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1. 发明授权

US4451596A Water-dilutable lacquer binders based upon alkyd and acrylate resins 失效
标题翻译：基于醇酸树脂和丙烯酸酯树脂的水可稀释漆粘合剂
公开(公告)号：US4451596A
公开(公告)日：1984-05-29
申请号：US415067
申请日：1982-09-07
申请人： Hans-Christoph Wilk , Bernd Wegemund
发明人： Hans-Christoph Wilk , Bernd Wegemund
IPC分类号： C08L33/00 , C08F2/44 , C08F283/02 , C08L33/02 , C08L33/04 , C08L67/00 , C08L67/08 , C09D133/04 , C09D151/00 , C09D151/08 , C09D167/00 , C09D167/08 , C08L67/06
CPC分类号： C09D151/08 , C08F283/02 , C09D167/08
摘要： This invention is directed to water-dilutable alkyd and acrylate resins. More particularly, this invention is directed to a method for the preparation of water-dilutable resin preparations based upon alkyd and acrylate resins which comprises the steps of:(a) preparing an aqueous alkyd resin dispersion, wherein the alkyd resin has an acid number of from about 5 to 40 and a hydroxyl number of from about 150 to 300 and the dispersion has a solids content of from about 30 to 90 percent by weight; and(b) polymerizing monomers of acrylic acid derivatives or methacrylic acid derivatives in the dispersion from step (a), optionally in the presence of additional water, to obtain a total solids content of from about 30 to 80 percent by weight, the weight ratio of alkyd resin to acrylate resin being from about 1:4 to 9:1.This invention is also directed to the use of these binders in water-dilutable lacquer systems.
摘要翻译：本发明涉及水可稀释的醇酸树脂和丙烯酸酯树脂。更具体地，本发明涉及一种制备基于醇酸树脂和丙烯酸酯树脂的水可稀释树脂制剂的方法，其包括以下步骤：（a）制备醇酸树脂水分散体，其中醇酸树脂的酸值为约5至40，羟值为约150至300，分散体具有约30至90重量％的固体含量; 和（b）在步骤（a）的分散体中任选地在另外的水的存在下，将丙烯酸衍生物或甲基丙烯酸衍生物的单体聚合，得到约30至80重量％的总固体含量，重量比的醇酸树脂与丙烯酸酯树脂的比例为约1:4至9:1。本发明还涉及这些粘合剂在水可稀释漆系统中的用途。

2. 发明授权

US4474940A Alkyd resins from opened epoxidized hydroxyl compounds 失效
标题翻译：开环氧化羟基化合物的醇酸树脂
公开(公告)号：US4474940A
公开(公告)日：1984-10-02
申请号：US561622
申请日：1983-12-15
申请人： Hans-Christoph Wilk , Alfred Meffert , Herbert Fischer , Bernd Wegemund
发明人： Hans-Christoph Wilk , Alfred Meffert , Herbert Fischer , Bernd Wegemund
IPC分类号： C08G63/00 , C08G63/46 , C08G63/48 , C08G63/66 , C08G63/685 , C08G63/78 , C09D167/00 , C09D167/08 , C08G63/54
CPC分类号： C08G63/66 , C08G63/48 , C08G63/685 , C09D167/08
摘要： Alkyd resins useful in forming stoving lacquers, containing the reaction product of a polybasic carboxylic acid or reactive derivative thereof and a polyhydric alcohol which is itself the reaction product of an epoxidized fatty acid ester, fatty acid amide or fatty alcohol and an alcohol or phenol, and, optionally, a monofunctional modifying agent.
摘要翻译：用于形成烘烤漆的醇酸树脂，其含有多元羧酸或其活性衍生物的反应产物和本身是环氧化脂肪酸酯，脂肪酸酰胺或脂肪醇与醇或酚的反应产物的多元醇，和任选的单官能改性剂。

