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1. 发明专利

CA2087921A1 THIOCHROMENONE DERIVATIVES AS ANTIDOTES, AND HERBICIDES CONTAINING THEM 未知
公开(公告)号：CA2087921A1
公开(公告)日：1993-07-24
申请号：CA2087921
申请日：1993-01-22
申请人： HAGEN HELMUT , RAATZ PETER , WALTER HELMUT , LANDES ANDREAS , BASF AG
发明人： HAGEN HELMUT , RAATZ PETER , WALTER HELMUT , LANDES ANDREAS
IPC分类号： A01N25/32 , A01N43/18 , C07D335/06
摘要： O.Z. 0050/42969 Thiochromenone derivatives as antidotes, and herbicides containg them Herbicidal agents containing at least one thiochromenone of the formula I where n is 1, 2, 3 or 4, and the radicals R3 may have different meanings when n is > 1; R1 is hydrogen; cyano; halogen; substituted or unsubstituted alkyl, aryl or hetaryl; a group -XR4 or a group -COYR4, where X is oxygen, sulfur and NR5, Y is oxygen and NR5, R4 is one of the following groups: hydrogen; formyl; alkyl; cycloalkyl; alkylcarbonyl; cycloalkylcarbonyl; alkylsulfonyl; cycloalkylsulfonyl; substituted or unsubstituted aryl, hetaryl, arylcarbonyl, hetarylcarbonyl, arylsulfonyl or hetarylsulfonyl; and R5 is hydrogen or substituted or unsubstituted alkyl, aryl or hetaryl; O.Z. 0050/42969 R2 is hydrogen; cyano; nitroso; nitro; halogen; substituted or unsubstituted alkyl, alkoxy, alkylthio, aryl or hetaryl; a group -NR4R5 or a group -COYR4, where Y, R4 and R5 have the above meanings; R3 is hydrogen; cyano; halogen; substituted or unsubstituted alkyl, aryl or hetaryl; a group -YR4, a group -COYR4, a group -COR6 or a group -SO2R7, where Y and R4 have the above meanings; R6 is one of the following groups: hydrogen; alkyl; cycloalkyl; substituted or unsubstituted aryl or hetaryl; and R7 is hydrogen; alkyl; cycloalkyl; substituted or unsubsti tuted aryl or hetaryl; or a group -NR4R5, where R4 and R5 have the above meanings, and the plant-tolerated salts of those compounds I in which one or several of the substituents denote an acidic or basic group, and at least one herbicidal active ingredient.

2. 发明专利

CA2017800A1 DERIVATIVES OF QUINOLINE FUSED TO A FIVE-MEMBERED HETEROCYCLIC RING 未知
公开(公告)号：CA2017800A1
公开(公告)日：1990-12-01
申请号：CA2017800
申请日：1990-05-30
申请人： BRILL GUNTER , HAGEN HELMUT , WESTPHALEN KARL OTTO , WUERZER BRUNO
发明人： BRILL GUNTER , HAGEN HELMUT , WESTPHALEN KARL-OTTO , WUERZER BRUNO
IPC分类号： A01N43/52 , A01N43/76 , A01N43/90 , C07D471/04 , C07D498/04 , A61K31/47
摘要： O.Z. 0050/40871 Quinoline derivatives fused to a five-membered heterocyclic ring and of the formula where R1 is hydrogen, halogen, carboxyl or substituted or unsubstituted alkyl, Y is nitrogen or C-R2, where R2 is hydrogen, halogen, hydroxyl, alkoxy, alkylthio, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted benzyl, phenethyl, phenyl or naphthyl, or a substituted or unsubstituted 5- or 6-membered heterocyclic ring with one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, X is oxygen or N-R3, R3 being hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl or substituted or unsubstituted benzyl, processes for their manufacture and their use for combating unwanted plant growth.

3. 发明专利

CA1297879C FLUORALKYL-SUBSTITUTED QUINOLINE DERIVATIVES AND THEIR USE FOR CONTROLLING UNDESIRABLE PLANT GROWTH 未知
公开(公告)号：CA1297879C
公开(公告)日：1992-03-24
申请号：CA539314
申请日：1987-06-10
申请人： HAGEN HELMUT
发明人： HAGEN HELMUT , EICHENAUER ULRICH , KOHLER ROLF-DIETER , PLATH PETER , LIESE-SAUER THOMAS , EICKEN KARL , WUERZER BRUNO , MEYER NORBERT
IPC分类号： A01N43/42 , C07D215/48 , A01N43/38
摘要： BASF Aktiengesellschaft O.Z. 0050/38498 Fluoroalkyl-substituted quinoline derivatives of the formula where R1 is chlorine. fluorine, hydroxyl, O?Met?, C1-C4-alkoxy or a radical of the formula , R2 and R3 independently of one another are each hydrogen, C1-C3-alkyl or C1-C3-fluoroalkyl, R4 is fluorine, chlorine or bromine, with the proviso that one or both of the radicals R2 and R3 are C1-C3-fluoroalkyl. herbicides containing these compounds as active ingredients, and their use for controlling unwanted plant growth.

