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1. 发明授权

US09156976B2 Multi-stage polymer composition and films and polarizer plates made therefrom 有权
标题翻译：多级聚合物组合物和由其制成的膜和偏振片
公开(公告)号：US09156976B2
公开(公告)日：2015-10-13
申请号：US14111574
申请日：2012-08-14
申请人： Hailan Guo , Veera Nelliappan , Eric G. Lundquist
发明人： Hailan Guo , Veera Nelliappan , Eric G. Lundquist
IPC分类号： C08L33/12 , C08F2/00 , C08F220/14 , C08F285/00 , G02B1/04 , C08F220/18
CPC分类号： C08L33/12 , C08F2/001 , C08F220/14 , C08F285/00 , C08F2220/1808 , G02B1/04 , Y10T428/2998 , C08F2220/281 , C08F236/20 , C08F222/1006 , C08L33/08 , C08L33/10
摘要： A multi-stage polymer composition comprising a crosslinked core component, one or more intermediate layer components and an outermost layer component in which the refractive index of each of the crosslinked core, the one or more intermediate layers and the outermost layer are within 2% of the refractive index of each adjacent component; wherein the crosslinked core component comprises from 75 to 99.9 weight percent of units derived from at least one first monomer selected from the group consisting of alkyl, aryl, and cycloalkyl (meth)acrylate monomer, optionally from 1 to 20 weight percent of units derived from a second monomer selected from the group consisting vinyl monomers; and from 0.1 to 5 weight percent of units derived from cross-linking monomers, graft-linking monomers, or combination thereof, and has a Tg of from −75 to −35° C.; wherein each of the one or more intermediate layer components comprises from 71 to 99.9 weight percent of units derived from a third monomer selected from the group consisting alkyl, aryl and cycloalkyl (meth)acrylate monomers, from 0 to 5 weight percent of units derived from a cross-linking monomer, graft-linking monomer, or combination thereof, optionally from 1 to 10 weight percent of units derived from one or more functional monomers, from 0 to 14 weight percent of vinyl monomers, and has a Tg of from −35 to 100° C.; and wherein the outermost layer component comprises from 90 to 100 weight percent units derived from a fourth monomer selected from the group consisting of alkyl (meth)acrylate having from one to twelve carbon atoms, optionally from 0.5 to 10 weight percent of units derived from one or more functional monomers, and has a Tg of from 80 to 130° C. is provided. Films and polarizer plates made from the compositions are also provided.
摘要翻译：一种多级聚合物组合物，其包含交联核心组分，一种或多种中间层组分和最外层组分，其中每个交联核心，一个或多个中间层和最外层的折射率在每个相邻部件的折射率; 其中所述交联核心组分包含75至99.9重量％的衍生自至少一种选自烷基，芳基和（甲基）丙烯酸环烷基酯单体的第一单体的单元，任选地1至20重量％衍生自选自乙烯基单体的第二单体; 和0.1至5重量％的衍生自交联单体，接枝单体或其组合的单元，并且具有-75至-35℃的Tg。其中所述一种或多种中间层组分中的每一种包含71至99.9重量％的衍生自选自烷基，芳基和（甲基）丙烯酸环烷基酯单体的第三单体的单元，0至5重量％的衍生自交联单体，接枝单体或其组合，任选地1至10重量％的衍生自一种或多种官能单体的单元，0至14重量％的乙烯基单体，并且具有-35 至100℃。并且其中最外层组分包含90至100重量％的衍生自第四单体的单元，所述第四单体选自具有1至12个碳原子的（甲基）丙烯酸烷基酯，任选地0.5至10重量％的衍生自一个或更多官能单体，并且具有80至130℃的Tg。还提供了由组合物制成的膜和偏振片。

