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1. 发明授权

US07507866B2 Method for producing optically active alcohols or carboxylic acids 失效
标题翻译：光学活性醇或羧酸的制备方法
公开(公告)号：US07507866B2
公开(公告)日：2009-03-24
申请号：US10589049
申请日：2005-02-08
申请人： Heiko Urtel , Markus Rösch , Andrea Haunert , Markus Schubert
发明人： Heiko Urtel , Markus Rösch , Andrea Haunert , Markus Schubert
IPC分类号： C07C31/18 , C07C53/00
CPC分类号： C07C29/149 , C07B41/02 , C07B53/00 , C07B2200/07 , C07C213/00 , C07D307/33 , C07C215/08 , C07C215/10 , C07C215/18 , C07C215/28 , C07C31/22 , C07C31/207 , C07C31/205 , C07C31/36 , C07C31/20 , C07C31/12
摘要： The present invention relates to a process for preparing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxy carboxylic acids having from 3 to 25 carbon atoms or their acid derivatives or cyclization products by hydrogenating the correspondingly substituted optically active mono- or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active component consists of rhenium or of rhenium and comprises at least one further element having an atomic number of from 22 to 83, with the provisos that a. the at least one further element having an atomic number of from 22 to 83 is not ruthenium and b. in the case of the preparation of optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxy-1-alkanols by catalytically hydrogenating corresponding optically active 2-aminocarboxylic acids, 2-chlorocarboxylic acids, 2-hydroxycarboxylic acids and 2-alkoxycarboxylic acids or their acid derivatives, the at least one further element having an atomic number of from 22 to 83 is not palladium or platinum.
摘要翻译：本发明涉及通过氢化制备光学活性羟基，烷氧基 - ，氨基 - ，烷基 - ，芳基 - 或氯取代的醇或具有3至25个碳原子的羟基羧酸或其酸衍生物或环化产物的方法相应地取代的光学活性单羧酸或二羧酸或其酸衍生物在其活性组分由铼或铼组成的催化剂存在下，并且包含至少一种原子序数为22至83的另外的元素，条件是一个。原子序数为22〜83的至少一个以上的元素不是钌，而是b。在通过催化氢化相应的光学活性2-氨基羧酸，2-氯羧酸，2-羟基羧酸的2-氨基 - ，2-氯 - ，2-羟基 - 和2-烷氧基-1-链烷醇的制备酸和2-烷氧基羧酸或其酸衍生物，原子序数为22至83的至少一种另外的元素不是钯或铂。

2. 发明申请

US20070135648A1 Method for producing optically active alcohols or carboxylic acids 失效
标题翻译：光学活性醇或羧酸的制备方法
公开(公告)号：US20070135648A1
公开(公告)日：2007-06-14
申请号：US10589049
申请日：2005-02-08
申请人： Heiko Urtel , Markus Rosch , Andrea Haunert , Markus Schubert
发明人： Heiko Urtel , Markus Rosch , Andrea Haunert , Markus Schubert
IPC分类号： C07D307/02 , C07C27/04
CPC分类号： C07C29/149 , C07B41/02 , C07B53/00 , C07B2200/07 , C07C213/00 , C07D307/33 , C07C215/08 , C07C215/10 , C07C215/18 , C07C215/28 , C07C31/22 , C07C31/207 , C07C31/205 , C07C31/36 , C07C31/20 , C07C31/12
摘要： The present invention relates to a process for preparing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxy carboxylic acids having from 3 to 25 carbon atoms or their acid derivatives or cyclization products by hydrogenating the correspondingly substituted optically active mono- or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active component consists of rhenium or of rhenium and comprises at least one further element having an atomic number of from 22 to 83, with the provisos that a. the at least one further element having an atomic number of from 22 to 83 is not ruthenium and b. in the case of the preparation of optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxy-1-alkanols by catalytically hydrogenating corresponding optically active 2-aminocarboxylic acids, 2-chlorocarboxylic acids, 2-hydroxycarboxylic acids and 2-alkoxycarboxylic acids or their acid derivatives, the at least one further element having an atomic number of from 22 to 83 is not palladium or platinum.
摘要翻译：本发明涉及通过氢化制备光学活性羟基，烷氧基 - ，氨基 - ，烷基 - ，芳基 - 或氯取代的醇或具有3至25个碳原子的羟基羧酸或其酸衍生物或环化产物的方法相应地取代的光学活性单羧酸或二羧酸或其酸衍生物在其活性组分由铼或铼组成的催化剂存在下，并且包含至少一种原子序数为22至83的另外的元素，条件是一个。原子序数为22〜83的至少一个以上的元素不是钌，而是b。在通过催化氢化相应的光学活性2-氨基羧酸，2-氯羧酸，2-羟基羧酸的2-氨基 - ，2-氯 - ，2-羟基 - 和2-烷氧基-1-链烷醇的制备酸和2-烷氧基羧酸或其酸衍生物，原子序数为22至83的至少一种另外的元素不是钯或铂。

