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    • 1. 发明申请
    • IMPROVED-CARE WASHING PROCESS FOR TEXTILES
    • 洗涤程序具有改进的护理性能CLOTHES
    • WO1997049789A1
    • 1997-12-31
    • PCT/EP1997003049
    • 1997-06-12
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENBÖCKER, MonikaENGELS, ThomasJEBENS, HeikeSCHAMBIL, FredARTIGA-GONZALEZ, Rene-AndresNICKEL, DieterMEINE, Georg
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C11D01/66
    • C11D3/0094C11D1/22C11D1/662C11D10/04C11D11/0017D06F35/006
    • Even high-grade textiles like silk, viscose or wool can be carefully washed by machine by the use of a foaming powdered to granular washing agent with an apparent density of 300 to 1000 g/l, containing one or more highly foaming tensides, especially alkyl glycosides and/or low-ethoxylated alkyl ether sulphates in quantities such that, when used in a concentration of 2.5 to 8 g/l at washing temperatures of 60 DEG C at most, the agent forms a foam which, measured by the SSF method, meets the stability critera: (1) no holes occur in the foam column with samples in the useful concentration range from 2.5 to 8 g/l (water hardness 16 DEG d, temperature 16 DEG C); (ii) the foam column has a height of at least 30 cm and at the most 40 cm after 120 seconds' foaming time; (iii) the theoretical foam height after the application of a 50 g weight is no less than 28 cm, where the difference between the maximum foam height a fter 120 seconds and the theoretical foam height is less than 4.3 cm, and/or (iv) the drop in the foam height per unit time after the application of the weight is less than 2 cm per minute.
    • 通过施加发泡粉末形式到粒状洗涤剂具有300至1000的堆积密度克/升,其包含一个或多个高发泡的表面活性剂,特别是烷基糖苷和/或量niedrigethoxylierte烷基醚,对于2.5的浓度的应用的装置 -C形成至8克/升在从最大60°,其泡沫的洗涤液的温度 - 由SSF方法测定 - 满足以下的稳定性标准:(I)发生在在2.5应用浓度范围的样本至8克/升 (水硬度16°D,温度16℃)在泡沫塔和没有空隙(ii)所述泡沫列具有后的高度的至少30厘米,但至多40厘米,和(iii)的理论泡沫高度放置120秒后发泡时间 50克重量不小于28厘米,其中所述最大泡沫高度之间120秒后的和发泡时间th的差值 比4.3厘米少eoretischen泡沫高度和/或(iv)按重量支撑每单位时间的泡沫高度的降低是每分钟小于2厘米,还高质量织物,例如丝绸,人造丝或羊毛的织物可洗涤调理机。
    • 4. 发明申请
    • SOIL RELEASE POLYESTERS
    • 污聚酯
    • WO1995032232A1
    • 1995-11-30
    • PCT/EP1995001786
    • 1995-05-11
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENBIRNBRICH, PaulMEINE, GeorgPASTURA, AmerigoSCHAMBIL, Fred
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C08G63/672
    • C08G63/672C11D3/0036C11D3/3715
    • Soil release polyesters have the general formula (I): X-(O-(CHR-)a)b[O-OC-Ph-CO-(CHR-)o)p]yO-Y, in which a equals 2 to 8, b equals 1 to 300, o equals 2 to 8, p equals 1 to 300, y equals 1 to 500, Ph stands for an o-, m- or p-phenylene residue that may bear 1 to 4 substituents selected among alkyl residues with 1 to 22 C atoms, sulfonic acid groups, carboxyl groups and their mixtures, R stands for hydrogen, an alkyl residue with 1 to 22 C atoms or their mixtures, X and Y represent independently from each other hydrogen, alkyl- and arylmonocarboxylic acid residues with 5 to 32 C atoms, hydroxymonocarboxylic acid residues with 2 to 22 C atoms and an oligomerisation degree from 1 to 100 or dicarboxylic acid semi-ester residues whose second carboxylic acid group is esterified with an alcohol A-(OCHZCH2)d-OH, in which A stands for an alkyl or alkenyl residue with 1 to 2 C atoms and d equals 1 to 40, provided that X and Y be not both hydrogen; when R stands for hydrogen or an alkyl residue with 1 C atom, a and/or o equals 2 and b and/or p equals 1. Incorporated to washing and cleaning agents, these polyesters effectively remove greasy soils.
