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    • 2. 发明专利
    • DE2852143A1
    • 1979-06-21
    • DE2852143
    • 1978-12-01
    • HITACHI LTD
    • KIMURA SHOICHITAKAHASHI TOSHIHIKOTAMURA ZENSUKE
    • C10K1/04C10K1/20C10K1/34
    • A high temperature, high pressure raw coal gas containing hydrogen sulfide, ammonia, and tarry matter, is purified by contacting the raw coal gas with solid particles thereby cooling the raw coal gas to a temperature suitable for hydrogen sulfide removal and at the same time depositing the tarry matter onto the solid particles by condensation to recover the tarry matter from the raw coal gas, removing the hydrogen sulfide from the cooled and substantially tar-free coal gas, expanding the raw coal gas to a pressure suitable for ammonia decomposition, heating the expanded raw coal gas to a temperature suitable for ammonia decomposition by heat obtained by combusting the recovered tarry matter on the solid particles, thereby regenerating the solid particles for reuse, and then decomposing ammonia in the raw coal gas, thereby removing ammonia therefrom. A process for efficiently purifying raw coal gas by removing tarry matter, hydrogen sulfide and ammonia, including effectively utilizing the recovered tarry matter to produce heat while also effectively utilizing the energy obtained by expanding the coal gas through a pressure-reducing means such as an expansion turbine.
    • 4. 发明专利
    • DE2759049A1
    • 1978-07-06
    • DE2759049
    • 1977-12-30
    • HITACHI LTD
    • KIMURA SHOICHITAKAHASHI TOSHIHIKO
    • C01B17/04
    • Hydrogen sulfide is removed from coal gas for gas turbine power generation and recovered as elemental sulfur by contacting a coal gas formed by gasification of coal with an iron oxide catalyst, thereby removing hydrogen sulfide from the coal gas and obtaining a desulfurized coal gas; regenerating the iron oxide catalyst of lowered desulfurization activity, thereby obtaining a regeneration off-gas containing sulfur dioxide; converting a portion of said desulfurized coal gas to reducing gas containing hydrogen; reacting the hydrogen of the resulting reducing gas with the sulfur dioxide in a portion of said regeneration off-gas, thereby producing hydrogen sulfide; reacting the resulting hydrogen sulfide with the sulfur dioxide in the remaining portion of the regeneration off-gas in the presence of a catalyst, thereby producing a gas containing elemental sulfur, and recovering the elemental sulfur from the gas.