4. 发明专利

CA2040939A1 2-AMINO-4-TRICHLOROPYRIDINE DERIVATIVES 未知
公开(公告)号：CA2040939A1
公开(公告)日：1991-10-24
申请号：CA2040939
申请日：1991-04-22
申请人： HAGEN HELMUT , ZIEGLER HANS , PFISTER JUERGEN , NILZ GERHARD , LORENZ GISELA , DRESSEL JUERGEN
发明人： HAGEN HELMUT , ZIEGLER HANS , PFISTER JUERGEN , NILZ GERHARD , LORENZ GISELA , DRESSEL JUERGEN
IPC分类号： C05G3/90 , C07D213/74 , C07D213/75 , C07D213/76 , C07D401/04 , C07F9/58 , C07D213/72 , C05C1/00 , C07D413/12
摘要： O.Z. 0050/41556 2-Amino-4-trichloromethyl-pyridines of the general formula I I, where R1 is hydrogen or C1-C8-alkyl, R2 is C1-C8-alkyl, C5-C8-cycloalkyl, C2-C4-alkenyl or phenyl, benzyl or phenylsulfonyl, -CX-R3, -SO2R3 or -PX(OR4)2 or R1 and R2 together form =CR5R6 or -CO-Z-CO-, X is oxygen or sulfur, R3 is C1-C20-alkyl, C2-C6-alkenyl, amino, C1-C6-alkylamino, di-C1-C6-alkylamino, morpholino, piperidino, pyrazolidino or C1-C8-alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino, R4 is C1-C8-alkyl, C1-C8-haloalkyl or substituted or unsubstituted phenyl, R5 is hydrogen, C1-C4-alkyl or substituted or unsubstituted phenyl, R6 is substituted or unsubstituted phenyl, Z is substituted or unsubstituted ethylene which may be part of a substituted or unsubstituted cycloalkyl or cycloalkylene radical, substituted or unsubstituted ethenylene which may be part of a substituted or unsubstituted aromatic or heteroaromatic ring, and Z is not part of an unsubskituted phenyl radical, agriculturally useful salts thereof, processes for their preparation and the use thereof as nitrification inhibitors.

5. 发明专利

CA2020416A1 3-ANILINOBENZOISOTHIAZOLES AND FUNGICIDES CONTAINING THESE 未知
公开(公告)号：CA2020416A1
公开(公告)日：1991-01-06
申请号：CA2020416
申请日：1990-07-04
申请人： SCHUBERT JUERGEN , WILD JOCHEN , HAGEN HELMUT , NILZ GERHARD , SAUTER HUBERT , AMMERMANN EBERHARD , LORENZ GISELA
发明人： SCHUBERT JUERGEN , WILD JOCHEN , HAGEN HELMUT , NILZ GERHARD , SAUTER HUBERT , AMMERMANN EBERHARD , LORENZ GISELA
IPC分类号： A01N43/80 , C07D275/04
摘要： O.Z. 0050/40923 3-Anilinobenzoisothiazoles of the formula I, where X is hydrogen, NO2, CN, halogen, SO2-alkyl, alkyl, cycloalkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, or phenoxy or phenylthio, each of which is unsubstituted or substituted, m is an integer from 1 to 4, R1 is hydrogen, halogen, alkoxy, haloalkyl, alkylthio, haloalkoxy, or phenoxy, phenylthio, benzyloxy or benzylthio, each of which is unsubstituted or substituted, R2 and R3 are hydrogen, NO2, halogen, CN, alkyl, SO2-alkyl, haloalkyl, SO2NR5R6, haloalkoxy, COOR5 or CONR5R6, R4 is hydrogen, COOR7, CONR5R6, CHO, COR7 or SO2R7, R5 and R6 are hydrogen or alkyl, R7 is alkyl, haloalkyl, benzyl, or aryl which is unsubstituted or substituted, plant-tolerated salts thereof, and fungicides containing these compounds.