3. 发明申请

US20070142648A1 Hydrogenation method for producing optically active alcohols or carboxylic acids 审中-公开
标题翻译：用于制备光学活性醇或羧酸的氢化方法
公开(公告)号：US20070142648A1
公开(公告)日：2007-06-21
申请号：US10588948
申请日：2005-02-08
申请人： Heiko Urtel , Markus Rosch , Andrea Haunert
发明人： Heiko Urtel , Markus Rosch , Andrea Haunert
IPC分类号： C07D305/12 , C07D307/02 , C07D207/04 , C07C29/14
CPC分类号： C07C29/149 , C07B41/02 , C07B53/00 , C07B2200/07 , C07C213/00 , C07D307/33 , C07C215/08 , C07C31/22 , C07C31/207 , C07C31/205 , C07C31/36 , C07C31/20 , C07C31/12
摘要： The present invention relates to a process for preparing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxy carboxylic acids having from 3 to 25 carbon atoms or their acid derivatives or cyclization products by hydrogenating the correspondingly substituted optically active mono- or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active component comprises a noble metal selected from the group of the metals Pt, Pd, Rh, Ir, Ag, Au and at least one further element selected from the group of the elements: Sn, Ge, Mo, W, Ti, Zr, V, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Pb, Bi, Cr, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu.
摘要翻译：本发明涉及通过氢化制备光学活性羟基，烷氧基 - ，氨基 - ，烷基 - ，芳基 - 或氯取代的醇或具有3至25个碳原子的羟基羧酸或其酸衍生物或环化产物的方法相应地取代的光学活性单羧酸或二羧酸或其酸衍生物在催化剂存在下，其活性组分包括选自金属Pt，Pd，Rh，Ir，Ag，Au的贵金属和至少一种元素选自Sn，Ge，Mo，W，Ti，Zr，V，Mn，Fe，Co，Ni，Cu，Zn，Ga，In，Pb，Bi，Cr，Ce，Pr，Nd ，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Lu。

4. 发明申请

US20130310616A1 PROCESS FOR SEPARATION OF WATER FROM PYROLYSIS GASOLINE 有权
标题翻译：从热解汽油中分离水的方法
公开(公告)号：US20130310616A1
公开(公告)日：2013-11-21
申请号：US13983319
申请日：2012-01-30
申请人： Dirk Neumann , Andreas Bode , Daniel Pfeiffer , Matthias Hinrichs , Keshav Ruthiya , Marco Bosch , Andrea Haunert
发明人： Dirk Neumann , Andreas Bode , Daniel Pfeiffer , Matthias Hinrichs , Keshav Ruthiya , Marco Bosch , Andrea Haunert
IPC分类号： C10G33/06
CPC分类号： C10G33/06 , B01D17/0208 , B01D17/0211 , B01D17/0217 , B01D17/045 , C10G9/00 , C10G45/34 , C10G69/06 , C10G2400/02
摘要： A process for separating water from pyrolysis gasoline obtained from a steam cracking step uses a coalescer for the water separation. And a device comprises a coalescer for water separation from pyrolysis gasoline.
摘要翻译：从蒸汽裂解步骤获得的从裂解汽油中分离水的方法使用聚结器进行水分离。并且装置包括用于与热解汽油水分离的聚结器。

