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1. 发明授权

US5986021A Process for manufacturing LLDPE polymers 失效
标题翻译：制造LLDPE聚合物的方法
公开(公告)号：US5986021A
公开(公告)日：1999-11-16
申请号：US930696
申请日：1998-02-10
申请人： Harri Hokkanen , Hannu Salminen , Kalle Kallio , Hilkka Knuuttila , Ari Palmroos
发明人： Harri Hokkanen , Hannu Salminen , Kalle Kallio , Hilkka Knuuttila , Ari Palmroos
IPC分类号： C08F2/00 , C08F2/06 , C08F2/34 , C08F4/642 , C08F210/00 , C08F210/02 , C08F210/16 , C08G85/00
CPC分类号： C08F210/16 , Y10S526/904 , Y10S526/943
摘要： Process for manufacturing ethylene copolymers by polymerizing ethylene and a minor amount of C.sub.3 -C.sub.6 alphaolefins in particle form in slurry reactor in the presence of an ethylene polymerizing catalyst. According to the invention the polymerization is carried out in propane diluent by using a metallocene catalyst activated with an alumoxane compound.
摘要翻译： PCT No.PCT / FI96 / 00240 Sec。 371日期1998年2月10日 102（e）1998年2月10日PCT 1996年4月30日PCT PCT。第WO96 / 34895号公报日期1996年11月7日在乙烯聚合催化剂存在下，通过在淤浆反应器中聚合乙烯和少量C3-C6α-烯烃制备乙烯共聚物的方法。根据本发明，通过使用由铝氧烷化合物活化的茂金属催化剂在丙烷稀释剂中进行聚合。

2. 发明授权

US06632884B1 Polymer composition, a process for the production thereof and films prepared thereof 有权
标题翻译：聚合物组合物，其制备方法和其制备的膜
公开(公告)号：US06632884B1
公开(公告)日：2003-10-14
申请号：US09857901
申请日：2001-10-01
申请人： Merete Skar , Ole Jan Myhre , Arja Lehtinen , Harri Hokkanen , Hilkka Knuuttila , Kalle Kallio , Esa Kinnunen , Eija Lappi
发明人： Merete Skar , Ole Jan Myhre , Arja Lehtinen , Harri Hokkanen , Hilkka Knuuttila , Kalle Kallio , Esa Kinnunen , Eija Lappi
IPC分类号： C08F2002
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F2/001 , C08F4/65927 , C08F2500/12 , C08F2500/07 , C08F2500/26 , C08F210/08
摘要： This invention concerns process for producing polyethylene compositions, films prepared thereof and process for the preparation of the films. The process comprises subjecting ethylene, optionally hydrogen and comonomers to polymerization or copolymerization reactions in a multistage polymerization. At least one polymerization stage is conducted essentially in the absence of hydrogen. The polymerization reactions are carried out in the presence of a single-site catalyst capable of forming a composition comprising a low molecular weight component with MFR2 of at least 10 g/10 min and a density higher than the density of the composition and a high molecular weight component. The melt flow rate of the composition is in the range MFR2=0.1-5.0 g/10 min and the density of the composition is 915-960 kg/m3. The invention makes it possible to produce polyethylene compositions for manufacturing films with a good balance between optical and mechanical properties.
摘要翻译：本发明涉及生产聚乙烯组合物的方法，其制备的薄膜及其制备方法。该方法包括使乙烯，任选的氢和共聚单体在多级聚合中进行聚合或共聚反应。基本上在不存在氢的情况下进行至少一个聚合阶段。聚合反应在能够形成包含至少10g / 10分钟的MFR低于2分子量组分的组合物的单中心催化剂的存在下进行并且密度高于组合物的密度和高分子量组分。组合物的熔体流动速率在MFR 2 = 0.1-5.0g / 10min的范围内，组合物的密度为915-960kg / m 2 <3 。本发明使得可以生产用于制造具有光学和机械性能之间良好平衡的膜的聚乙烯组合物

