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    • 4. 发明专利
    • SEMICONDUCTOR DEVICE
    • JPS63115372A
    • 1988-05-19
    • JP26069086
    • 1986-11-04
    • HITACHI LTDHITACHI HARAMACHI SEMI CONDUCT
    • OKUBO TOSHIOTAKAHASHI KAZUYUKIKANEKO KAZUO
    • H01L29/872H01L29/47
    • PURPOSE:To prevent the breakdown of an interlayer insulation film due to hillocks and to improve reliability by a method wherein at least the part serving as the Schottky barrier electrode is constructed in two layers - the first layer made of viewer Al and the second layer made of Si-doped Al. CONSTITUTION:A lightly-doped N type Si substrate 1 is prepared. First, a ther mal oxide film (SiO2)2 generated over the surface is partly windowed by photoresist technique, and a viewer Al film 3 is formed thereon by evaporation (or sputtering). Next, a 2-3% Si-doped Al film 4 is formed over the whole surface and then etched in succession to produce wiring patterns. A plasma SiN film 6 is deposited as the underlayer film of an interlayer insulation film. Thereafter, the work undergoes contact alloying in dry O2 to form a Schottky barrier 7 between the viewer Al and the Si substrate. This process prevents the generation of voids of Al wirings and of hillocks and ensures the improve ment of the initial yield and the reliability. Since the underlayer Al is viewer Al, Schottky characteristics can be secured.
    • 7. 发明专利
    • METHOD FOR METALLIZATION TREATMENT
    • JPS61177717A
    • 1986-08-09
    • JP1856585
    • 1985-02-04
    • HITACHI MICROCUMPUTER ENGHITACHI LTD
    • KATO HIROSHIKOBAYASHI MASAMICHIOKUBO TOSHIO
    • H01L29/73H01L21/28H01L21/331H01L29/72
    • PURPOSE:To obtain strong binding between a metal and silicon by treating so as to cause a low-molecular-weight carbon layer adsorbed from vapor phase or liquid phase to lie between the substrate and the metal, thereby performing a metallization treatment having extremely strong carbide binding. CONSTITUTION:Element activation regions 12 having a PN junction semiconduc tor are formed on one primary surface of a silicon semiconductor substrate 11, and an aluminum electrode 13 making low resistance connection is formed on the surface of these regions. Coated with wax 14 on the surface, this struc ture is dipped in a mixture of hydrofluoric acid and nitric acid 15, and the reverse side of the substrate is applied with back etching. The semiconductor substrate 11 is taken out of the etchant 15, rinsed, dried up and dipped in a solution 16 for treating low carbon to dissolve and remove the wax 14. By this treatment, a thin, low-molecular-weight carbon film is formed on the reverse side of the substrate. After the substrate 11 is taken out, rinsed with an organic solvent, and dried, it is placed in an evaporation apparatus 18, a titanium, a nickel and a silver films are sequentially formed on the reverse side of th substrate, and this is alloyed in an inert gas.
    • 9. 发明专利
    • Manufacture of electronic device
    • 电子器件的制造
    • JPS61125149A
    • 1986-06-12
    • JP24603284
    • 1984-11-22
    • Hitachi Ltd
    • MATSUZAWA MANABUOKUBO TOSHIOURYU TAKESHIKOBAYASHI MASAMICHI
    • H01L29/78H01L21/3205H01L23/52
    • PURPOSE:To improve the accuracy of finishing of etching by forming a high melting-point metallic film body under the state, in which the film body occludes oxygen, onto a substrate, processing the film body to a required wiring pattern through dry etching and thermally treating it at 700 deg.C or higher. CONSTITUTION:A high-resistivity p type silicon layer 2 is shaped onto a low- resistivity p type silicon substrate 1, and a field oxide film is formed. The silicon layer 2 is exposed partially, and the surface of the substrate 1 is termally oxidized to shape a gate oxide film 3. A metallic molybdenum film 4 is formed onto the oxide film 3. A section not masked in the Mo film 4 is removed, and a Mo gate 4a is shaped. n type layers 7 are formed while using the Mo gate 4a and a peripheral field film 6 as masks. An inter-layer insulating film 8 is shaped onto the whole surface. The whole is annealed and treated in a N2 atmosphere at 900 deg.C. Al electrodes 9 brought into ohmic-contact with sourcedrain sections and an Al wiring 10 connected to the Mo gate are formed through Al evaporation and etching.
    • 目的:为了通过在薄膜体内吸附氧的状态下形成高熔点金属膜体来提高蚀刻精度,通过干蚀刻和热处理将膜体加工成所需的布线图案 在700摄氏度以上处理。 构成:将高电阻率p +型硅层2成形为低电阻率p +型硅衬底1,形成场氧化膜。 硅层2被部分曝光,并且衬底1的表面被定期氧化以形成栅极氧化膜3.在氧化物膜3上形成金属钼膜4.去除Mo膜4中未被掩蔽的部分 并且Mo门4a成形。 在使用Mo门4a和外围场膜6作为掩模的同时形成n +型层7。 层间绝缘膜8成形为整个表面。 整个退火并在900℃的N 2气氛中进行处理。 通过Al蒸发和蚀刻形成与源极区段欧姆接触的Al电极9和连接到Mo栅极的Al布线10。