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1. 发明授权

US4254176A Novel transparent polyurethane polyurea films for lamination of glazing materials and their method of production 失效
标题翻译：用于层压玻璃材料的新型透明聚氨酯聚脲膜及其生产方法
公开(公告)号：US4254176A
公开(公告)日：1981-03-03
申请号：US947121
申请日：1978-09-29
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： C03C27/12 , B32B7/12 , B32B17/10 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/65 , C08G18/71 , C08G18/75 , C09J175/00 , B29D7/02 , C08G18/32
CPC分类号： B32B17/10018 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , C08G18/2805 , C08G18/71 , C08G18/75 , F41H5/0407 , Y10T428/269 , Y10T428/31551 , Y10T428/31601
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20.degree. and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.
摘要翻译：本公开涉及一种新型的透明聚氨酯聚脲，其特别适用于层压至玻璃和玻璃状透明塑料。聚合物是高分子量二醇，任选的低分子量二醇，二羟基羧酸，仅具有脂肪和环状结合的异氰酸酯的二异氰酸酯和具有脂族和环烯键合的伯氨基的有机二胺的反应产物。具体规定了羧基和脲基的含量，在20℃〜60℃都具有最小的剪切弹性模量。本发明还涉及合成这些聚合物的方法。优选的方法是使二异氰酸酯和含羟基的化合物反应以制备异氰酸酯封端的预聚物，并且链与二胺延伸。还讨论了通过挤出和溶液流延从这些聚合物生产膜，生产具有玻璃和玻璃状塑料的层压材料以及如此生产的层压材料。可以通过施加热和压力将溶液流延或挤出的膜层压到这些基底上。

2. 发明授权

US4166149A Novel transparent polyurethane polyureas for lamination of glazing materials 失效
标题翻译：用于玻璃复合材料层压的新型透明聚氨酯聚合物
公开(公告)号：US4166149A
公开(公告)日：1979-08-28
申请号：US947221
申请日：1978-09-29
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： B32B17/10 , C08G18/08 , C08G18/12 , C08G18/75 , B32B27/40 , B29D7/02 , C08G18/32 , C09J5/04
CPC分类号： C08G18/75 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , F41H5/0407 , Y10T428/26 , Y10T428/263 , Y10T428/269 , Y10T428/31507 , Y10T428/31576 , Y10T428/31591 , Y10T428/31601 , Y10T428/31935 , Y10T428/31971
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20.degree. and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.

3. 发明授权

US4174240A Novel transparent polyurethane polyureas for lamination of glazing materials 失效
标题翻译：用于层压玻璃材料的新型透明聚氨酯聚脲
公开(公告)号：US4174240A
公开(公告)日：1979-11-13
申请号：US947222
申请日：1978-09-29
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： B32B17/10 , C08G18/08 , C08G18/12 , C08G18/75 , C03C27/04 , B32B27/40 , C08G18/32 , C09J5/04
CPC分类号： C08G18/75 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , F41H5/0407 , Y10T428/26 , Y10T428/263 , Y10T428/269 , Y10T428/31576 , Y10T428/31601
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20.degree. and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.
摘要翻译：本公开涉及一种新型的透明聚氨酯聚脲，其特别适用于层压至玻璃和玻璃状透明塑料。聚合物是高分子量二醇，任选的低分子量二醇，二羟基羧酸，仅具有脂肪和环状结合的异氰酸酯的二异氰酸酯和具有脂族和环烯键合的伯氨基的有机二胺的反应产物。具体规定了羧基和脲基的含量，在20℃〜60℃都具有最小的剪切弹性模量。本发明还涉及合成这些聚合物的方法。优选的方法是使二异氰酸酯和含羟基的化合物反应以制备异氰酸酯封端的预聚物，并且链与二胺延伸。还讨论了通过挤出和溶液流延从这些聚合物生产膜，生产具有玻璃和玻璃状塑料的层压材料以及如此生产的层压材料。可以通过施加热和压力将溶液流延或挤出的膜层压到这些基底上。