3. 发明授权

US06451725B1 Method for preparing catalyst components 失效
标题翻译：制备催化剂组分的方法
公开(公告)号：US06451725B1
公开(公告)日：2002-09-17
申请号：US09489662
申请日：2000-01-21
申请人： Hilkka Knuuttila , Harri Hokkanen , Eija Salo
发明人： Hilkka Knuuttila , Harri Hokkanen , Eija Salo
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , Y10S526/907 , Y10S526/943 , C08F4/65916 , C08F2500/12 , C08F2500/03 , C08F210/14
摘要： Method for preparing a catalyst component for homo or copolymerization of olefins, said catalyst component comprising at least one metallocene compound on porous inorganic carrier, wherein said metallocene compound is mixed as pure compound in the absence of solvents with said carrier at a temperature which is at least 50° C. but below the vaporization temperature of the metallocene compound in reactor conditions for a sufficient time to obtain said catalyst component having said metallocene evenly distributed onto carrier particles.
摘要翻译：制备用于烯烃均相或共聚的催化剂组分的方法，所述催化剂组分在多孔无机载体上包含至少一种茂金属化合物，其中所述茂金属化合物在不存在溶剂的条件下与所述载体在温度为至少50℃，但低于茂金属化合物在反应器条件下的蒸发温度足够长的时间，以获得所述茂金属均匀分布在载体颗粒上的催化剂组分。

4. 发明授权

US6143844A Catalyst for olefin polymerization and a method for the manufacture thereof 失效
标题翻译：烯烃聚合用催化剂及其制造方法
公开(公告)号：US6143844A
公开(公告)日：2000-11-07
申请号：US58806
申请日：1998-04-13
申请人： Harri Hokkanen , Hilkka Knuuttila , Eeva-Liisa Lakomaa , Pekka Sormunen
发明人： Harri Hokkanen , Hilkka Knuuttila , Eeva-Liisa Lakomaa , Pekka Sormunen
IPC分类号： C08F4/02 , B01J31/22 , B01J37/02 , C08F4/619 , C08F4/6192 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F10/00 , C08F10/02 , C08F110/02 , C08F4/44
CPC分类号： B01J31/143 , B01J31/1616 , B01J31/2295 , B01J31/38 , B01J37/0238 , C08F10/00 , C08F10/02 , C08F4/65912 , B01J21/08 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , C08F110/02 , C08F2410/03 , C08F4/6192 , C08F4/65908 , C08F4/6592 , C08F4/65925 , Y10S526/901 , Y10S526/907 , Y10S526/943
摘要： Provided are heterogeneous catalysts for homo- and copolymerization of olefins as well as a method for preparing these catalysts, which comprise at least one metallocene compound of a Group 4A, 5A or 6A (Hubbard) transition metal on a solid inorganic support. The method comprises the steps of vaporizing the metallocene compound, treating the support material with the vaporized metallocene compound at a temperature which is sufficiently high to keep the metallocene compound in the vaporous state, contacting the support material with an amount of the vaporized metallocene compound which is sufficient to allow for a reaction between the metallocene compound and at least a substantial part of the available surface sites capable of reacting therewith, removing the rest of the metallocene compound not bound to the support, and optionally treating the product thus obtained with an activating agent. The catalysts are active even if very low amounts of activator agents, such as alumoxane, are used. Furthermore, the polymerization performance of the catalysts can be regulated during the preparation of the catalysts. Thus, by using different support pretreatment temperatures, or by using two or more different metallocenes, and by altering the order in which they are added on the support, it is possible to control and regulate the activity of the catalysts and the polymer properties, such as molecular weight and molecular weight distribution.
摘要翻译：提供了用于烯烃均聚和共聚的非均相催化剂以及制备这些催化剂的方法，其包含至少一种在固体无机载体上的4A，5A或6A族（Hubbard）过渡金属茂金属化合物。该方法包括以下步骤：气化金属茂化合物，在足够高的温度下用汽化金属茂化合物处理载体材料以保持茂金属化合物处于气态，使载体材料与一定量的气化茂金属化合物接触，足以允许茂金属化合物与能够反应的至少大部分可用表面位点之间的反应，除去未结合到载体上的其余的金属茂化合物，以及任选地用活化的方法处理由此获得的产物代理商即使使用非常少量的活化剂如铝氧烷，催化剂也是有活性的。此外，可以在制备催化剂期间调节催化剂的聚合性能。因此，通过使用不同的载体预处理温度，或通过使用两种或更多种不同的金属茂，并通过改变它们在载体上的添加顺序，可以控制和调节催化剂的活性和聚合物性质，例如作为分子量和分子量分布。

