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    • 2. 发明授权
    • Radiation detection
    • 辐射检测
    • US06787250B2
    • 2004-09-07
    • US10182924
    • 2002-07-29
    • Kengo ShibuyaMasanori KoshimizuYuko TakeokaKeisuke Asai
    • Kengo ShibuyaMasanori KoshimizuYuko TakeokaKeisuke Asai
    • G01T120
    • G01T1/2018
    • This invention relates to a radiation detection device for detecting ionizing beam discharges such as gamma rays, x-rays, electron beams, charged particle beams and neutral particle beams. Specifically, it relates to a radiation detection device which can measure radiations which exist for a very short time (of the order of subnanoseconds or less) from the appearance of photoemission to extinction. It is an object of this invention to provide a radiation detection device using a perovskite organic-inorganic hybrid compound as a scintillator, the formula of this compound being (R1—NR113)2MX4 or (R2═NR122)2MX4, or alternatively, (NR133—R3—NR133)MX4 or (NR142═R4═NR142)MX4 (in the formula, R1 is a monovalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, R2 is a divalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, and may be cyclic, R3 is a divalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, R4 is a tetravalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, R11-R14 may be identical or different, and may be hydrogen atoms or alkyl groups having two or more atoms, M is a Group IVa metal, Eu, Cd, Cu, Fe, Mn or Pd, and X is a halogen atom). This radiation detection device can quantify the radiation amount of the detected radiation.
    • 本发明涉及一种用于检测诸如γ射线,X射线,电子束,带电粒子束和中性粒子束的电离束放电的放射线检测装置。 具体地说,本发明涉及一种放射线检测装置,该放射线检测装置可以测量从光照发射到消光的非常短的时间(亚纳秒级以下)存在的辐射。本发明的目的是提供一种辐射检测装置 使用钙钛矿有机 - 无机杂化化合物作为闪烁体,该化合物的化学式为(R 1 -NR 11)2 M 2或(R 2 = NR 12)2 X 2,或者, NR 13 R 3或-NR 14 R 3 =(NR 14)= NR 4 = NR 14)MX 4(式中,R 1为单价 可以含有杂环并且可以被卤素原子取代的烃基,R 2是可以含有杂环并且可以被卤素原子取代的二价烃基,并且可以是环状,R 3是 可以含有杂环并且可以被卤素原子取代的二价烃基,R 4是可以含有杂环的四价烃基,并且可被ha取代 碱原子,R 11 -R 14可以相同或不同,可以是氢原子或具有两个或多个原子的烷基,M是Ⅳa族金属,Eu,Cd,Cu,Fe,Mn或Pd ,X为卤素原子)。 该放射线检测装置能够量化检测出的放射线的辐射量。
    • 3. 发明授权
    • Method and apparatus for measuring heat flux distribution on object surface using temperature-sensitive paint
    • 使用温度敏感涂料测量物体表面热流分布的方法和装置
    • US07069169B2
    • 2006-06-27
    • US10743786
    • 2003-12-24
    • Kazuyuki NakakitaKeisuke Asai
    • Kazuyuki NakakitaKeisuke Asai
    • G01K11/12
    • G01K17/20G01K11/12
    • An object of the present invention is to provide a method that allows the heat flux distribution on an object surface to be measured even when the heat flux is an unsteady or short-duration phenomenon, and that does not depend on the material of the object; and to provide a system for measuring the heat flux distribution on an object surface with the aid of this method. In the method for measuring the heat flux on an object surface in accordance with the present invention, the emission intensity of a temperature-sensitive paint that varies with the temperature of the object surface is chronologically captured and sensed as video information at a high frame rate, an image of the temperature distribution on the object surface is obtained based on characteristics between the emission intensity and temperature calibration, and the heat flux in each domain is calculated by the Cook and Feldermann method.
    • 本发明的目的是提供即使当热通量是不稳定或短时间现象而且不依赖于物体的材料时,也能够测量物体表面上的热通量分布的方法。 并提供一种借助于该方法测量物体表面上的热通量分布的系统。 在根据本发明的用于测量物体表面上的热通量的方法中,随着物体表面的温度而变化的温度敏感性涂料的发射强度按时间顺序捕获并被感测为高帧率的视频信息 根据发光强度和温度校准之间的特性,获得物体表面温度分布的图像,并通过Cook和Feldermann方法计算每个域中的热通量。
    • 6. 发明申请
    • Temperature sensitive paint for low-temperature use
    • 耐温敏涂料用于低温使用
    • US20050040368A1
    • 2005-02-24
    • US10745970
    • 2003-12-29
    • Yoshimi IijimaKeisuke Asai
    • Yoshimi IijimaKeisuke Asai
    • G01K11/16C09D5/22C09D5/26C09D175/04C09K11/06G01K11/20G01N31/22
    • G01K11/20
    • The present invention provides a temperature sensitive paint for low-temperature use which shows durability at low temperatures, has a high light emission intensity, and makes it possible to perform precise temperature measurements of surface temperature fields by applying the paint to the surface of an object and measuring the light emission even in cases where the measurement distance is long in, for example, a large cryogenic wind tunnel or the like. The temperature sensitive paint for low-temperature use contains a ruthenium complex having a high light emission intensity as a temperature sensitive luminophore, a urethane type polymer as a binder, and an alcohol organic solvent as a solvent. Use of an alcohol organic solvent makes it possible to dissolve a temperature sensitive luminophore at a high solubility and to increase the light emission intensity by raising the temperature sensitive luminophore concentration in the coating film, so that more precise temperature measurements can be performed. By using the urethane type polymer having the durability at low-temperature, it is possible to obtain durability where no cracks occur at low temperatures even when the film thickness is increased. Therefore, adjustment of the light emission intensity and surface treatment such as surface polishing and the like can be performed by using this temperature sensitive paint for low-temperature use.
