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    • 9. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR INTEGRATED CIRCUIT DEVICE
    • JPS6467938A
    • 1989-03-14
    • JP22396387
    • 1987-09-09
    • HITACHI LTDHITACHI VLSI ENG
    • YOSHIDA SEIJI
    • H01L21/316H01L21/76
    • PURPOSE:To prevent crystal defects from generating in a semiconductor substrate near the end of a field insulating film at the time of thermal oxidation by thermally oxidizing it in an oxidative atmosphere containing at least phosphorus. CONSTITUTION:An SiO2 film 2, an Si3N4 film 3 are sequentially formed on a semiconductor substrate 1, the films 3, 2 are then sequentially etched to form an opening 4. Then, an Si3N4 film 5 and an SiO2 film 6 are sequentially formed on a whole surface. Thereafter, the insulating films 6, 5 are sequentially anisotropically etched to remain only on the sidewall of the opening 4, and with them as masks the substrate 1 is anisotropically etched to form a groove 1a. Then, with the films 3, 6 as oxide preventive films the substrate 1 is thermally oxidized in an oxidative atmosphere containing P. The formed field insulating film is formed of glass containing phosphorus, has a low melting point, a large fluidity, and alleviates a stress generated in the substrate near the end of the film, thereby preventing crystal defects from generating.