    • 通式(I)的污垢解脱聚酯:X-(O-(CHR-)A)B [O-OC-PH-CO-(O-(CHR-)O)p] Y 2 O-Y,其中a是一个数 为2〜8,b为1〜300的数,o为2〜8的数,p是一个从1到300,y是一个从1到500,Ph是邻 - ,间 - 或对亚苯基 其可具有选自具有1至22个碳原子,磺酸基团,羧基基团及其混合物的烷基中的1〜4个取代基,R选自氢,烷基具有1至22个碳原子以及它们的混合物,和X和 Y独立地选自碳原子数5〜32个氢,烷基和Arylmonocarbonsäureresten,具有2至22个碳原子和至100和Dicarbonsäurehalbesterresten其第二羧酸基团与醇A-(OCHZCH2)D-OH度为1低聚Hydroxymonocarbonsäureresten选择 被酯化,其中一个是烷基或具有8至22个C原子的链烯基,Z是氢或烷基碳原子数1〜2和DE 的1至40组INE数,条件是X和Y不同时为氢时,R是氢或具有1个碳原子,和/或O 2和B和/或p为1,被选择为一烷基 在洗涤剂和清洁剂,对油污非常有效的结合。
    • 7. 发明申请
    • PROCESS FOR PRODUCING PARAFFIN-CONTAINING FOAM REGULATORS
    • 用于生产含石蜡泡沫调节
    • WO1998009701A1
    • 1998-03-12
    • PCT/EP1997004714
    • 1997-08-29
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENARTIGA GONZALEZ, Rene-AndresLIPHARD, MariaKRAUS, IngridHAMMELSTEIN, Stefan
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • B01D19/04
    • C11D17/065B01D19/0404C11D3/0026C11D3/08C11D3/18C11D3/225C11D3/32C11D3/3761C11D11/0088B01D19/0409B01D19/0413
    • A process is disclosed for producing stable foam regulator compositions which during the production of particulate washing and cleaning agents withstand the mixing process with the remaining constitutive elements of the washing or cleaning agents without loosing their granulated structure and without dusting, but which nevertheless are quickly dissolved, without leaving any residues, in the conditions of use, releasing the foam-inhibiting combination of active substances, which in particular include a low melting paraffin. For this purpose, a progressive granulation process is carried out in a granulation mixer, in that 50 to 100 parts by weight of an inorganic carrier salt, optionally with up to 5 parts by weight of an anionic and/or non-ionic cellulose ethers are intensively mixed, 1 to 10 parts by weight of an aqueous alkali silicate and/or polymer polycarboxylate solution are added while granulation is pursued, and finally 10 parts by weight of a an antifoaming combination of active substances heated up to a temperature in the 70 DEG C to 180 DEG C range is added.
    • 一种制备它的生产颗粒状洗涤剂和清洁剂与其他洗涤剂或清洁组合物组分混合过程中的不破坏它们的粒状结构和无粉尘的形成,但迅速溶解和不留应用条件下的残存活稳定的泡沫调节剂的制剂,并且所述泡沫活性成分组合过程中,向其中 特别应包括低熔点石蜡,释放是发展。 这是通过在造粒混合器中进行的事实基本上实现的,积聚在这样一种方式,为50〜100重量份的无机载体盐的量,任选地集中具有高达5份的量(重量)的阴离子型和/或非离子型纤维素醚的混合,用进一步制粒 重量的含水碱金属硅酸盐和/或聚羧酸溶液中的1至10份的量被添加,然后(重量)的加热的添加10份至的范围内,以180℃,消泡剂的温度从70℃。