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    • 6. 发明专利
    • JPH05339705A
    • 1993-12-21
    • JP14594192
    • 1992-06-05
    • HITACHI LTD
    • WATANABE ATSUSHIIBE HIDEFUMISAGAWA WATARU
    • C23C14/16C23C14/22C23C14/32C23F15/00
    • PURPOSE:To secure the soundness of a metallic member, especially an atomic reactor structural member, and to prolong the service life of the member by easing the corrosion environment of the crevice of a metallic member. CONSTITUTION:The crevice corrosion rate of a metallic member largely depends on the concn. of an oxidizing agent inside and outside the crevice. Oxygen and hydrogen peroxide act as the main oxidizing agents in the atomic reactor. The metal ion, especially hexavalent Cr ion and hexavalent or heptavalent Mn ion, eluted from the base material of a metallic member has a strong oxidizing power and promotes the corrosion. The trivalent Cr ion or Mn ion is easily oxidized to the hexavalent or heptavalent ion, and hence the environment in the crevice is further made severe. Accordingly, a material capable of reducing Cr ion or Mn ion such as Pt and Pd is previously incorporated into the surface layer of the base material of the metallic member with the crevice surrounded by a corrosive environment. Consequently, the concn. of the Cr or Mn ion as the main oxidizing agent in the crevice is reduced, and the crevice corrosion of the metallic member is suppressed or prevented.