5. 发明授权

US06500780B1 Method for preparing heterogeneous catalysts of desired metal content 失效
标题翻译：制备所需金属含量的非均相催化剂的方法
公开(公告)号：US06500780B1
公开(公告)日：2002-12-31
申请号：US08840274
申请日：1997-04-14
申请人： Tuomo Suntola , Suvi Haukka , Arla Kytökivi , Eeva-Liisa Lakomaa , Marina Lindblad , Jukka Hietala , Harri Hokkanen , Hilkka Knuuttila , Pekka Knuuttila , Outi Krause , Lars Peter Lindfors
发明人： Tuomo Suntola , Suvi Haukka , Arla Kytökivi , Eeva-Liisa Lakomaa , Marina Lindblad , Jukka Hietala , Harri Hokkanen , Hilkka Knuuttila , Pekka Knuuttila , Outi Krause , Lars Peter Lindfors
IPC分类号： B01J3702
CPC分类号： B01J37/0238 , B01J21/063 , B01J23/26 , B01J23/30
摘要： The present invention concerns a method for preparing heterogeneous catalysts. According to the method, preparation is carried out under such process conditions in which the bonding of compounds from the gas phase onto the surface of a support material is primarily determined by the properties of the support surface. The constituents contained in the reagent are then selectively bonded to the bonding sites of the support material surface, thus forming stable surface bonds. According to the invention, the number of surface-bond sites available for preparing a stable product with surface bonds is controlled by varying the reaction temperature and/or selecting a suitable reagent. The invention makes it possible to control the metal content of the end product at a predetermined level.
摘要翻译：本发明涉及一种制备非均相催化剂的方法。根据该方法，在这样的工艺条件下进行制备，其中化合物从气相到载体材料的表面上的键合主要由支撑体表面的性质决定。然后将包含在试剂中的组分选择性地结合到载体材料表面的结合位点，从而形成稳定的表面键。根据本发明，通过改变反应温度和/或选择合适的试剂来控制可用于制备具有表面键的稳定产物的表面键合位点的数目。本发明使得能够将最终产品的金属含量控制在预定水平。

6. 发明授权

US5767032A Catalyst for olefin polymerization and a method for the manufacture thereof 失效
标题翻译：烯烃聚合用催化剂及其制造方法
公开(公告)号：US5767032A
公开(公告)日：1998-06-16
申请号：US905799
申请日：1997-08-12
申请人： Harri Hokkanen , Hilkka Knuuttila , Eeva-Liisa Lakomaa , Pekka Sormunen
发明人： Harri Hokkanen , Hilkka Knuuttila , Eeva-Liisa Lakomaa , Pekka Sormunen
IPC分类号： C08F4/02 , B01J31/22 , B01J37/02 , C08F4/619 , C08F4/6192 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： B01J31/143 , B01J31/1616 , B01J31/2295 , B01J31/38 , B01J37/0238 , C08F10/00 , C08F10/02 , C08F4/65912 , B01J21/08 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , C08F110/02 , C08F2410/03 , C08F4/6192 , C08F4/65908 , C08F4/6592 , C08F4/65925 , Y10S526/901 , Y10S526/907 , Y10S526/943
摘要： Provided are heterogeneous catalysts for homo- and copolymerization of olefins as well as a method for preparing these catalysts, which comprise at least one metallocene compound of a Group 4A, 5A or 6A (Hubbard) transition metal on a solid inorganic support. The mtehod comprises the steps of vaporizing the metallocene compound, treating the support material with the vaporized metallocene compound at a temperature which is sufficiently high to keep the metallocene compound in the vaporous state, contacting the support material with an amount of the vaporized metallocene compound which is sufficient to allow for a reaction between the metallocene compound and at least a substantial part of the available surface sites capable of reacting therewith, removing the rest of the metallocene compound not bound to the support, and optionally treating the product thus obtained with an activating agent. The catalysts are active even if very low amounts of activator agents, such as alumoxane, are used. Furthermore, the polymerization performance of the catalysts can be regulated during the preparation of the catalysts. Thus, by using different support pretreatment temperatures, or by using two or more different metallocenes, and by altering the order in which they are added on the support, it is possible to control and regulate the activity of the catalysts and the polymer properties, such as molecular weight and molecular weight distribution.
摘要翻译：提供了用于烯烃均聚和共聚的非均相催化剂以及制备这些催化剂的方法，其包含至少一种在固体无机载体上的4A，5A或6A族（Hubbard）过渡金属茂金属化合物。该方法包括蒸发茂金属化合物的步骤，在足够高的温度下用蒸发的金属茂化合物处理载体材料以保持茂金属化合物处于气态，使载体材料与一定量的汽化金属茂化合物接触，足以允许茂金属化合物与能够反应的至少大部分可用表面位点之间的反应，除去未结合到载体上的其余的金属茂化合物，以及任选地用活化的方法处理由此获得的产物代理商即使使用非常少量的活化剂如铝氧烷，催化剂也是有活性的。此外，可以在制备催化剂期间调节催化剂的聚合性能。因此，通过使用不同的载体预处理温度，或通过使用两种或更多种不同的金属茂，并通过改变它们在载体上的添加顺序，可以控制和调节催化剂的活性和聚合物性质，例如作为分子量和分子量分布。