    • 本发明提供一种低温用温敏涂料,其在低温下显示耐久性,发光强度高,并且可以通过将涂料施涂到物体的表面上来进行表面温度场的精确温度测量 并且即使在例如大型低温风洞等中测量距离长的情况下也测量发光。 用于低温用途的感温涂料含有作为温度敏感的发光体具有高发光强度的钌配合物,作为粘合剂的聚氨酯类聚合物和作为溶剂的醇有机溶剂。 使用醇有机溶剂使得可以以高溶解度溶解温度敏感的发光体并通过提高涂膜中的温度敏感的发光体浓度来增加发光强度,从而可以进行更精确的温度测量。 通过使用在低温下具有耐久性的氨基甲酸酯型聚合物,即使膜厚增加,也可获得在低温下不发生裂纹的耐久性。 因此,通过使用这种温度敏感的低温用涂料,可以进行发光强度的调整和表面处理等的表面处理等。
    • 8. 发明授权
    • Functional polymer with supported pressure-sensitive luminophore, and pressure-sensitive paint and pressure-sensitive element using same
    • 具有支持的压敏发光体的功能性聚合物和使用其的压敏涂料和压敏元件
    • US06797390B2
    • 2004-09-28
    • US10386671
    • 2003-03-13
    • Keisuke AsaiHiroyuki Nishide
    • Keisuke AsaiHiroyuki Nishide
    • B32B904
    • C08G61/04Y10T428/2852Y10T428/31663Y10T436/209163
    • An oxygen-quenching luminophore constituting part of a pressure-sensitive luminophore is directly bonded by a covalent bond to an organic polymer compound having trimethylsilyl groups, so the luminophore molecules are retained in the polymer and free aggregation is inhibited when the organic solvent is evaporated. It is therefore possible to prevent light response from being reduced by the aggregation of the luminophore molecules during evaporation of the organic solvent, which is a drawback of forming films from conventional mixed-type pressure-sensitive paints. A thin-film sensor with uniform characteristics can be formed by spraying or application from a pressure-sensitive paint obtained by mixing a functional polymer with a solvent. In addition, a coating solution that has high reproducibility and is suitable for spraying or application can be obtained merely by dissolving the functional polymer as a single component in a suitable solvent. It is possible to obtain a functional polymer, a pressure-sensitive paint, and a pressure-sensitive element in which a reduction in light response due to luminophore aggregation can be prevented, and a thin sensor film having uniform characteristics can be formed, even when the organic solvent has evaporated.
    • 构成压敏发光体的一部分的氧猝发发光体通过共价键直接键合到具有三甲基甲硅烷基的有机高分子化合物上,因此,当有机溶剂蒸发时,发光体分子保留在聚合物中,并且抑制游离聚集。 因此,通过在有机溶剂的蒸发过程中发光体分子的聚集来防止光的反应降低,这是由传统的混合型压敏涂料形成薄膜的缺点。 具有均匀特性的薄膜传感器可以通过将功能性聚合物与溶剂混合得到的压敏涂料进行喷涂或涂布而形成。 此外,仅通过将功能性聚合物作为单一成分溶解在合适的溶剂中,可以获得具有高再现性并且适于喷涂或施用的涂布溶液。 可以获得功能性聚合物,压敏涂料和能够防止由于发光聚集引起的光响应减少的压敏元件,并且即使形成具有均匀特性的薄传感器膜,即使 有机溶剂蒸发。
    • 10. 发明授权
    • Positron emission tomography device
    • 正电子发射断层摄影装置
    • US07087904B2
    • 2006-08-08
    • US10451755
    • 2002-07-29
    • Kengo ShibuyaMasanori KoshimizuKeisuke Asai
    • Kengo ShibuyaMasanori KoshimizuKeisuke Asai
    • G01T1/161C09K11/06
    • C09K11/664
    • This invention is a positron emission tomography (PET) device comprising as a scintillator a perovskite organic/inorganic hybrid compound selected from the group represented by the general formulae: (R1—NR113)2MX4 or (R2—NR12)2MX4, (NR133—R3—NR133)MX4, or (NR142═R4═NR142)MX4, or AMX3. When used as a scintillator, the perovskite organic/inorganic hybrid compound emits visible light with a very fast (subnanosecond order) response, allowing for improved resolution and time-of-flight PET methods.
    • 本发明是一种正电子发射断层摄影(PET)装置,其包括选自以下通式表示的钙钛矿有机/无机杂化化合物作为闪烁体:<?in-line-formula description =“In-line Formulas”end =“ (“1”)11“3”3“(”1“)。 或(R 12)-NR 12,(NR 12)12,或(R 12) 3个或3个或更多个(NR(R 3)3) 2 4 或AMX 3 <?in-line-formula description =“In-line Formulas”end =“tail”?>当用作闪烁体时,钙钛矿有机/无机杂化物 复合物以非常快的(亚纳秒级)响应发出可见光,允许改进分辨率和飞行时间PET方法。