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1. 发明申请

US20120277334A1 AQUEOUS COMPOSITIONS COMPRISING ION EXCHANGE RESINS THAT DELIVER PAINT AND PRIMER PROPERTIES IN A COATING 有权
标题翻译：含有交联树脂的水性组合物，在涂料中提供涂料和涂料性能
公开(公告)号：US20120277334A1
公开(公告)日：2012-11-01
申请号：US13453057
申请日：2012-04-23
申请人： Wei ZHANG , Ozzie M. PRESSLEY , Monica A. LUCKENBACH , James C. BOHLING
发明人： Wei ZHANG , Ozzie M. PRESSLEY , Monica A. LUCKENBACH , James C. BOHLING
IPC分类号： C09D125/08
CPC分类号： C09D5/002 , C09D5/022 , C09D5/1637 , C09D7/65 , C09D143/02
摘要： The present invention provides one component aqueous compositions comprising (i) from 0.01 to 7 wt. %, based on the total weight of solids in the composition, of anion exchange resin beads having a weight average particle size of from 0.1 to 20 μm a low crosslinker content, the anion exchange resin copolymer beads being chosen from gelular beads, beads having a dual morphology, and mixtures thereof, (ii) an emulsion copolymer having a copolymerization residue of one or more phosphorus acid monomer, and having an anionic surfactant or its polymerization residue and a reductant or its polymerization residue and, (iii) at least one phosphorous containing surfactant in the amount of from 0.1 to 5 wt. %, based on the weight of emulsion copolymer solids. The compositions find use as coating binders and either pigmented or unpigmented paints and enable the provision of a single coat primer plus topcoat with excellent stain blocking.
摘要翻译：本发明提供单组分水性组合物，其包含（i）0.01至7重量％％，基于组合物中固体的总重量，具有低交联剂含量的重均粒径为0.1至20μm的阴离子交换树脂珠，阴离子交换树脂共聚物珠选自凝胶珠，具有双重形态及其混合物，（ii）具有一个或多个磷酸单体的共聚残基并具有阴离子表面活性剂或其聚合残基和还原剂或其聚合残基的乳液共聚物，和（iii）至少一种磷含量为0.1-5重量％的表面活性剂。％，基于乳液共聚物固体的重量。该组合物用作涂料粘合剂和着色或未着色的涂料，并且能够提供具有优异污渍阻挡性能的单一涂料底漆和外涂层。

2. 发明授权

US09518192B2 Process for improving hiding efficiency in pigmented paints 有权
标题翻译：提高着色涂料遮盖效率的方法
公开(公告)号：US09518192B2
公开(公告)日：2016-12-13
申请号：US14131071
申请日：2011-07-05
申请人： James C. Bohling , Deborah G. Fradkin , Wei Gao , John W. Hook, III , Tao Wang , Tao Wang
发明人： James C. Bohling , Deborah G. Fradkin , Wei Gao , John W. Hook, III , Tao Wang , Tao Wang
IPC分类号： C08J3/215 , C08K3/22 , C09D133/08 , C09C1/36 , C09D135/06 , C09D5/02 , C09D7/12 , C09D7/14 , C08K3/20
CPC分类号： C09D133/08 , C01P2004/62 , C08K3/20 , C08K3/22 , C08K2003/2241 , C09C1/3676 , C09D5/028 , C09D7/61 , C09D7/80 , C09D135/06
摘要： The present invention relates to a process comprising the steps of a) contacting an aqueous dispersion of a TiO2 slurry containing adsorbing dispersant with an adsorbing latex to form a mixture, wherein the pH of the mixture of the TiO2 slurry and adsorbing latex are sufficiently high to inhibit interaction between the TiO2 and the adsorbing latex; then b) lowering the pH of the mixture of step a) sufficiently to promote interaction between the TiO2 and the adsorbing latex, thereby forming a composite. The process of the present invention provides for improved hiding and reduced grit for coatings compositions.
摘要翻译：本发明涉及一种方法，包括以下步骤：a）将含有吸附分散剂的TiO 2浆料的水性分散体与吸附胶乳接触以形成混合物，其中TiO 2浆料和吸附胶乳的混合物的pH足够高至抑制TiO 2和吸附胶乳之间的相互作用; 然后b）降低步骤a）的混合物的pH足以促进TiO 2和吸附胶乳之间的相互作用，从而形成复合材料。本发明的方法提供了改进的涂层组合物的隐藏和减小的砂砾。