7. 发明授权

US5880055A Catalyst for polymerization of ethylene 失效
标题翻译：乙烯聚合催化剂
公开(公告)号：US5880055A
公开(公告)日：1999-03-09
申请号：US843610
申请日：1997-04-10
申请人： Hilkka Knuuttila , Pekka Sormunen , Eero Iiskola , Eeva-Liisa Lakomaa , Harri Hokkanen
发明人： Hilkka Knuuttila , Pekka Sormunen , Eero Iiskola , Eeva-Liisa Lakomaa , Harri Hokkanen
IPC分类号： B01J37/02 , C08F4/16 , C08F10/00 , B01J37/00
CPC分类号： C08F10/00 , B01J37/0238
摘要： The present invention concerns heterogeneous catalysts for polymerization of olefins. The catalysts include at least one Group IVa metal compound on a solid inorganic oxidic support. According to the invention the catalysts are prepared by vapourizing at least one solid Group IVa metal halide compound and routing the vapour of the metal halide compound into a reaction chamber, wherein the vapour is reacted with the support at a temperature of about 250.degree. to about 450.degree. C. in order to bind said metal halide compound to said support. Any metal compound not bound to said support as well as any volatile reaction products emanating from the reaction between said metal halide compound and said support are then removed from the reaction chamber in the vapour phase. Optionally, the product obtained is treated with an organic aluminum compound to increase the catalytic activity of said catalyst. The catalysts thus prepared are very well suited for polymerization of ethylene or copolymerization of ethylene with other alpha-olefins, such as propylene, butylene, 4-methyl-1-pentene and hexene. A polymerization process employing the novel catalyst will provide products of the Ultra High Molecular Weight-type (UHMWPE) having very broad MWD.
摘要翻译：本发明涉及用于烯烃聚合的多相催化剂。催化剂包括在固体无机氧化物载体上的至少一种IVa族金属化合物。根据本发明，催化剂是通过将至少一种固体IVa族金属卤化物化合物挥发并将金属卤化物化合物的蒸气引导到反应室中制备的，其中蒸气在约250°至约 450℃，以便将所述金属卤化物化合物结合到所述载体上。然后在气相中从反应室中除去未结合到所述载体上的任何金属化合物以及从所述金属卤化物和所述载体之间的反应产生的任何挥发性反应产物。任选地，将获得的产物用有机铝化合物处理以增加所述催化剂的催化活性。如此制备的催化剂非常适合于乙烯的聚合或乙烯与其它α-烯烃如丙烯，丁烯，4-甲基-1-戊烯和己烯的共聚合。采用新型催化剂的聚合方法将提供具有非常宽MWD的超高分子量型（UHMWPE）产品。

8. 发明授权

US06284849B1 Method of catalyst transitions in olefin polymerizations 失效
标题翻译：烯烃聚合中催化剂转变的方法
公开(公告)号：US06284849B1
公开(公告)日：2001-09-04
申请号：US09142402
申请日：1999-01-11
申请人： Vidar Almquist , Tone Aastad , Ingrid Sorum Melaaen , Harri Hokkanen , Kalle Kallio
发明人： Vidar Almquist , Tone Aastad , Ingrid Sorum Melaaen , Harri Hokkanen , Kalle Kallio
IPC分类号： C08F238
CPC分类号： C08F10/00 , Y10S526/943 , C08F2/42
摘要： A method for transitioning between two different catalysts in olefin polymerizations, a first catalyst and a second catalyst, comprising the steps of: discontinuing the feed of the first catalyst into the polymerization reactor, and introducing the second catalyst into the reactor, wherein the transition is performed between a chromium-based catalyst and a metallocene catalyst.
摘要翻译：一种用于在烯烃聚合中的两种不同催化剂之间转化的方法，第一催化剂和第二催化剂，包括以下步骤：将第一催化剂进料停止进入聚合反应器，并将第二催化剂引入反应器，其中转变为在铬基催化剂和茂金属催化剂之间进行。