2. 发明申请

US20130116382A1 THERMOPLASTIC COMPOSITION, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：热塑性组合物，其制造方法及其制造方法
公开(公告)号：US20130116382A1
公开(公告)日：2013-05-09
申请号：US13808951
申请日：2011-07-06
申请人： Srdjan Kisin , Eric G. Lundquist , Timothy E. Clayfield , Yannick Saint-Gerard , Veera Nelliappan
发明人： Srdjan Kisin , Eric G. Lundquist , Timothy E. Clayfield , Yannick Saint-Gerard , Veera Nelliappan
IPC分类号： C08L55/02 , C08L33/08
CPC分类号： C08L51/003 , C08L51/04 , C08L69/00 , C08L77/00 , C08L77/02 , C08L2666/20 , C08L2666/18 , C08L2666/24
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (a) from 10 to 75 percent by weight of a continuous phase, based on the total weight of the thermoplastic composition, wherein said continuous phase comprises one or more thermoplastic polymers; and (b) from 25 to 90 percent by weight of a dispersed phase comprising one or more core/shell polymer particles, based on the total weight of the thermoplastic composition, wherein said one or more core/shell polymer particles comprise a crosslinked elastomer core and a thermoplastic shell and wherein said core/shell polymer has an average particle size diameter in the range of from 70 to 10,000 nm.
摘要翻译：本发明提供一种热塑性组合物，其制造方法和由其制成的制品。根据本发明的热塑性组合物包含：（a）基于热塑性组合物的总重量为10至75重量％的连续相的熔融共混产物，其中所述连续相包含一种或多种热塑性聚合物; 和（b）基于热塑性组合物的总重量，25至90重量％的包含一种或多种核/壳聚合物颗粒的分散相，其中所述一种或多种核/壳聚合物颗粒包含交联弹性体芯和热塑性壳，其中所述核/壳聚合物的平均粒度直径在70至10,000nm的范围内。

3. 发明授权

US09493647B2 Thermoplastic composition, method of producing the same, and articles made therefrom 有权
标题翻译：热塑性组合物，其制造方法和由其制成的制品
公开(公告)号：US09493647B2
公开(公告)日：2016-11-15
申请号：US13876001
申请日：2011-10-26
申请人： Yannick Saint-Gerard , Veera Nelliappan , Yannick Chiquet , Eric G. Lundquist
发明人： Yannick Saint-Gerard , Veera Nelliappan , Yannick Chiquet , Eric G. Lundquist
IPC分类号： C08L67/02 , C08L67/07 , C08L69/00 , B29C45/00 , C08L33/12
CPC分类号： C08L67/07 , B29C45/0001 , C08L33/12 , C08L67/02 , C08L69/00 , C08L2205/22
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08.
摘要翻译：本发明提供一种热塑性组合物，其制造方法和由其制成的制品。根据本发明的热塑性组合物包含熔融共混产物：（A）55至95重量％的包含一种或多种热塑性聚合物的热塑性基质; 和（B）5至45重量％的包含交联的（甲基）丙烯酸酯共聚物的分散相，其中（甲基）丙烯酸酯共聚物包含至少95重量％衍生自甲基丙烯酸甲酯单元，并且大于0至衍生自一种或多种多官能交联单体和/或接枝连接剂的小于0.5重量％其中组分（A）和（B）之间的折射率差大于0.08。

4. 发明申请

US20130237673A1 Thermoplastic Composition, Method of Producing the Same, and Articles Made Therefrom 有权
标题翻译：热塑性组合物，其制造方法及其制品
公开(公告)号：US20130237673A1
公开(公告)日：2013-09-12
申请号：US13876001
申请日：2011-10-26
申请人： Yannick Saint-Gerard , Veera Nelliappan , Yannick Chiquet , Eric G. Lundquist
发明人： Yannick Saint-Gerard , Veera Nelliappan , Yannick Chiquet , Eric G. Lundquist
IPC分类号： C08L67/07 , B29C45/00
CPC分类号： C08L67/07 , B29C45/0001 , C08L33/12 , C08L67/02 , C08L69/00 , C08L2205/22
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08.
摘要翻译：本发明提供一种热塑性组合物，其制造方法和由其制成的制品。根据本发明的热塑性组合物包含熔融共混产物：（A）55至95重量％的包含一种或多种热塑性聚合物的热塑性基质; 和（B）5至45重量％的包含交联的（甲基）丙烯酸酯共聚物的分散相，其中（甲基）丙烯酸酯共聚物包含至少95重量％衍生自甲基丙烯酸甲酯单元，并且大于0至衍生自一种或多种多官能交联单体和/或接枝连接剂的小于0.5重量％其中组分（A）和（B）之间的折射率差大于0.08。