3. 发明申请

US20120172561A1 Method of Making Polymeric Bead From Phosphorous Acid Containing Monomers 有权
标题翻译：从含有单体的亚磷酸制备聚合物珠的方法
公开(公告)号：US20120172561A1
公开(公告)日：2012-07-05
申请号：US13339480
申请日：2011-12-29
申请人： James C. Bohling , Jose Antonio Trejo-O'Reilly
发明人： James C. Bohling , Jose Antonio Trejo-O'Reilly
IPC分类号： C08F230/02
CPC分类号： C08F2/20 , C08F230/02 , C08F220/06 , C08F212/36
摘要： The present invention is a method for making a polymeric bead by suspension polymerization processes from a phosphoric acid monoester.
摘要翻译：本发明是通过从磷酸单酯的悬浮聚合方法制备聚合物珠粒的方法。

4. 发明申请

US20100034975A1 Aqueous polymeric dispersion and method for providing improved adhesion 有权
标题翻译：水性聚合物分散体和提供改善粘合力的方法
公开(公告)号：US20100034975A1
公开(公告)日：2010-02-11
申请号：US12460072
申请日：2009-07-13
申请人： James C. Bohling , Andrew Hejl , Alvin M. Maurice
发明人： James C. Bohling , Andrew Hejl , Alvin M. Maurice
IPC分类号： B05D3/02 , C08K5/3437 , C08K5/01
CPC分类号： C08F220/18 , C08F230/02 , C08F232/08 , C09J133/14 , C09J143/02
摘要： This invention provides an aqueous polymeric dispersion, the polymer including, as polymerized units: from 0.1 to 10%, by weight based on the weight of the polymer, monomer selected from the group consisting of strong carboxylic acid monomers, sulfonic acid monomers and phosphorous-containing acid monomers, and from 0.01 to 3%, by weight based on the weight of the polymer, a moiety including the structure, wherein X═CY, N, or P and Y, independently ═H, C, N, O, Cl, Br, F, Si, S, or P. Also, a method for forming the aqueous polymeric dispersion and a method for providing a coating having improved adhesion to a substrate, particularly to a metal substrate, is provided.
摘要翻译：本发明提供一种水性聚合物分散体，该聚合物包含聚合单元：基于聚合物重量的0.1至10重量％，选自强羧酸单体，磺酸单体和磷酸单体的单体，其中X-CY，N或P和Y独立地为-H，C，N，O，Cl Br，F，Si，S或P.此外，还提供了形成水性聚合物分散体的方法和提供具有改善的对基材，特别是金属基材的粘合性的涂层的方法。

5. 发明授权

US09346970B2 Adsorbing vinyl acetate binders 有权
标题翻译：吸附乙酸乙烯酯粘合剂
公开(公告)号：US09346970B2
公开(公告)日：2016-05-24
申请号：US14398487
申请日：2012-05-04
申请人： James C. Bohling , Qiaoqiao Cai , Edwin H. Nungesser , Morris C. Wills , Tingke Zhang
发明人： James C. Bohling , Qiaoqiao Cai , Edwin H. Nungesser , Morris C. Wills , Tingke Zhang
IPC分类号： C08L31/04 , C08L43/02 , C09D131/04 , C08F2/22 , C09D143/02 , C08F220/60 , C08K3/22 , C09D7/12
CPC分类号： C09D131/04 , C08F2/22 , C08F220/60 , C08K3/22 , C08K2003/2241 , C08L2201/50 , C08L2201/54 , C09D7/61 , C09D143/02 , C08F218/08 , C08F230/02 , C08F220/18 , C08F2220/585
摘要： The present invention relates to a composition comprising and a method for preparing a stable aqueous dispersion of polymer particles comprising structural units of vinyl acetate and a phosphorous acid monomer. The composition of the present invention provides vinyl acetate/phosphorus acid based polymer particles that improve hiding efficiency in pigmented coatings formulations.
摘要翻译：本发明涉及一种组合物，它包括一种制备包含乙酸乙烯酯和亚磷酸单体的结构单元的聚合物颗粒的稳定水分散体的方法。本发明的组合物提供了改善着色涂料配方中遮盖效率的乙酸乙烯酯/磷酸基聚合物颗粒。