9. 发明授权

US06780809B1 Catalyst for the (co)polymerization of ethylene and a method for the preparation thereof 失效
标题翻译：乙烯（共）聚合的催化剂及其制备方法
公开(公告)号：US06780809B1
公开(公告)日：2004-08-24
申请号：US09601652
申请日：2003-05-21
申请人： Arild Follestad , Vidar Almquist , Ulf Palmqvist , Harri Hokkanen
发明人： Arild Follestad , Vidar Almquist , Ulf Palmqvist , Harri Hokkanen
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/63912 , C08F4/63916 , C08F4/63925 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/63904 , C08F4/24 , C08F2500/12 , C08F2500/17 , C08F2500/07 , C08F210/14 , C08F2500/02
摘要： A particulate, modified chromium oxide catalyst for the polymerisation of ethylene or ethylene with &agr;-olefins, comprising: a) a chromium-oxide catalyst, b) a transition metal compound, and c) a catalyst activator. A method for the preparation of the catalyst comprises the steps of: a) subjecting a chromium oxide catalyst precursor, which comprises a chromium oxide compound combined with an inorganic support, to a temperature in the range of from 400 to 950° C. under oxidising conditions, and b) impregnating the obtained chromium catalyst with a catalyst activator and with a transition metal compound which comprises at least one cyclopentadienylic ring bonded to said transition metal and at least ligand selected from the group comprising alkoxy, amido and hydrocarbyl radicals, halogen and hybride bonded to said transition metal, which cyclopentadienylic ring may contain hetero atoms, be unsubstituted or substituted, be bonded to said transition metal through a bridge, and optionally annealed to other substituted or unsubstituted ring structures, and if two cyclopentadienyl rings are present they may be bonded to each other through a bridge, and c) subjecting the thus obtained particulate catalyst to drying conditions. This catalyst is suitable for producing polyethylenes under conditions of continuous feeding of all reactants.
摘要翻译：一种用于乙烯或乙烯与α-烯烃聚合的颗粒状改性氧化铬催化剂，包括：a）氧化铬催化剂，b）过渡金属化合物，和c）催化剂活化剂。制备催化剂的方法包括以下步骤：a）将氧化铬催化剂前体（其包含与无机载体结合的氧化铬化合物）在400-950℃的温度下氧化条件，以及b）用催化剂活化剂和过渡金属化合物浸渍所获得的铬催化剂，所述过渡金属化合物包含至少一个与所述过渡金属键合的环戊二烯基环和至少选自烷氧基，酰胺基和烃基的配体的卤素和杂环结合到所述过渡金属上，该环戊二烯基环可以含有杂原子，是未取代的或被取代的，通过桥键合到所述过渡金属上，并任选地退火至其它取代或未取代的环结构，如果存在两个环戊二烯基环，则它们可以通过桥接物彼此结合，并且c）对由此获得的颗粒催化剂进行处理干燥条件。该催化剂适用于在连续供给所有反应物的条件下生产聚乙烯。

10. 发明授权

US06225423B1 Olefin polymerization catalyst system, producing and using it 有权
标题翻译：烯烃聚合催化剂体系，生产和使用它
公开(公告)号：US06225423B1
公开(公告)日：2001-05-01
申请号：US09101869
申请日：1998-09-21
申请人： Ove S. Andell , Harri Hokkanen , Marja Mustonen
发明人： Ove S. Andell , Harri Hokkanen , Marja Mustonen
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F210/16 , Y10S526/943 , C08F4/611 , C08F210/14 , C08F2500/12
摘要： The invention relates to a novel olefin polymerization catalyst system comprising a reaction product of a transition metal compound. A stable and active single active site catalyst is obtained by producing said reaction product by: (I) contacting in an organic solvent the following reactive components (a) a transition metal compound, which is at least partially soluble in the organic solvent and contains in its molecule at least one organic group and a transition metal chosen from periods 4-7 and groups 3-10 of the Periodic Table (IUPAC 1990), and (b) 0.05-500 moles of an unsaturated organic compound per mole of transition metal of the transition metal compound, which unsaturated organic compound is at least partially soluble in the organic solvent, has in its molecule 2-30 carbon atoms and at least one terminal double bond, to obtain a reaction product dissolved in the organic solvent; and (II) recovering the reaction product of the transition metal compound.
摘要翻译：本发明涉及包含过渡金属化合物的反应产物的新型烯烃聚合催化剂体系。通过以下方法得到稳定且活性的单活性位点催化剂：（I）在有机溶剂中接触下列反应性组分（a）过渡金属化合物，该过渡金属化合物至少部分可溶于有机溶剂并含有其分子中至少有一种有机基团和选自周期表第4-7和3-10族的过渡金属（IUPAC 1990）和（b）每摩尔过渡金属的0.05-500摩尔不饱和有机化合物该不饱和有机化合物至少部分可溶于有机溶剂的过渡金属化合物在其分子中具有2-30个碳原子和至少一个末端双键，以获得溶解在有机溶剂中的反应产物; 和（II）回收过渡金属化合物的反应产物。

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