B32B18/00 , C09D5/29 , B32B27/06 , C09D5/08
CPC分类号： C09C1/644 , C01P2004/20 , C09C1/0015 , C09C3/10 , C09C3/12 , C09C2200/1004 , C09C2200/102 , C09C2200/307 , C09C2200/405 , C09C2200/505 , Y10T428/2911 , Y10T428/2991 , Y10T428/2993 , Y10T428/2996 , Y10T428/2998
摘要： The present invention relates to surface-modified effect pigments based on flake-form substrates which are distinguished by the fact that they are sheathed with one or more layers of immobilised LCST and/or UCST polymers. The invention furthermore relates to a process for the production of the surface-modified effect pigments and to the use thereof in surface coatings, water-borne coatings, powder coatings, paints, printing inks, security printing inks, plastics, concrete, in cosmetic formulations, in agricultural sheeting and tarpaulins, for the laser marking of papers and plastics, as light protection, as pigment for corrosion protection and for the preparation of pigment compositions and dry preparations.
摘要翻译：本发明涉及基于片状基材的表面改性效果颜料，其特征在于它们被一层或多层固定化LCST和/或UCST聚合物包覆。本发明还涉及一种生产表面改性效果颜料的方法及其在表面涂料，水性涂料，粉末涂料，油漆，印刷油墨，安全印刷油墨，塑料，混凝土，化妆品配方中的用途，用于农用片材和防水油布，用于纸张和塑料的激光打标，作为防光剂，作为防腐颜料和颜料组合物和干燥制剂的制备。

9. 发明授权

US06686046B2 Method of coating substrate surfaces with LCST polymers 有权
标题翻译：用LCST聚合物涂覆基材表面的方法
公开(公告)号：US06686046B2
公开(公告)日：2004-02-03
申请号：US10219911
申请日：2002-08-15
申请人： Thadeus Schauer , Marc Entenmann , Claus D. Eisenbach
发明人： Thadeus Schauer , Marc Entenmann , Claus D. Eisenbach
IPC分类号： B32B516
CPC分类号： C09C1/24 , C01P2004/62 , C09C1/3676 , C09C3/10 , Y10T428/2991 , Y10T428/2998
摘要： In order to make it possible to treat particles in such a manner that they are stabilized as disperse particles in liquid media, such as varnishes, a method of coating particles with LCST polymers is proposed which is characterized by the following steps: a) dissolution of an LCST polymers in a solvent at a temperature below the LCST; b) mixing the solution obtained in step a) with the particles to be coated; and c) increasing the temperature of the mixture obtained in step b) to or beyond the point at which the LCST polymer deposits onto the particle surfaces.
摘要翻译：为了使得可以以这样的方式处理颗粒，使得它们作为分散粒子稳定在液体介质如清漆中的液体介质中，提出了用LCST聚合物涂覆颗粒的方法，其特征在于以下步骤：a）在低于LCST的温度下在溶剂中的LCST聚合物; b）将步骤a）中获得的溶液与待涂覆的颗粒混合; 和c）将步骤b）中获得的混合物的温度提高到或超过LCST聚合物沉积到颗粒表面上的点。

10. 发明授权

US07026051B2 Method of treating the surface of substrates 有权
标题翻译：处理基材表面的方法
公开(公告)号：US07026051B2
公开(公告)日：2006-04-11
申请号：US10775891
申请日：2004-02-09
申请人： Thadeus Schauer , Mark Entenmann , Claus D. Eisenbach , Waldemar Ph. Oechsner
发明人： Thadeus Schauer , Mark Entenmann , Claus D. Eisenbach , Waldemar Ph. Oechsner
IPC分类号： B32B5/16
CPC分类号： C08K9/08 , C01P2004/64 , C09C1/644 , C09D125/06 , Y10T428/2991 , Y10T428/2998
摘要： In order to provide a method by means of which the surface of substrates can be protected from corrosive attack and which, in particular, avoids the necessity for oxidative treatment to form oxide layers on surfaces or for phosphatizing or chromatizing treatment steps and is, in addition, simple to apply, it is proposed that the substrate be brought into contact with a solution of a polymer which exhibits UCST properties and which is caused to be deposited onto the surface of the substrate as a layer by decreasing the temperature of the polymer solution.
摘要翻译：为了提供一种可以保护基材表面免受腐蚀侵蚀的方法，特别是避免氧化处理在表面上形成氧化物层或用于磷酸化或染色处理步骤的方法，并且另外通过降低聚合物溶液的温度，提出使基板与表现出UCST性质的聚合物溶液接触，并且通过降低聚合物溶液的温度而沉积在基材表面上作为层。

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