4. 发明授权

US4139674A Novel transparent polyurethane polyureas for lamination of glazing materials 失效
标题翻译：用于层压玻璃材料的新型透明聚氨酯聚脲
公开(公告)号：US4139674A
公开(公告)日：1979-02-13
申请号：US833311
申请日：1977-09-14
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： C03C27/12 , B32B7/12 , B32B17/10 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/65 , C08G18/71 , C08G18/75 , C09J175/00 , B32B27/40 , B29D7/02 , C08G18/32 , C09J5/04
CPC分类号： B32B17/10018 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , C08G18/2805 , C08G18/71 , C08G18/75 , F41H5/0407 , Y10T428/269 , Y10T428/31551 , Y10T428/31601
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20 and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.
摘要翻译：本公开涉及一种新型的透明聚氨酯聚脲，其特别适用于层压至玻璃和玻璃状透明塑料。聚合物是高分子量二醇，任选的低分子量二醇，二羟基羧酸，仅具有脂肪和环状结合的异氰酸酯的二异氰酸酯和具有脂族和环烯键合的伯氨基的有机二胺的反应产物。具体规定了羧基和脲基的含量，在20和60℃下均具有最小的剪切模量。

5. 发明授权

US4134935A Dental varnishes 失效
标题翻译：牙科清漆
公开(公告)号：US4134935A
公开(公告)日：1979-01-16
申请号：US702904
申请日：1976-07-06
申请人： Bernd Quiring , Kuno Wagner , Joachim Konig
发明人： Bernd Quiring , Kuno Wagner , Joachim Konig
IPC分类号： A61K6/09 , C08G18/04 , C08G18/72 , C08L75/00
CPC分类号： A61K6/0017 , C08G18/04 , C08G18/728
摘要： Graft copolymers or telomerisates made of polyisocyanates and a copolymer of methylmethacrylate bearing isocyanategroups or groups reactive with isocyanates can be employed as dental varnishes. They demonstrate high abrasion resistance, are quick drying and hardening, and possess excellent adhesion properties.
摘要翻译：可以使用由多异氰酸酯制成的接枝共聚物或调聚物和甲基丙烯酸甲酯带有异氰酸酯基团或与异氰酸酯反应的基团的共聚物作为牙科清漆。它们表现出高耐磨性，快速干燥和硬化，并且具有优异的粘合性能。

6. 发明授权

US3943159A Process for the production of telomers containing isocyanate groups 失效
标题翻译：生产含有异氰酸酯基团的调聚物的方法
公开(公告)号：US3943159A
公开(公告)日：1976-03-09
申请号：US414575
申请日：1973-11-09
申请人： Bernd Quiring , Kuno Wagner
发明人： Bernd Quiring , Kuno Wagner
IPC分类号： C07C323/12 , C07C67/00 , C07C313/00 , C08F2/38 , C08G18/04 , C07C118/00
CPC分类号： C08G18/04
摘要： An improved process for the preparation of isocyanate group containing telomers of reduced viscosity by conducting the telomerization of an ethylenically unsaturated monomer with an organic isocyanate in the presence of an organic compound containing at least one sulfhydryl group.
摘要翻译：一种通过在含有至少一个巯基的有机化合物存在下，通过使有机异氰酸酯进行调节烯键式不饱和单体来制备具有降低的粘度的含异氰酸酯基的调聚物的改进方法。