5. 发明授权

US09376562B2 Thermoplastic composition, method of producing the same, and articles made therefrom 有权
标题翻译：热塑性组合物，其制造方法和由其制成的制品
公开(公告)号：US09376562B2
公开(公告)日：2016-06-28
申请号：US13989925
申请日：2011-12-21
申请人： Veera Nelliappan , Eric G. Lundquist , Yannick Saint-Gerard
发明人： Veera Nelliappan , Eric G. Lundquist , Yannick Saint-Gerard
IPC分类号： C08L69/00 , C08L33/12
CPC分类号： C08L69/00 , C08L33/12 , C08F220/14 , C08F2222/1013
摘要： A thermoplastic composition comprising from 60 percent to 99 percent by weight of one or more thermoplastic polymers; and from 40 percent to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked methylmethacrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers; wherein the crosslinked (meth)acrylate polymer has a volume average particle size of equal to or less than 1.0 micron; and wherein an article produced from the scratch-resistant thermoplastic composition has a hardness of greater than F is provided. Also provided are a method of making the thermoplastic composition, articles made from the polycarbonate composition, and a method of making the articles.
摘要翻译：一种热塑性组合物，其包含60重量％至99重量％的一种或多种热塑性聚合物; 和40重量％至1重量％的包含交联的（甲基）丙烯酸酯聚合物的添加剂，其中交联的甲基丙烯酸甲酯聚合物包含衍生自甲基丙烯酸甲酯单元的至少99.5重量％，并且从大于0至小于0.5％衍生自一种或多种多官能交联单体的重量; 其中所述交联的（甲基）丙烯酸酯聚合物具有等于或小于1.0微米的体积平均粒度; 并且其中由耐刮擦热塑性组合物制成的制品具有大于F的硬度。还提供了制造热塑性组合物的方法，由聚碳酸酯组合物制成的制品以及制造该制品的方法。

6. 发明申请

US20130317174A1 Thermoplastic Composition, Method of Producing the Same, and Articles Made Therefrom 有权
标题翻译：热塑性组合物，其制造方法及其制品
公开(公告)号：US20130317174A1
公开(公告)日：2013-11-28
申请号：US13989925
申请日：2011-12-21
申请人： Veera Nelliappan , Eric G. Lundquist , Yannick Saint-Gerard
发明人： Veera Nelliappan , Eric G. Lundquist , Yannick Saint-Gerard
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08L33/12 , C08F220/14 , C08F2222/1013
摘要： A thermoplastic composition comprising from 60 percent to 99 percent by weight of one or more thermoplastic polymers; and from 40 percent to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked methylmethacrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers; wherein the crosslinked (meth)acrylate polymer has a volume average particle size of equal to or less than 1.0 micron; and wherein an article produced from the scratch-resistant thermoplastic composition has a hardness of greater than F is provided. Also provided are a method of making the thermoplastic composition, articles made from the polycarbonate composition, and a method of making the articles.
摘要翻译：一种热塑性组合物，其包含60重量％至99重量％的一种或多种热塑性聚合物; 和40重量％至1重量％的包含交联的（甲基）丙烯酸酯聚合物的添加剂，其中交联的甲基丙烯酸甲酯聚合物包含衍生自甲基丙烯酸甲酯单元的至少99.5重量％，并且从大于0至小于0.5％衍生自一种或多种多官能交联单体的重量; 其中所述交联的（甲基）丙烯酸酯聚合物具有等于或小于1.0微米的体积平均粒度; 并且其中由耐刮擦热塑性组合物制成的制品具有大于F的硬度。还提供了制造热塑性组合物的方法，由聚碳酸酯组合物制成的制品以及制造该制品的方法。

