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1. 发明授权

US07026499B2 Linear carboxy-functional organosiloxanyl derivatives and the use thereof for the treatment of the surfaces of leather 失效
标题翻译：线性羧基官能的有机硅氧烷衍生物及其用于处理皮革表面的用途
公开(公告)号：US07026499B2
公开(公告)日：2006-04-11
申请号：US10772166
申请日：2004-02-02
申请人： Heike Buskies , Manfred Krakenberg , Sascha Oestreich , Stefan Stadtmüller
发明人： Heike Buskies , Manfred Krakenberg , Sascha Oestreich , Stefan Stadtmüller
IPC分类号： C07F7/18 , C07F7/08 , C07F7/02
CPC分类号： C08G77/46 , C08G77/38 , C14C9/00
摘要： The invention relates to linear carboxy-functional organosiloxane compounds of the general formula (I) in which a is from 1 to 200, R1 are identical or different aliphatic or aromatic hydrocarbon radicals and R2 is —(Y)[O(C2H4-b(R3)bO)c(CdH2dO)e]fX, and the use thereof for the treatment of the surface of leather.
摘要翻译：本发明涉及通式（I）的线性羧基官能的有机硅氧烷化合物，其中a为1至200，R 1是相同或不同的脂族或芳族烃基和R 2 是 - （Y）[O（C 2 H 4-b）（R 3）3

2. 发明授权

US06630132B2 UV-light-absorbing quaternary polysiloxanes 有权
标题翻译：紫外线吸收四元聚硅氧烷
公开(公告)号：US06630132B2
公开(公告)日：2003-10-07
申请号：US10217000
申请日：2002-08-12
申请人： Michael Fender , Manfred Krakenberg , Holger Leidreiter , Sascha Oestreich
发明人： Michael Fender , Manfred Krakenberg , Holger Leidreiter , Sascha Oestreich
IPC分类号： A61K742
CPC分类号： A61K8/898 , A61K2800/57 , A61Q17/04 , C08G77/045 , C08G77/388
摘要： The present invention relates to UV-light-absorbing quaternary polysiloxanes that exert a care effect on natural or synthetic fibers, exhibit high substantivity to fibers, and offer protection against damage caused by UV-light. The UV-light-absorbing quaternary compounds can be used in formulations for textile care products and cosmetic, including skin and hair, products.
摘要翻译：本发明涉及对天然或合成纤维发挥保护作用的紫外光吸收性四元聚硅氧烷，对纤维表现出高亲和性，并且提供防止由紫外光引起的损伤的保护。紫外光吸收季铵化合物可用于纺织品护理产品和化妆品的制剂，包括皮肤和头发，产品。

3. 发明授权

US06617391B2 Linear polydialkylorganosiloxanes having polyoxyalkylene and amino-functional groups which additionally have terminal alkoxy groups 有权
公开(公告)号：US06617391B2
公开(公告)日：2003-09-09
申请号：US09887184
申请日：2001-06-21
申请人： Manfred Krakenberg , Holger Leidreiter , Sascha Oestreich , Stefan Stadtmuller , Akfred Walter
发明人： Manfred Krakenberg , Holger Leidreiter , Sascha Oestreich , Stefan Stadtmuller , Akfred Walter
IPC分类号： C08L8312
CPC分类号： C08L83/08 , C08G77/388
摘要： The present invention relates to linear polyalkylorgano-siloxanes having polyoxyalkylene and amino-functional groups which additionally have terminal alkoxy groups, and to the preparation and use thereof.

