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    • 5. 发明专利
    • Gel electrolyte and a secondary battery
    • 凝胶电解质和二次电池
    • JP2006261024A
    • 2006-09-28
    • JP2005079288
    • 2005-03-18
    • Hitachi LtdNof Corp日本油脂株式会社株式会社日立製作所
    • OKUMURA SOUBUNNISHIMURA SHINIWAYASU NORIOKONO KAZUSHIGEYOKOYAMA SHOICHIMIZUTANI MASAHITOITO TETSUYA
    • H01B1/06H01M10/05H01M10/0565
    • H01M10/0565H01M2300/0085
    • PROBLEM TO BE SOLVED: To provide a gel electrolyte having high ion conductivity and stability at high temperature with a high compliance to a large current when used as a battery electrolyte, and a secondary battery. SOLUTION: The secondary battery comprises a gel electrolyte which is composed of a polymer matrix obtained by polymerizing boric acid ester having a polymeric functional group as expressed by a formula (1) at the end portion, an electrolyte salt, and a non-aqueous solvent. Herin, Z 1 , Z 2 , Z 3 are polymeric functional group or hydrocarbon group having carbon number 1-10, and out of three groups Z 1 , Z 2 , Z 3 , the hydrocarbon groups with the carbon number 1-10 are included 1.0-2.5 in mol average. AO is oxy-alkylene group having carbon number 2-4, and l, m, n are average repeating number of oxy-alkylene group and are each independently 0-100, and l+m+n is 1-300, and B is boron atom. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有高离子电导率和在高温下的稳定性的凝胶电解质,当用作电池电解质时,具有高的依赖于大电流的凝胶电解质和二次电池。 解决方案:二次电池包括凝胶电解质,该凝胶电解质由通过在端部聚合具有由式(1)表示的聚合官能团的硼酸酯获得的聚合物基质,电解质盐和非电解质 - 水溶剂。 Herin,Z 1 ,Z 2 ,Z 3 是聚合官能团或碳数为1-10的烃基, Z 1 ,Z 2 ,Z 3 ,碳数为1-10的烃基的摩尔含量为1.0-2.5。 AO是碳数为2-4的氧亚烷基,l,m,n为氧亚烷基的平均重复数,各自为0〜100,l + m + n为1-300,B为 硼原子。 版权所有(C)2006,JPO&NCIPI