3. 发明授权

US4474941A Alkyd resins containing functional epoxides 失效
标题翻译：含有功能性环氧化物的醇酸树脂
公开(公告)号：US4474941A
公开(公告)日：1984-10-02
申请号：US561626
申请日：1983-12-15
申请人： Hans-Christoph Wilk , Alfred Meffert , Bernd Wegemund
发明人： Hans-Christoph Wilk , Alfred Meffert , Bernd Wegemund
IPC分类号： C08G63/00 , C08G63/48 , C08G63/78 , C09D167/00 , C09D167/08 , C08G63/54
CPC分类号： C08G63/48 , C09D167/08
摘要： Alkyd resins containing functional epoxides as long-chain modifying agents. The functional epoxides used are selected from the following:(a) epoxidized unsaturated fatty alcohols containing from 16 to 22 C-atoms,(b) esters of epoxidized fatty acids and monofunctional alcohols containing from 1 to 18 C-atoms,(c) epoxidized triglycerides,(d) reaction products of epoxidized triglycerides containing in the molecule epoxide groups and secondary hydroxyl groups formed by ring opening.The alkyd resins according to the invention are distinguished by particularly good weathering properties.
摘要翻译：含有功能性环氧化物的醇酸树脂作为长链改性剂。所使用的功能性环氧化物选自以下：（a）含有16-22个碳原子的环氧化不饱和脂肪醇，（b）环氧化脂肪酸的酯和含有1至18个碳原子的单官能醇，（c）环氧化甘油三酸酯，（d）环氧化甘油三酸酯在分子环氧基中的反应产物和由开环形成的仲羟基。根据本发明的醇酸树脂的特征是特别好的耐候性。

4. 发明授权

US4517334A Polyol-modified alkyd resins 失效
标题翻译：多元醇改性醇酸树脂
公开(公告)号：US4517334A
公开(公告)日：1985-05-14
申请号：US561630
申请日：1983-12-15
申请人： Hans-Christoph Wilk , Bernd Wegemund , Manfred Gorzinski
发明人： Hans-Christoph Wilk , Bernd Wegemund , Manfred Gorzinski
IPC分类号： C08G63/49 , C08G63/12 , C08G63/20 , C08G63/42 , C08G63/48 , C08G63/66 , C09D167/00 , C09D167/08 , C08L67/00
CPC分类号： C09D167/08 , C08G63/48 , C08G63/66
摘要： Alkyd resin mixtures for use in stoving water lacquers which contain polyols having an average molecular weight of from 200 to 2000 g/mole, an average --OH functionality of >2, and terminal groups of the formula, --CHR--OH in which R=--H, --CH.sub.3, or both --H and --CH.sub.3.
摘要翻译：用于烘干水漆的醇酸树脂混合物，其含有平均分子量为200至2000g / mol，平均-OH官能度> 2的多元醇和式-CHR-OH的末端基团，其中R = -H，-CH 3或-H和-CH 3。

5. 发明授权

US4497933A Emulsifier-free and solvent-free alkyd resin water lacquers 失效
标题翻译：无乳化剂和无溶剂的醇酸树脂水漆
公开(公告)号：US4497933A
公开(公告)日：1985-02-05
申请号：US561808
申请日：1983-12-15
申请人： Manfred Gorzinski , Hans-Christoph Wilk , Herbert Fischer , Bernd Wegemund
发明人： Manfred Gorzinski , Hans-Christoph Wilk , Herbert Fischer , Bernd Wegemund
IPC分类号： C08G63/00 , C08G63/12 , C08G63/46 , C08G63/48 , C08G63/49 , C08G63/78 , C08L67/08 , C09D167/00 , C09D167/08 , C09D3/64 , C08G63/20
CPC分类号： C08G63/48 , C09D167/08
摘要： Process for the production of alkyd resins having a final acid number of not more than 40 and a high --OH number for use in water lacquers. The resins of the invention can be made up with the aid of aminoalcohols containing more than two hydroxyl groups into optically clear water lacquers which are distinguished both by their lack of environmental problems and also by their advantageous lacquer properties.
摘要翻译：生产具有不超过40的最终酸值的醇酸树脂和用于水漆的高-OH数的方法。本发明的树脂可以借助于含有两个以上羟基的氨基醇组成光学透明的水漆，这两者通过缺乏环境问题以及它们有利的漆特性来区别。

6. 发明授权

US4385183A Telomerization of water-soluble monomers 失效
标题翻译：水溶性单体的凝聚
公开(公告)号：US4385183A
公开(公告)日：1983-05-24
申请号：US270491
申请日：1981-06-04
申请人： Rainer Hofer , Hans-Christoph Wilk , Bernd Wegemund
发明人： Rainer Hofer , Hans-Christoph Wilk , Bernd Wegemund
IPC分类号： C08F2/00 , C08F2/16 , C08F2/22 , C08F2/38 , C07C55/22 , C07C55/24
CPC分类号： C08F2/38
摘要： This invention is directed to the telomerization of water-soluble monomers in an aqueous phase. More particularly, this invention is directed to a process for the telomerization of water-soluble monomers and water-insoluble telogens in aqueous phase, wherein the water-insoluble telogens are solubilized by the addition of an effectively solubilizing amount of surface-active compounds.
摘要翻译：本发明涉及在水相中水溶性单体的调聚。更具体地说，本发明涉及一种在水相中调节水溶性单体和水不溶性前体体的方法，其中通过加入有效溶解量的表面活性化合物来溶解水不溶性的前体药物。