4. 发明授权

US4891166A Diquaternary polysiloxanes, their synthesis and use in cosmetic preparations 失效
标题翻译：二季用聚硅氧烷，它们的合成和用于化妆品制剂
公开(公告)号：US4891166A
公开(公告)日：1990-01-02
申请号：US348089
申请日：1989-05-03
申请人： Dietmar Schaefer , Manfred Krakenberg
发明人： Dietmar Schaefer , Manfred Krakenberg
IPC分类号： A61K8/893 , A61K8/898 , A61Q5/02 , A61Q5/12 , C08G77/388
CPC分类号： A61Q5/02 , A61K8/898 , A61Q5/12 , C08G77/388
摘要： Compounds of the general formula ##STR1## are disclosed in which Z is ##STR2## R.sup.1, R.sup.2, R.sup.3 are alkyl groups with 1 to 22 carbon atoms or alkenyl groups with 2 to 22 carbon atoms, at least one of the R.sup.1, R.sup.2 or R.sup.3 groups having at least 10 carbon atoms,R.sup.4, R.sup.5, R.sup.7 are alkyl groups with 1 to 22 carbon atoms or alkenyl groups with 2 to 22 carbon atoms,R.sup.6 is --O-- or the NR.sup.8 group, R.sup.8 being an alkyl or hydroxyalkyl group with 1 to 4 carbon atoms or a hydrogen group,x is 2 to 4,M is a bivalent hydrocarbon group with at least 4 carbon atoms, which has a hydroxyl group and may be interrupted by an oxygen atom,n is a number from 0 to 200, andX.crclbar. is an inorganic or organic anion.The compounds can be prepared by reacting compounds of the general formula ##STR3## in which Q is a hydrocarbon group with at least 4 carbon atoms, which has an epoxide group and may be interrupted by an oxygen atom, andn is as defined above,with tertiary amines of the general formula ##STR4## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and x are defined as above, in such quantitative ratios that at least one tertiary amino group corresponds to each epoxide group. The reaction is carried out in the presence of one acid equivalent or HX, based on the nitrogen atom to be quaternized, and at temperatures of 40.degree. to 120.degree. C.The compounds are useful in cosmetic preparations, especially in preparations for the care of the hair. They improve the combability of the hair and, at the same time, improve the gloss and give permanence to the hairstyle.
摘要翻译：公开了通式“IMAGE”的化合物，其中Z为R 1，R 2，R 3为具有1至22个碳原子的烷基或具有2至22个碳原子的烯基，R 1，R 2或具有至少10个碳原子的R 3基团，R 4，R 5，R 7是具有1至22个碳原子的烷基或具有2至22个碳原子的烯基，R 6是-O-或NR 8基，R 8是烷基或羟烷基具有1至4个碳原子或氢原子，x为2至4，M为具有至少4个碳原子的二价烃基，其具有羟基并且可能被氧原子间隔，n为0 至200，X（ - ）是无机或有机阴离子。化合物可以通过使具有至少4个碳原子的通式为“IMAGE”的化合物与具有环氧基且可以被氧原子间隔的至少4个碳原子反应而制备，n如上定义，其中R1，R2，R3，R4，R5，R6，R7和x如上定义的具有通式为“IMAGE”的叔胺，其定量比例为至少一个叔氨基对应于每个环氧基。反应在一个酸当量或基于待季氮的氮原子存在下进行，并在40℃至120℃的温度下进行。化合物可用于化妆品制剂中，特别是用于护理头发。它们提高了头发的梳理性，并同时提高了光泽，赋予了发型的永恒性。

5. 发明授权

US06489498B2 Silanes with hydrophilic groups, their synthesis and use as surfactants in aqueous media 失效
标题翻译：具有亲水基团的硅烷，它们的合成和用作水性介质中的表面活性剂
公开(公告)号：US06489498B2
公开(公告)日：2002-12-03
申请号：US09818419
申请日：2001-03-27
申请人： Klaus-Dieter Klein , Wilfried Knott , Götz Koerner , Manfred Krakenberg
发明人： Klaus-Dieter Klein , Wilfried Knott , Götz Koerner , Manfred Krakenberg
IPC分类号： C07F708
CPC分类号： B01F17/0071 , C07F7/081
摘要： Silanes of the general formula are prepared, wherein R1, R2 and R3 in the molecule are the same or different and represent aliphatic or aromatic hydrocarbon groups, R4 is a divalent hydrocarbon group with 4 to 12 carbon atoms and a lateral hydroxyl group, wherein the hydrocarbon group can be interrupted by an ether oxygen, R5 is a hydrophilic, ionic group. A method for synthesizing these compounds is described. The silanes greatly lower the surface tension of aqueous solutions, the surface tension being reduced to values of about 23 mN/m. The silanes are biologically degradable and have pronounced surfactant properties.
摘要翻译：制备通式的硅烷，其中分子中的R 1，R 2和R 3相同或不同并且表示脂族或芳族烃基，R 4是具有4至12个碳原子和侧羟基的二价烃基，其中烃组可以被醚氧中断，R5是亲水的离子基团。对这些化合物的合成方法进行说明。硅烷大大降低了水溶液的表面张力，表面张力降低到约23mN / m。硅烷是生物可降解的并且具有显着的表面活性剂性质。