7. 发明授权

US08779051B2 Thermoplastic composition, method of producing the same, and articles made therefrom 有权
标题翻译：热塑性组合物，其制造方法和由其制成的制品
公开(公告)号：US08779051B2
公开(公告)日：2014-07-15
申请号：US13808951
申请日：2011-07-06
申请人： Srdjan Kisin , Eric G. Lundquist , Timothy E. Clayfield , Yannick Saint-Gerard , Veera Nelliappan
发明人： Srdjan Kisin , Eric G. Lundquist , Timothy E. Clayfield , Yannick Saint-Gerard , Veera Nelliappan
IPC分类号： C08L51/00 , C08L53/00 , C08F290/04 , C08K5/00
CPC分类号： C08L51/003 , C08L51/04 , C08L69/00 , C08L77/00 , C08L77/02 , C08L2666/20 , C08L2666/18 , C08L2666/24
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (a) from 10 to 75 percent by weight of a continuous phase, based on the total weight of the thermoplastic composition, wherein said continuous phase comprises one or more thermoplastic polymers; and (b) from 25 to 90 percent by weight of a dispersed phase comprising one or more core/shell polymer particles, based on the total weight of the thermoplastic composition, wherein said one or more core/shell polymer particles comprise a crosslinked elastomer core and a thermoplastic shell and wherein said core/shell polymer has an average particle size diameter in the range of from 70 to 10,000 nm.
摘要翻译：本发明提供一种热塑性组合物，其制造方法和由其制成的制品。根据本发明的热塑性组合物包含：（a）基于热塑性组合物的总重量为10至75重量％的连续相的熔融共混产物，其中所述连续相包含一种或多种热塑性聚合物; 和（b）基于热塑性组合物的总重量，25至90重量％的包含一种或多种核/壳聚合物颗粒的分散相，其中所述一种或多种核/壳聚合物颗粒包含交联弹性体芯和热塑性壳，其中所述核/壳聚合物的平均粒度直径在70至10,000nm的范围内。

