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    • 4. 发明专利
    • JPH05335108A
    • 1993-12-17
    • JP14028792
    • 1992-06-01
    • HITACHI LTDHITACHI CHEMICAL CO LTD
    • NIIHORI HIROSHIASAI TADAMICHIOGAWA TOSHIO
    • H01C7/00H01C17/06
    • PURPOSE:To provide a resistance composition which gives a thick film resistor having stabilized resistance characteristics by a method wherein a wide resistance region is obtained by uniformly dispersing microscopic conductive particles into the glass matrix of a resistor after it has been calcined. CONSTITUTION:A metal boride of 0.1 to 50wt.% having the y/x, indicated by MxBy (M indicates a metal element, and B indicates a boride, and x and y indicate integers), in excess of 6, and glass frit, containing the glass component of 1 to 50 pts.wt. in terms of tantalum oxide, of 50 to 99.9 pts.wt. are mixed. Further, an organic vehicle is added, and a thick film resistance composition is obtained. The surface of an inorganic substrate is coated with the above- mentioned composition, and a rasistance film of prescribed shape is formed. Then, aforesaid material is calcined at 700 to 950 deg.C in an inert gas atmosphere. As a result, the tantalum boride particles of 1mum or smaller in diameter are precipitated into the glass matrix, or a conductive path can be formed, the resistivity of the resistor can be made uniform, and resistance characteristics can also be stabilized.