7. 发明授权

US4143060A Process for the preparation of silyl substituted urea derivatives 失效
标题翻译：制备SILYL替代尿素衍生物的方法
公开(公告)号：US4143060A
公开(公告)日：1979-03-06
申请号：US535537
申请日：1974-12-23
申请人： Kuno Wagner , Gunter Oertel , Hans D. Golitz, deceased , Bernd Quiring
发明人： Kuno Wagner , Gunter Oertel , Hans D. Golitz, deceased , Bernd Quiring
IPC分类号： C07F7/10 , C07F7/18 , C08G18/71 , C08G18/80 , C07F7/02 , C07F7/07
CPC分类号： C08G18/718 , C07F7/10 , C07F7/1804 , C08G18/809
摘要： The instant invention is directed to a process of preparing a silyl substituted urea derivative comprising reacting an isocyanate of the formula ##STR1## wherein R represents a C.sub.1 -C.sub.18 alkyl group, a C.sub.4 -C.sub.14 cycloalkyl group or a phenyl group,R' represents an optionally halogenated or cyano-substituted C.sub.1 -C.sub.10 alkyl, C.sub.4 -C.sub.10 cycloalkyl or C.sub.6 -C.sub.10 aryl group,R" represents a hydrogen atom, a methyl group or a phenyl group,R'" represents a hydrogen atom or an optionally halogenated or cyano-substituted C.sub.1 -C.sub.18 alkyl, C.sub.4 -C.sub.14 cycloalkyl or C.sub.6 -C.sub.14 aryl group,Q' represents a divalent alkyl group containing 4 to 12 carbon atoms or a divalent C.sub.4 -C.sub.14 cycloalkyl, C.sub.7 -C.sub.15 aralkyl, C.sub.6 -C.sub.14 aryl or C.sub.8 alkylaryl group,A = 0 or 1,With a compound of the formula: Q (XH).sub.c, whereinQ represents a c-valent radical derived by the removal of c-XH groups from compounds with a molecular weight of 4000 to 80,000 which contains urea and urethane groups and in addition thereto, contains groups selected from the group consisting of ester groups, ether groups, and carbonate groups,C = 1 to 8 andX represents NH or NY, where Y is a C.sub.1 -C.sub.8 alkyl group, at a temperature of between -20.degree. to 150.degree. C in the presence of a stabilizing amount of a secondary or tertiary alcohol.The products so obtained have excellent storage stability, controlled reactivity and improved properties of cross-linked end products.

8. 发明授权

US5210170A Process for stabilizing plastics containing ester groups 失效
标题翻译：用于稳定含有酯类的塑料的方法
公开(公告)号：US5210170A
公开(公告)日：1993-05-11
申请号：US708590
申请日：1991-05-31
申请人： Bernd Quiring , Thomas Munzmay , Wolfgang Henning , Eduard Mayer , Walter Meckel , Wilhelm Goyert
发明人： Bernd Quiring , Thomas Munzmay , Wolfgang Henning , Eduard Mayer , Walter Meckel , Wilhelm Goyert
IPC分类号： C08G63/91 , C08G18/10 , C08G18/42 , C08G18/60 , C08G18/76 , C08G18/79 , C08G18/83 , C08K5/29 , C08L67/00 , C09J175/06
CPC分类号： C09J175/06 , C08G18/10 , C08G18/42 , C08G18/60 , C08G18/7678 , C08G18/797 , C08K5/29 , C08G2101/00 , C08G2150/20
摘要： The invention relates to a process for stabilizing ester-containing plastics against degradation by heat and/or hydrolysis by the incorporation of sterically hindered isocyanate-terminated carbodiimides. The incorporable carbodiimides produce an excellent anti-aging effect and do not give rise to volatile products, even at very high temperatures.
摘要翻译：本发明涉及稳定含酯塑料的方法，以防止加入和/或水解通过加入空间位阻异氰酸酯封端的碳二亚胺的降解。可加入的碳二亚胺产生优异的抗老化作用，即使在非常高的温度下也不会产生挥发性产物。

9. 发明授权

US4656199A Process for the production of matte, non-blocking, thin-walled molded articles from linear thermoplastic polyurethane elasotomers containing polyadducts and their use 失效
标题翻译：用于生产含有聚加成物的线性热塑性聚氨酯洗涤剂的无光泽，非阻塞，薄壁成型制品的方法及其用途
公开(公告)号：US4656199A
公开(公告)日：1987-04-07
申请号：US824337
申请日：1986-01-30
申请人： Georg Niederdellmann , Wilhelm Goyert , Bernd Quiring , Hans Wagner
发明人： Georg Niederdellmann , Wilhelm Goyert , Bernd Quiring , Hans Wagner
IPC分类号： C08G18/00 , C08G18/08 , C08G18/40 , C08G18/64 , C08L75/00 , C08L75/04 , C08G18/14
CPC分类号： C08G18/409 , C08G18/0876 , C08L75/04
摘要： The present invention is directed to a process for the production of matte, non-blocking, thin-walled molded articles, films or tubes from polyurethane elastomers prepared from high molecular weight polyols which contain dispersed polyadducts based on polyisocyanate polyaddition products. The use of these high molecular weight polyols contained dispersed polyadducts allows for the preparation of thin-walled, molded articles which have reduced surface tackiness. The present invention is additionally directed to the molded articles produced by this process and to their use for forming polyurethane foam composites.
摘要翻译：本发明涉及一种由高分子量多元醇制备的聚氨酯弹性体制备无光泽，非阻塞，薄壁成型制品，薄膜或管的方法，所述高分子量多元醇含有基于多异氰酸酯加聚产物的分散的多加成物。使用这些分子量高的多元醇多元醇可以制备具有降低的表面粘性的薄壁模塑制品。本发明另外涉及通过该方法制备的模塑制品及其用于形成聚氨酯泡沫复合材料的用途。