5. 发明申请

US20100056364A1 CATALYST AND PROCESS FOR HYDROGENATING CARBONYL COMPOUNDS 有权
标题翻译：催化剂和加氢处理碳化合物
公开(公告)号：US20100056364A1
公开(公告)日：2010-03-04
申请号：US12608125
申请日：2009-10-29
申请人： Sylvia HUBER-DIRR , Michael Hesse , Andrea Haunert , Henrik Junicke
发明人： Sylvia HUBER-DIRR , Michael Hesse , Andrea Haunert , Henrik Junicke
IPC分类号： B01J21/18
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.
摘要翻译：氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在成型制品存在下氢化，所述成型制品包含（i）包含氧化铜，氧化铝和氧化镧的氧化物质和（ii ）粉末状金属铜，铜薄片，水泥粉末，石墨或其混合物。

6. 发明申请

US20090043102A1 METHOD FOR PRODUCING HETEROAROMATIC ALCOHOLS 审中-公开
标题翻译：生产异构醇的方法
公开(公告)号：US20090043102A1
公开(公告)日：2009-02-12
申请号：US12063316
申请日：2006-08-02
申请人： Nils Bottke , Andrea Haunert
发明人： Nils Bottke , Andrea Haunert
IPC分类号： C07D213/62
CPC分类号： C07D213/30
摘要： A process for preparing heteroaromatic alcohols by catalytically hydrogenating heteroaromatic carboxylic acids or esters thereof by hydrogenating with hydrogen in the presence of a ruthenium-phosphine complex in an organic solvent.
摘要翻译：通过在有机溶剂中在钌 - 膦配合物的存在下用氢气氢化杂芳族羧酸或其酯来制备杂芳族醇的方法。

7. 发明申请

US20080299390A1 Moulded Catalyst Bodies and Method for Hydrogenation of Carbonyl Compounds 有权
标题翻译：成型催化剂体和羰基化合物氢化方法
公开(公告)号：US20080299390A1
公开(公告)日：2008-12-04
申请号：US11571766
申请日：2005-07-07
申请人： Christophe Houssin , Henrik Junicke , Andrea Haunert
发明人： Christophe Houssin , Henrik Junicke , Andrea Haunert
IPC分类号： B32B1/00 , C07C51/36 , C07C69/44 , C07D315/00
CPC分类号： B01J23/83 , B01J23/002 , B01J23/72 , B01J23/85 , B01J23/885 , B01J23/888 , B01J37/0009 , B01J37/03 , B01J2523/00 , C07C29/149 , Y10T428/2982 , C07C31/20 , B01J2523/17 , B01J2523/27 , B01J2523/31 , B01J2523/3706
摘要： The invention relates to a method for hydrogenation of an organic compound comprising at least one carbonyl group, whereby the organic compound is brought into contact with a moulded body in the presence of hydrogen. Said body may be produced by a method in which (i) an oxidic material is prepared, comprising copper oxide, aluminium oxide, and at least one oxide of lanthanum, tungsten, molybdenum, titanium, or zirconium, followed by (ii) addition of powdered metallic copper, copper platelets, powdered cement, graphite, mixtures or a mixture thereof with graphite to the oxidic material and (iii) moulding the mixture from (ii) to give a moulded body, characterised in that the moulded body is in the form of catalyst tablets or catalyst extrudates with a diameter d and/or height h
摘要翻译：本发明涉及一种包含至少一个羰基的有机化合物的氢化方法，其中有机化合物在氢气存在下与成型体接触。所述体可以通过以下方法制备，其中（i）制备氧化物材料，其包含氧化铜，氧化铝和至少一种镧，钨，钼，钛或锆的氧化物，然后加入（ⅱ）粉末状金属铜，铜片，粉末水泥，石墨，与石墨的混合物或其混合物与氧化物材料，（iii）从（ii）模塑混合物得到成型体，其特征在于成型体为具有直径d和/或高度h <2.5mm的催化剂片剂或催化剂挤出物，直径d <2.5mm的催化剂珠粒或具有泡孔直径rz <2.5mm的催化剂蜂窝体。