6. 发明授权

US09221992B2 Aqueous coating compositions 有权
标题翻译：水性涂料组合物
公开(公告)号：US09221992B2
公开(公告)日：2015-12-29
申请号：US14119905
申请日：2012-05-31
申请人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan , Ozzie M. Pressley , Wei Zhang
发明人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan , Ozzie M. Pressley , Wei Zhang
IPC分类号： C09D133/12 , C09D5/02 , C09D7/12 , C08F2/38 , C08F265/06 , C09D151/00
CPC分类号： C09D133/12 , C08F2/38 , C08F265/06 , C09D5/028 , C09D7/62 , C09D151/003 , C08F2220/1825 , C08F220/14 , C08F220/06 , C08F230/02 , C08F2220/346 , C08L51/003 , C08L33/12 , C08F2220/1808 , C08F2220/283
摘要： An aqueous coating composition including a) a composite particle including an opacifying pigment particle such as, for example, TiO2 and, disposed thereon, a plurality of particles of a first polymer, the first polymer being a select P-acid containing emulsion polymer and b) from 7% to 25% by weight, based on the total weight of polymer in the aqueous coating composition, of a select second polymer is provided. A method for forming the aqueous coating composition, a method for forming a dried coating therefrom, and the coating so formed are also provided.
摘要翻译：一种水性涂料组合物，其包含a）包含不透明颜料颗粒例如TiO 2的复合颗粒，并且在其上设置多个第一聚合物颗粒，所述第一聚合物是选择含P酸的乳液聚合物和b ）为7〜25重量％，基于水性涂料组合物中的聚合物的总重量，选择的第二聚合物。还提供了一种形成水性涂料组合物的方法，由其形成干燥涂层的方法和如此形成的涂层。

7. 发明授权

US09006365B2 Method of making polymeric bead from phosphorous acid containing monomers 有权
标题翻译：从含有亚磷酸的单体制备聚合物珠粒的方法
公开(公告)号：US09006365B2
公开(公告)日：2015-04-14
申请号：US13339480
申请日：2011-12-29
申请人： James C. Bohling , Jose Antonio Trejo-O'Reilly
发明人： James C. Bohling , Jose Antonio Trejo-O'Reilly
IPC分类号： C08F230/02 , C08F2/20
CPC分类号： C08F2/20 , C08F230/02 , C08F220/06 , C08F212/36
摘要： The present invention is a method for making a polymeric bead by suspension polymerization processes from a phosphoric acid monoester.
摘要翻译：本发明是由磷酸单酯通过悬浮聚合法制造聚合物珠粒的方法。

