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    • 6. 发明专利
    • DE69120250T2
    • 1996-10-10
    • DE69120250
    • 1991-03-18
    • HITACHI LTD
    • YASUTOMI YOSHIYUKIWATAHIKI SEIJISAKAI JUNJICHIBA AKIOMIYOSHI TADAHIKOSOBUE MASAHISA
    • C04B35/00C04B35/565C04B35/58C04B35/591C04B35/622C04B35/80C04B38/00C23C16/34C04B35/56C04B38/06C04B41/87
    • The present invention provides a composite ceramic structure of sintered ceramics having a porosity of 5 to 40 % by volume and, if necessary, a maximum pore size of 10 mu m or less comprising particles selected from the group consisting of grains and whiskers of at least one inorganic compound AB selected from the group consisting of carbides, nitrides, and oxides which are composed of an element A and an element B, where a difference in electronegativity between the element A and the element B is not higher than 1.7; or particles selected from the group consisting of grains and whiskers of an inorganic compound, between the components of which a difference in electronegativity is higher than 1.7, and having layers of the inorganic compound AB formed on the surfaces of said particles; where said particles are bonded one another with silicon nitride particles having an average particle size not more than 0.2 mu m. The composite ceramic structure is produced by sintering a shape composed of particles selected from the group consisting of grains and whiskers of at least one of the inorganic compound AB; or a shape composed of particles selected from the group consisting of grains and whiskers of an inorganic compound, between the components of which a difference in electronegativity is higher than 1.7, and having layers of the inorganic compound AB formed on the surfaces of said particles; in a gaseous atmosphere containing silicon and nitrogen to grow silicon nitride particles having an average particle size not higher than 0.2 mu m on the surfaces of said inorganic compound particles, thereby bonding said inorganic compound particles one another. A ceramic sintered shape highly accurate in dimension having a surface configuration which is a replica of the surface contour of a mold as a ceramic mechanical part of precision is also proveded.
    • 8. 发明专利
    • DE69120250D1
    • 1996-07-18
    • DE69120250
    • 1991-03-18
    • HITACHI LTD
    • YASUTOMI YOSHIYUKIWATAHIKI SEIJISAKAI JUNJICHIBA AKIOMIYOSHI TADAHIKOSOBUE MASAHISA
    • C04B35/00C04B35/565C04B35/58C04B35/591C04B35/622C04B35/80C04B38/00C23C16/34C04B35/56C04B38/06C04B41/87
    • The present invention provides a composite ceramic structure of sintered ceramics having a porosity of 5 to 40 % by volume and, if necessary, a maximum pore size of 10 mu m or less comprising particles selected from the group consisting of grains and whiskers of at least one inorganic compound AB selected from the group consisting of carbides, nitrides, and oxides which are composed of an element A and an element B, where a difference in electronegativity between the element A and the element B is not higher than 1.7; or particles selected from the group consisting of grains and whiskers of an inorganic compound, between the components of which a difference in electronegativity is higher than 1.7, and having layers of the inorganic compound AB formed on the surfaces of said particles; where said particles are bonded one another with silicon nitride particles having an average particle size not more than 0.2 mu m. The composite ceramic structure is produced by sintering a shape composed of particles selected from the group consisting of grains and whiskers of at least one of the inorganic compound AB; or a shape composed of particles selected from the group consisting of grains and whiskers of an inorganic compound, between the components of which a difference in electronegativity is higher than 1.7, and having layers of the inorganic compound AB formed on the surfaces of said particles; in a gaseous atmosphere containing silicon and nitrogen to grow silicon nitride particles having an average particle size not higher than 0.2 mu m on the surfaces of said inorganic compound particles, thereby bonding said inorganic compound particles one another. A ceramic sintered shape highly accurate in dimension having a surface configuration which is a replica of the surface contour of a mold as a ceramic mechanical part of precision is also proveded.