8. 发明申请

US20140205825A1 Multi-Stage Polymer Composition and Films and Polarizer Plates Made Therefrom 有权
标题翻译：多阶段聚合物组合物和薄膜以及偏光板
公开(公告)号：US20140205825A1
公开(公告)日：2014-07-24
申请号：US14111574
申请日：2012-08-14
申请人： Hailan Guo , Veera D. Nelliappan , Eric G. Lundquist
发明人： Hailan Guo , Veera D. Nelliappan , Eric G. Lundquist
IPC分类号： C08L33/12
CPC分类号： C08L33/12 , C08F2/001 , C08F220/14 , C08F285/00 , C08F2220/1808 , G02B1/04 , Y10T428/2998 , C08F2220/281 , C08F236/20 , C08F222/1006 , C08L33/08 , C08L33/10
摘要： A multi-stage polymer composition comprising a crosslinked core component, one or more intermediate layer components and an outermost layer component in which the refractive index of each of the crosslinked core, the one or more intermediate layers and the outermost layer are within 2% of the refractive index of each adjacent component; wherein the crosslinked core component comprises from 75 to 99.9 weight percent of units derived from at least one first monomer selected from the group consisting of alkyl, aryl, and cycloalkyl (meth)acrylate monomer, optionally from 1 to 20 weight percent of units derived from a second monomer selected from the group consisting vinyl monomers; and from 0.1 to 5 weight percent of units derived from cross-linking monomers, graft-linking monomers, or combination thereof, and has a Tg of from −75 to −35° C.; wherein each of the one or more intermediate layer components comprises from 71 to 99.9 weight percent of units derived from a third monomer selected from the group consisting alkyl, aryl and cycloalkyl (meth)acrylate monomers, from 0 to 5 weight percent of units derived from a cross-linking monomer, graft-linking monomer, or combination thereof, optionally from 1 to 10 weight percent of units derived from one or more functional monomers, from 0 to 14 weight percent of vinyl monomers, and has a Tg of from −35 to 100° C.; and wherein the outermost layer component comprises from 90 to 100 weight percent units derived from a fourth monomer selected from the group consisting of alkyl (meth)acrylate having from one to twelve carbon atoms, optionally from 0.5 to 10 weight percent of units derived from one or more functional monomers, and has a Tg of from 80 to 130° C. is provided. Films and polarizer plates made from the compositions are also provided.
摘要翻译：一种多级聚合物组合物，其包含交联核心组分，一种或多种中间层组分和最外层组分，其中每个交联核心，一个或多个中间层和最外层的折射率在每个相邻部件的折射率; 其中所述交联核心组分包含75至99.9重量％的衍生自至少一种选自烷基，芳基和（甲基）丙烯酸环烷基酯单体的第一单体的单元，任选地1至20重量％衍生自选自乙烯基单体的第二单体; 和0.1至5重量％的衍生自交联单体，接枝单体或其组合的单元，并且具有-75至-35℃的Tg。其中所述一种或多种中间层组分中的每一种包含71至99.9重量％的衍生自选自烷基，芳基和（甲基）丙烯酸环烷基酯单体的第三单体的单元，0至5重量％的衍生自交联单体，接枝单体或其组合，任选地1至10重量％的衍生自一种或多种官能单体的单元，0至14重量％的乙烯基单体，并且具有-35 至100℃。并且其中最外层组分包含90至100重量％的衍生自第四单体的单元，所述第四单体选自具有1至12个碳原子的（甲基）丙烯酸烷基酯，任选地0.5至10重量％的衍生自一个或更多官能单体，并且具有80至130℃的Tg。还提供了由组合物制成的膜和偏振片。

9. 发明授权

US08614268B2 Stabilized polymer compositions 有权
标题翻译：稳定的聚合物组合物
公开(公告)号：US08614268B2
公开(公告)日：2013-12-24
申请号：US12661958
申请日：2010-03-26
申请人： Eric G. Lundquist , Jian-Yang Cho
发明人： Eric G. Lundquist , Jian-Yang Cho
IPC分类号： C08K5/02 , C08K5/58 , C08K5/57 , C08K13/00
CPC分类号： C08L27/00 , C08L33/02 , C08L2666/04
摘要： This invention relates to the thermal stabilization of halogen-containing polymer compositions, more particularly, this invention relates to a poly(vinyl chloride) (PVC) or a chlorinated polyvinyl chloride (cPVC) composition comprising an alkyl tin stabilizer and at least one salt of a polymeric polyacid such as a polycarboxylic acid salt supported on a polymeric material.
摘要翻译：本发明涉及含卤聚合物组合物的热稳定化，更具体地说，本发明涉及一种聚（氯乙烯）（PVC）或氯化聚氯乙烯（cPVC）组合物，其包含烷基锡稳定剂和至少一种聚合多元酸，例如负载在聚合物材料上的多元羧酸盐。

10. 发明授权

US06982307B2 Matrix and process for polyolefin production 有权
公开(公告)号：US06982307B2
公开(公告)日：2006-01-03
申请号：US09932865
申请日：2001-08-17
申请人： Eric G. Lundquist , Jennifer A. Reichl , James C. Bohling
发明人： Eric G. Lundquist , Jennifer A. Reichl , James C. Bohling
IPC分类号： C08F4/64 , C08F4/60
CPC分类号： B01J31/2295 , B01J31/069 , B01J31/165 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/824 , C08F4/65904 , C08F4/65908 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/027 , C08F4/025 , C08F4/6543 , C08F4/65916 , C08F210/14 , C08F2500/03 , C08F4/7006
摘要： Olefin-based materials react with a range of catalysts and catalytic systems to form catalytic matrices, which are employed in the production of a variety of polyolefin products.

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