6. 发明授权

US06242554B1 Polysiloxanes having polyether quat functions 有权
标题翻译：具有聚醚四官能团的聚硅氧烷
公开(公告)号：US06242554B1
公开(公告)日：2001-06-05
申请号：US09439409
申请日：1999-11-11
申请人： Stephan Busch , Manfred Krakenberg , Peter Lersch , Stephan Stadtmüller
发明人： Stephan Busch , Manfred Krakenberg , Peter Lersch , Stephan Stadtmüller
IPC分类号： C08G7726
CPC分类号： D06M15/647 , C08G77/388 , C08G77/46 , D06M15/6436 , Y10S8/01 , Y10T428/2915 , Y10T428/2962
摘要： The invention relates to novel polyether-quaternary organosiloxanyl derivatives, to the preparation of these compounds and to their use in formulations for improving the surface properties of fabrics and fibers.
摘要翻译：本发明涉及新型聚醚 - 季有机硅氧烷衍生物，用于制备这些化合物及其用于改善织物和纤维表面性能的配方中。

7. 发明授权

US4833225A Polyquaternary polysiloxane polymers, their synthesis and use in cosmetic preparations 失效
标题翻译：聚季铵盐聚硅氧烷聚合物，它们在化妆品中的合成和应用
公开(公告)号：US4833225A
公开(公告)日：1989-05-23
申请号：US154964
申请日：1988-02-10
申请人： Dietmar Schaefer , Manfred Krakenberg
发明人： Dietmar Schaefer , Manfred Krakenberg
IPC分类号： A61K8/893 , A61K8/898 , A61Q5/02 , A61Q5/12 , C08G77/388 , C08G77/54
CPC分类号： A61Q5/12 , A61K8/898 , A61Q5/02 , C08G77/388 , C08G77/54
摘要： Polyquaternary polysiloxane polymers are disclosed comprising repeating units of ##STR1## wherein X is a bivalent hydrocarbon group with at least 4 carbon atoms, which has a hydroxyl group and may be interrupted by an oxygen atom,Y is a bivalent hydrocarbon group with at least 2 carbon atoms, which has a hydroxyl group and which may be interrupted by an oxygen or nitrogen atom,R.sup.1, R.sup.2, R.sup.3, R.sup.4 are the same or different and may be alkyl groups with at least 1 to 4 carbon atoms or benzyl groups or in which R.sup.1 and R.sup.3 or R.sup.2 and R.sup.4 may be components of a bridging alkylene group,A.crclbar. is an inorganic or organic anion,n=5 to 200m is a whole number.gtoreq.1.The compounds may be synthesized by an addition reaction between .alpha.,.omega.-hydrogenpolysiloxane of the formula ##STR2## and epoxides which have a terminal olefinic bond and reacting the product obtained with a diamine of the general formula ##STR3## The polymers may be used in cosmetic preparations, especially in hair cosmetics. They improve the ability to comb the hair wet and dry, increase the gloss and reduce the electrostatic charge on the treated hair.
摘要翻译：公开了包含重复单元的聚季铵盐聚硅氧烷聚合物，其中X是具有至少4个碳原子的二价烃基，其具有羟基并且可以被氧原子间隔，Y是具有至少2个的二价烃基碳原子，其具有羟基并且可被氧或氮原子间隔，R 1，R 2，R 3，R 4相同或不同，并且可以是具有至少1至4个碳原子的烷基或苄基或在其中R 1和R 3或R 2和R 4可以是桥连亚烷基的组分，A（ - ）是无机或有机阴离子，n = 5至200μm是整数> / = 1。该化合物可以通过下式的α，ω-氢聚硅氧烷与具有末端烯属键的环氧化物之间的加成反应合成，并使所得产物与通式为的二胺反应。聚合物可以用于化妆品，特别是头发化妆品。它们可以提高梳理头发的干燥和干燥能力，增加光泽度并减少被处理毛发上的静电电荷。