8. 发明授权

US08575262B2 Aqueous polymeric dispersion and method for providing improved adhesion 有权
标题翻译：水性聚合物分散体和提供改善粘合力的方法
公开(公告)号：US08575262B2
公开(公告)日：2013-11-05
申请号：US12460072
申请日：2009-07-13
申请人： James C. Bohling , Andrew Hejl , Alvin M. Maurice
发明人： James C. Bohling , Andrew Hejl , Alvin M. Maurice
IPC分类号： C08F220/04 , C08F230/02 , C08K5/3437
CPC分类号： C08F220/18 , C08F230/02 , C08F232/08 , C09J133/14 , C09J143/02
摘要： This invention provides an aqueous polymeric dispersion, the polymer including, as polymerized units: from 0.1 to 10%, by weight based on the weight of the polymer, monomer selected from the group consisting of strong carboxylic acid monomers, sulfonic acid monomers and phosphorous-containing acid monomers, and from 0.01 to 3%, by weight based on the weight of the polymer, a moiety including the structure, wherein X═CY, N, or P and Y, independently ═H, C, N, O, Cl, Br, F, Si, S, or P. Also, a method for forming the aqueous polymeric dispersion and a method for providing a coating having improved adhesion to a substrate, particularly to a metal substrate, is provided.
摘要翻译：本发明提供一种水性聚合物分散体，该聚合物包含聚合单元：基于聚合物重量的0.1至10重量％，选自强羧酸单体，磺酸单体和磷酸单体的单体，含有酸单体和0.01至3重量％，基于聚合物的重量，包括结构的部分，其中X = CY，N或P和Y，独立地为H，C，N，O，Cl Br，F，Si，S或P.此外，还提供了形成水性聚合物分散体的方法和提供具有改善的对基材，特别是金属基材的粘合性的涂层的方法。

9. 发明授权

US09493585B2 Polymeric bead composition comprising polymerized phosphorous-containing acid monomer 有权
标题翻译：包含聚合的含磷酸单体的聚合物珠组合物
公开(公告)号：US09493585B2
公开(公告)日：2016-11-15
申请号：US13339459
申请日：2011-12-29
申请人： James C. Bohling , Jose Antonio Trejo-O'Reilly
发明人： James C. Bohling , Jose Antonio Trejo-O'Reilly
IPC分类号： C08G79/02 , C08G79/04 , C08K5/52 , C08F2/20 , C08K5/51 , C08F230/02
CPC分类号： C08F2/20 , C08F230/02 , C08G79/02 , C08G79/04 , C08K5/51 , C08K5/52 , Y10T428/2982
摘要： The present invention is a polymeric bead composition. More particularly the present invention is directed to a new polymeric bead composition formed by suspension polymerization processes from a phosphorous acid containing monomers.
摘要翻译：本发明是一种聚合物珠组合物。更具体地，本发明涉及通过来自含磷酸单体的悬浮聚合方法形成的新的聚合物珠组合物。

10. 发明授权

US09029465B2 Preparation of multistage latex polymer 有权
标题翻译：制备多级胶乳聚合物
公开(公告)号：US09029465B2
公开(公告)日：2015-05-12
申请号：US14234546
申请日：2012-07-25
申请人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan
发明人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan
IPC分类号： C08F275/00 , C09D151/00 , C08F2/00 , C08F2/22 , C08F265/04 , C08F265/06
CPC分类号： C08F275/00 , C08F2/001 , C08F2/22 , C08F265/04 , C08F265/06 , C09D151/003 , C08F220/18 , C08F220/36 , C08F230/02
摘要： The present invention relates to a process for preparing a multistage phosphorus acid functionalized latex polymer comprising the steps of: a) contacting a first acrylic monomer with a first phosphorus acid monomer under emulsion polymerization conditions to form a first stage polymer; then b) contacting the first stage polymer with a second acrylic monomer and a second phosphorus acid monomer under emulsion polymerization conditions to form the latex polymer. The latex polymer is useful as an absorbing polymer for pigment particles used, for example, in coatings formulations.
摘要翻译：本发明涉及一种制备多级磷酸官能化胶乳聚合物的方法，包括以下步骤：a）在乳液聚合条件下使第一丙烯酸类单体与第一种磷酸单体接触以形成第一级聚合物; 然后b）在乳液聚合条件下使第一阶段聚合物与第二丙烯酸类单体和第二种磷酸单体接触以形成胶乳聚合物。胶乳聚合物可用作用于例如涂料配方中的颜料颗粒的吸收聚合物。

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