7. 发明授权

US4801601A N-substituted polyglycidyl urazole compounds, processes for their production and pharmaceutical preparations 失效
标题翻译： N-取代的聚缩水甘油脲化合物，其制备方法和药物制剂
公开(公告)号：US4801601A
公开(公告)日：1989-01-31
申请号：US831373
申请日：1986-02-20
申请人： Herbert Fischer , Brigitte Hase , Hinrich Moller , Hans-Christoph Wilk , Ulrich Zeidler
发明人： Herbert Fischer , Brigitte Hase , Hinrich Moller , Hans-Christoph Wilk , Ulrich Zeidler
IPC分类号： C07D405/14 , A61K20060101 , A61K31/41 , A61K31/42 , A61K31/53 , A61K31/535 , A61P35/00 , A61P43/00 , C07D20060101 , C07D249/12 , C07D303/36 , C07D405/04 , C07D405/06 , C07D413/06
CPC分类号： C07D405/06
摘要： N-substituted polyglycidyl urazole compounds of the general formula ##STR1## in which the radicals R represent a glycidyl radical corresponding to the following general formula ##STR2## wherein R.sub.1 represents hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, or two of the radicals R represent a glycidyl radical of general formula II while the remaining radical R is a radical Z, other than said glycidyl radical, containing carbon, hydrogen and, optionally, heteroatoms, are useful in the treatment of various forms of leukemia.
摘要翻译：其中基团R表示与以下通式相应的缩水甘油基（II）的通式为（IMA）的N-取代的聚缩水甘油脲化合物，其中R 1表示氢或含有1至4个的烷基碳原子或两个基团R表示通式II的缩水甘油基，而剩余的基团R是除所述缩水甘油基之外的含有碳，氢和任选的杂原子的基团Z可用于各种白血病的形式。

8. 发明授权

US4463006A Diglycidyl-pteridine compounds 失效
标题翻译：二缩水甘油基 - 蝶啶化合物
公开(公告)号：US4463006A
公开(公告)日：1984-07-31
申请号：US391174
申请日：1982-06-23
申请人： Hinrich Moller , Brigitte Hase , Gunther Konrad , Hans-Christoph Wilk , Ulrich Zeidler
发明人： Hinrich Moller , Brigitte Hase , Gunther Konrad , Hans-Christoph Wilk , Ulrich Zeidler
IPC分类号： C07D475/04 , A61K31/505 , A61K31/519 , A61P35/00 , C07D475/02 , C07D475/14
CPC分类号： C07D475/02 , C07D475/14
摘要： Diglycidyl-substituted pteridine compounds of the general formula: ##STR1## wherein n is the whole number 1 or 2, R.sub.2 and R.sub.2 are the same or different, and are either hydrogen, a hydrocarbon radical, or together form a 5- or 6-membered carbocyclic or heterocyclic ring; processes for their preparation; and compositions and methods for their use as cytostatic agents.
摘要翻译：具有以下通式的二缩水甘油基取代的蝶啶化合物：其中n为整数1或2，R2和R2相同或不同，为氢，烃基或一起形成5-或6 碳环或杂环; 其准备过程; 以及用作细胞抑制剂的组合物和方法。