8. 发明授权

US06255511B1 Silanes with hydrophilic groups, their synthesis and use as surfactants in aqueous media 失效
标题翻译：具有亲水基团的硅烷，它们的合成和用作水性介质中的表面活性剂
公开(公告)号：US06255511B1
公开(公告)日：2001-07-03
申请号：US08301372
申请日：1994-09-06
申请人： Klaus-Dieter Klein , Wilfried Knott , Götz Koerner , Manfred Krakenberg
发明人： Klaus-Dieter Klein , Wilfried Knott , Götz Koerner , Manfred Krakenberg
IPC分类号： C07F708
CPC分类号： B01F17/0071 , C07F7/081
摘要： Silanes of the general formula are prepared, wherein R1, R2 and R3 in the molecule are the same or different and represent aliphatic or aromatic hydrocarbon groups, R4 is a divalent hydrocarbon group with 4 to 12 carbon atoms and a lateral hydroxyl group, wherein the hydrocarbon group can be interrupted by an ether oxygen, R5 is a hydrophilic, ionic group. A method for synthesizing these compounds is described. The silanes greatly lower the surface tension or aqueous solutions, the surface tension being reduced to values of about 23 mN/m. The silanes are biologically degradable and have pronounced surfactant properties.
摘要翻译：制备通式的硅烷，其中分子中的R 1，R 2和R 3相同或不同并且表示脂族或芳族烃基，R 4是具有4至12个碳原子和侧羟基的二价烃基，其中烃组可以被醚氧中断，R5是亲水的离子基团。对这些化合物的合成方法进行说明。硅烷大大降低了表面张力或水溶液，表面张力降低到约23mN / m。硅烷是生物可降解的并且具有显着的表面活性剂性质。

9. 发明授权

US4434008A Substantive preparation material for yarns or plied yarns 失效
标题翻译：用于纱线或合股纱线的实体制备材料
公开(公告)号：US4434008A
公开(公告)日：1984-02-28
申请号：US361462
申请日：1982-03-24
申请人： Heinz Dumm , G/o/ tz Koerner , Manfred Krakenberg , Hans Rott , G/u/ nter Schmidt
发明人： Heinz Dumm , G/o/ tz Koerner , Manfred Krakenberg , Hans Rott , G/u/ nter Schmidt
IPC分类号： C08L91/06 , C09D191/08 , D06M13/02 , D06M13/188 , D06M13/352 , D06M15/643 , C09D3/393 , C09G1/12
CPC分类号： D06M15/643 , C08L91/06 , D06M7/00 , D06M2200/40
摘要： Materials for substantively preparing yarns or plied yarns, especially sewing threads and preferably those of polyester, in the form of an oil/water dispersion are disclosed. The materials contain 5 to 80 weight percent of silicone oil of a viscosity of 500 to 50,000 mm.sup.2 /sec at 25.degree. C., 10 to 80 weight percent of wax with a melting point not less than 40.degree. C., 1 to 10 weight percent of fatty acids with 6 to 22 carbon atoms, 0.4 to 12 weight percent of cationic imidazolinium salts and 0 to 10 weight percent of ethoxylated fatty amines, dissolved or dispersed in water, the sum of the components having to add up to 100 weight percent. The production of this preparation is also disclosed. The inventive preparation materials have a good and uniform substantivity and bring about uniform reduction in friction over a long length of yarn and for different speeds of the running thread. They ensure little abrasion in the further processing of the yarns, especially during sewing, and at the same time, provide a high measure of antistatic effect. The breaking strength of the yarns or plied yarns is not significantly decreased.
摘要翻译：公开了用于实质上制备纱线或合股纱线的材料，特别是油/水分散体形式的缝合线，优选聚酯的缝合线。该材料含有5至80重量％的25℃下粘度为500至50,000mm 2 /秒的硅油，10至80重量％的熔点不低于40℃的蜡，1至10重量％具有6至22个碳原子的脂肪酸百分比，溶解或分散在水中的阳离子咪唑啉鎓盐0.4至12重量％和乙氧基化脂肪胺0至10重量％，所述组分的总和必须加至100重量％。还公开了该制剂的生产。本发明的制备材料具有良好且均匀的亲和性，并且在长长度的纱线上以及对于不同速度的运行螺纹产生均匀的摩擦力降低。它们确保纱线的进一步加工中的磨损很小，特别是在缝制期间，同时提供高度的抗静电效果。纱线或合股纱线的断裂强度不会明显降低。

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