10. 发明授权

US4826918A Polycarbonate moulding composition with improved flow and processiblity 失效
标题翻译：聚碳酸酯模塑组合物具有改善的流动性和可加工性
公开(公告)号：US4826918A
公开(公告)日：1989-05-02
申请号：US161711
申请日：1988-02-29
申请人： Hans-Jurgen Kress , Dieter Wittmann , Bernd Quiring , Horst Peters , Jochen Schoeps
发明人： Hans-Jurgen Kress , Dieter Wittmann , Bernd Quiring , Horst Peters , Jochen Schoeps
IPC分类号： C08L25/02 , C08L33/04 , C08L33/12 , C08L33/18 , C08L51/04 , C08L69/00 , C08L83/04 , C08L83/10
CPC分类号： C08L69/00 , C08L83/10 , Y10S525/902
摘要： Thermoplastic molding compositions containingA. 10 to 98 parts by weight and preferably 10 to 95 parts by weight of one or more thermoplastic aromatic polycarbonates,B. 2 to 60 parts by weight and preferably 5 to 60 parts by weight of one or more graft polymers of:B.1 5 to 90 parts by weight and preferably 30 to 80 parts by weight of a mixture ofB.1.1 50 to 95 parts by weight styrene, .alpha.-methyl styrene, nucleus-substituted styrene, methyl methacrylate or mixtures thereof andB.1.2 50 to 5 parts by weight acrylonitrile, methacrylonitrile, methyl methacrylate, maleic acid anhydride, N-substituted maleic imide or mixtures thereof, orB.2 95 to 10 parts by weight and preferably 70 to 20 parts by weight of a rubber having a glass transition temperature T.sub.G of .ltoreq.10.degree. C.,C. 0 to 80 parts by weight of a thermoplastic copolymer of:C.1 50 to 95 parts by weight styrene, .alpha.-methyl styrene, nucleus-substituted styrene, methyl methacrylate or mixtures thereof andC. 2 50 to 5 parts by weight acrylonitrile, methacrylonitrile, methyl methacrylate, maleic acid anhydride, N-substituted maleic imide or mixtures thereof, the sum of the parts by weight of A.+B.+C. being 100 parts by weight andD. 0.5 to 10 parts by weight and preferably 1.0 to 5.0 parts by weight, based on 100 parts by weight of the mixture of A.+B.+C., of a hydroxyl-terminated aliphatic polycarbonate.
摘要翻译：含有A.10至98重量份，优选10至95重量份的一种或多种热塑性芳族聚碳酸酯的热塑性模制组合物，B 2至60重量份，优选5至60重量份的一种或多种接枝聚合物 B.1 5〜90重量份，优选30〜80重量份B.1.1 50〜95重量份苯乙烯，α-甲基苯乙烯，核取代苯乙烯，甲基丙烯酸甲酯或其混合物的混合物， B.1.2 50-5重量份丙烯腈，甲基丙烯腈，甲基丙烯酸甲酯，马来酸酐，N-取代马来酰亚胺或其混合物，或B.2 95-10重量份，优选70-20重量份橡胶玻璃化转变温度TG <10℃，C.0-80重量份的热塑性共聚物：C.150-95重量份苯乙烯，α-甲基苯乙烯，核取代苯乙烯，甲基丙烯酸甲酯或其混合物和C. 2 50至5份b 重量的丙烯腈，甲基丙烯腈，甲基丙烯酸甲酯，马来酸酐，N-取代的马来酰亚胺或其混合物，A + B + C的重量份之和。相对于100重量份的由羟基封端的脂肪族聚碳酸酯的A. + B. + C的混合物，为100重量份，D为0.5〜10重量份，优选为1.0〜5.0重量份。

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