9. 发明授权

US4476269A Polymer dispersions or emulsions as temporary surface protectants 失效
标题翻译：聚合物分散体或乳液作为临时表面保护剂
公开(公告)号：US4476269A
公开(公告)日：1984-10-09
申请号：US450185
申请日：1982-12-15
申请人： Hans-Christoph Wilk , Jurgen Geke
发明人： Hans-Christoph Wilk , Jurgen Geke
IPC分类号： C09D5/02 , B01F17/34 , C09D5/00 , C09D5/20 , C09D157/04 , C09D157/06 , C08K5/12
CPC分类号： C09D157/04 , C09D157/06 , C09D5/008
摘要： Easily removable protective coatings formed from aqueous dispersions or emulsions of synthetic copolymers that can form a salt and wherein these aqueous coating materials, in addition to water, contain the following constituents:(a) at least one copolymer which:(i) at a temperature of about 5.degree. C. and above will form a film,(ii) contains acid or amino groups wherein the copolymer is water-insoluble therewith, but wherein the copolymer becomes water-soluble when the acid or amino groups are in the form of a salt, and(iii) can exist in the form of an aqueous dispersion or emulsion.(b) at least one water-immiscible non-solvent which:(i) will not dissolve the copolymer in (a),(ii) has low volatility, and(iii) is liquid at room temperature;(c) at least one nonionic emulsifier with an HLB-value of less than 10; and(d) additional adjuvants and/or additives.The invention also relates to the application of these coating materials as temporary surface protectors, especially for metallic and/or painted surfaces, for storage in the open air with exposure to climatic and/or mechanical influences.
摘要翻译：由水性分散体或可形成盐的合成共聚物的乳液形成的容易移除的保护涂层，除了水之外，这些含水涂料含有以下组分：（a）至少一种共聚物，其：（i）在温度约5℃以上将形成膜，（ii）含有酸或氨基，其中共聚物与其不溶于水，但其中当酸或氨基为盐，和（iii）可以水分散体或乳液的形式存在。（b）至少一种与水不混溶的非溶剂：（i）不溶于（a）中的共聚物，（ii）具有低挥发性，和（iii）在室温下为液体; （c）HLB值小于10的至少一种非离子乳化剂; 和（d）另外的佐剂和/或添加剂。本发明还涉及这些涂层材料作为临时表面保护器，特别是金属和/或涂漆表面的应用，用于暴露在气候和/或机械影响下的露天空间中。

10. 发明授权

US4376120A Therapeutic compositions with a cytostatic action containing isocyanuric acid derivatives and process of manufacture 失效
标题翻译：含有异氰脲酸衍生物的细胞生长抑制作用的治疗组合物及其制造方法
公开(公告)号：US4376120A
公开(公告)日：1983-03-08
申请号：US289392
申请日：1981-08-03
申请人： Ulrich Zeidler , Herbert Fischer , Brigitte Hase , Hinrich Moller , Hans-Christoph Wilk
发明人： Ulrich Zeidler , Herbert Fischer , Brigitte Hase , Hinrich Moller , Hans-Christoph Wilk
IPC分类号： C07D251/34 , A61K31/53
CPC分类号： C07D251/34
摘要： New cytostatic compounds based on isocyanuric acid derivatives having 2 or 3 epoxide group containing substituents on ring nitrogen atoms, of which at least one differs from a glycidyl, having the formula ##STR1## wherein Oxiranyl is the same or different and has the formula ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and members selected from the group consisting of hydrogen, alkyl, haloalkyl, hydroxyalkyl and alkoxyalkyl and n in an integer from 1 to 8, with the proviso that if n is 1 in all oxiranyl groups, at least one of R.sub.1 or R.sub.3 is other than hydrogen, and R is a member selected from the group consisting of oxiranyl as defined above, hydrogen, alkyl, alkenyl, hydrocarbon aryl, hydrocarbon aralkyl, hydrocarbon alkaryl, cycloalkyl, and cycloalkenyl, optionally containing substituents.When R.sub.1, R.sub.2 and/or R.sub.3 denote alkyl or substituted alkyl in the oxiranyl radical, the alkyl radicals preferably have from 1 to 4 carbon atoms. The total number of carbon atoms in one oxiranyl radical should not be more than 10. The preparation of these compounds by introducing oxiranyl groups of Formula II and the radical R in known manner into the isocyanuric acid ring is also claimed.
摘要翻译：基于在环氮原子上具有2或3个环氧基团的取代基的异氰脲酸衍生物的新的细胞抑制化合物，其中至少一个不同于缩水甘油基，其具有式（VII），其中环氧乙烷基相同或不同，具有式IMA图其中R 1，R 2和R 3相同或不同，并且选自氢，烷基，卤代烷基，羟基烷基和烷氧基烷基和n在1至8的整数中的成员，条件是如果在所有环氧乙烷基中n为1 基团，R 1或R 3中的至少一个不是氢，R是选自如上定义的环氧乙烷，氢，烷基，烯基，烃芳基，烃芳烷基，烃烷芳基，环烷基和环烯基的成员，任选地含有取代基。当R1，R2和/或R3表示环氧乙烷基中的烷基或取代的烷基时，烷基优选具有1至4个碳原子。一个环氧乙烷基中碳原子的总数不应大于10.通过将式II的环氧乙烷基和已知方式的基团R引入到异氰脲酸环中，这些化合物的制备也被要求保护。

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