8. 发明授权

US08080588B2 Surfactants for tertiary mineral oil extraction based on branched alcohols 有权
标题翻译：基于支链醇的三级矿物油萃取用表面活性剂
公开(公告)号：US08080588B2
公开(公告)日：2011-12-20
申请号：US12420248
申请日：2009-04-08
申请人： Christian Bittner , Günter Oetter , Ulrich Steinbrenner , Marcus Guzmann , Andrea Haunert , Rainer Papp , Jens Rudolph
发明人： Christian Bittner , Günter Oetter , Ulrich Steinbrenner , Marcus Guzmann , Andrea Haunert , Rainer Papp , Jens Rudolph
IPC分类号： B01F17/04 , B01F17/42 , C09K8/584
CPC分类号： B01F17/0021 , B01F17/0042 , B01F17/0057 , C09K8/584
摘要： Surfactants of the general formula R1—X where R1 is an aliphatic C17H35-alkyl radical and X is a hydrophilic group, and the mean degree of branching of the R1 radical is from 2.8 to 3.7. Mixtures which comprise such surfactants and the use of such surfactants and of mixtures thereof for tertiary mineral oil extraction.
摘要翻译：通式R1-X的表面活性剂，其中R1是脂族C17H35-烷基，X是亲水基团，R1基团的平均支化度为2.8-3.7。包含这种表面活性剂的混合物以及这些表面活性剂及其混合物用于三次矿物油提取的用途。

9. 发明申请

US20100298460A1 PROCESS FOR PREPARING POLYETHER ALCOHOLS 有权
标题翻译：制备聚醚醇的方法
公开(公告)号：US20100298460A1
公开(公告)日：2010-11-25
申请号：US12864425
申请日：2009-01-26
申请人： Darijo Mijolovic , Andrea Haunert , Andreas Kunst , Stephan Bauer , Qiang Miao , Berend Eling
发明人： Darijo Mijolovic , Andrea Haunert , Andreas Kunst , Stephan Bauer , Qiang Miao , Berend Eling
IPC分类号： C08J9/22 , C07C41/00 , C08G18/32
CPC分类号： C08G67/02 , C08G65/2609 , C08G65/2663
摘要： The invention relates to a process for preparing polyether alcohols, which comprises the steps a) reaction of an unsaturated natural oil or fat with a mixture of carbon monoxide and hydrogen, b) reaction of the mixture from step a) with hydrogen, c) reaction of the product from step b) with an alkylene oxide in the presence of a catalyst.
摘要翻译：本发明涉及一种制备聚醚醇的方法，其包括步骤a）使不饱和天然油或脂肪与一氧化碳和氢气的混合物反应，b）步骤a）的混合物与氢的反应，c）反应的来自步骤b）的产物与烯化氧在催化剂存在下反应。

10. 发明授权

US07449609B2 Method for production of 1,6-hexanediol with a purity in excess of 99.5% 失效
标题翻译：制备纯度超过99.5％的1,6-己二醇的方法
公开(公告)号：US07449609B2
公开(公告)日：2008-11-11
申请号：US10569980
申请日：2005-07-07
申请人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
发明人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
IPC分类号： C07C29/149
CPC分类号： C07C29/145 , C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要翻译：本发明提供了一种通过以下方式制备1,6-己二醇的方法：通过以下方法将氢化己二酸二烷基酯，6-羟基己酸烷基酯，1,4-环己二酮和4-羟基环己烷-1-酮作为包含杂质的酯混合物，在第一蒸馏阶段（醇去除）中的过量醇和低锅炉的b），b）在第二蒸馏阶段中将底部产物分离成基本上不含1,4-环己烷二醇的酯馏分和至少包含大部分1,4-环己烷二醇，c）催化氢化基本上不含1,4-环己二醇的酯馏分（酯氢化）和d）在纯化蒸馏阶段，以一种方式从氢化流出物中获得1,6-己二醇本身已知，其包括在阶段a）和/或阶段b）之前选择性地氢化酯混合物（纯化氢化）。

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