6. 发明专利

CA2128951A1 PREPARATION OF AROMATIC CARBOXYLIC ACIDS 未知
公开(公告)号：CA2128951A1
公开(公告)日：1995-02-06
申请号：CA2128951
申请日：1994-07-27
申请人： HAGEN HELMUT , GULDNER ANDREAS
发明人： HAGEN HELMUT , GULDNER ANDREAS
IPC分类号： B01J27/02 , B01J23/22 , C07B41/08 , C07B61/00 , C07C51/275 , C07C63/00 , C07D215/48 , C07D209/42 , C07D209/44 , C07D217/26 , C07D261/20 , C07D263/56 , C07D275/04 , C07D277/64 , C07D307/79 , C07D333/54
摘要： Preparation of Aromatic Carboxylic Acids of the disclosure: Preparation of aromatic carboxylic acids of the formula I Ar(COOH)n (Ar = isoaromatic or heteroaromatic radicals, n = 1 to 4) by oxidation of a compound II Ar(CH3)n II using an oxidizing nitrogen/oxygen compound (III) in the presence of sulfuric acid and a vanadium compound (IV) at from 120.degree. to 180.degree.C in the liquid phase, in which for each mole of compound II present in the reaction mixture, from 20 to 100 mol% of vanadium compound (IV) are available for the oxidation.

7. 发明专利

CA2024865A1 PREPARATION OF 3-METHYLQUINOLINE-8-CARBOXYLIC ACID 未知
公开(公告)号：CA2024865A1
公开(公告)日：1991-03-10
申请号：CA2024865
申请日：1990-09-07
申请人： HAGEN HELMUT , DUPUIS JACQUES , ARBOGAST KARLHEINZ
发明人： HAGEN HELMUT , DUPUIS JACQUES , ARBOGAST KARLHEINZ
IPC分类号： C07D215/48
摘要： 3-Methylquinoline-8-carboxylic acid I (see formula I) and derivatives thereof are prepared by reacting o-toluidine II or a derivative thereof (see formula II) with methacrolein III (see formula III) in 70-90% strength by weight sulfuric acid in the presence of iodine or of an iodine compound, and oxidizing the resulting 3,8-dimethylquinoline IV or a derivative thereof (see formula IV) with nitric acid in a solution containing sulfuric acid, in the presence of vanadium ions, by a process in which, in the sulfuric acid-containing reaction solution of the 3,8-dimethylquinoline IV, the byproducts of the reaction are first decomposed by oxidation, the resulting 3,8-dimethylquinoline solution is concentrated by distillation and the 3,8-dimethylquinoline is then oxidized in situ with nitric acid to give the 3-methylquinoline-carboxylic acid.

8. 发明专利

CA2011537A1 2,3-SUBSTITUED 1,8 NAPHTHYRIDINES, THEIR PREPARATION AND THEIR USE AS ANTIDOTES 未知
公开(公告)号：CA2011537A1
公开(公告)日：1990-09-11
申请号：CA2011537
申请日：1990-03-06
申请人： HAGEN HELMUT , PFISTER JUERGEN , ZIEGLER HANS , WUERZER BRUNO , WESTPHALEN KARL OTTO
发明人： HAGEN HELMUT , PFISTER JUERGEN , ZIEGLER HANS , WUERZER BRUNO , WESTPHALEN KARL-OTTO
IPC分类号： A01N25/32 , A01N43/90 , C07D471/04 , C07D471/14
摘要： O.Z. 0050/40630 2,3-substituted 1,8-naphthyridines of the general formula I I, where: R is hydrogen or C1-C4-alkyl (n = 1 or 2) R1 is amino or substituted amino, XR5, where X is oxygen or sulfur and R5 is hydrogen, C1-C12-alkyl, C1-C4-alkoxycarbonyl-(C1-C4)-alkyl, C5-C8-cycloakyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl-(C1-C3)-alkyl, halogen, isothiorhonium halide, C1-C12-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, R2 is C1-C4-alkyl, cyano, carboxyl or a group or , where X is oxygen or sulfur, O.Z. 0050/40630 B is C1-C6-alkyl, C1-C6-alkoxy or alkylthio, amino, mono- or dialkylamino, where each alkyl radical is of 1 to 4 carbon atoms, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl, D is C1-C4-alkyl or NH2 and R6 is hydrogen, C1-C8-alkyl or alkylcarbonyl, or R1 and R2 together are -NH-N=C(CH2)-, and their environmentally tolerated salts with the proviso that R2 is not cyano, carboxyl or a carboxamido or carboxylic ester group when R1 is methyl, hydroxyl or amino (NH2), processes for their manufacture, and herbicidal agents containing a naphthyridine I as safener and at least one herbicidal active ingredient selected from the group consisting of a) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives and b) cyclohexenone derivatives.

9. 发明专利

DE1660159U 未知
公开(公告)号：DE1660159U
公开(公告)日：1953-07-30
申请号：DEH0010542
申请日：1953-03-12
申请人： HAGEN HELMUT
发明人： HAGEN HELMUT

10. 发明专利

CA2042111A1 HERBICIDES WHICH CONTAIN CYCLOHEXENONE DERIVATIVES AS HERBICIDAL ACTIVE INGREDIENTS AND NAPHTHALENE DERIVATIVES AS ANTIDOTES 未知
公开(公告)号：CA2042111A1
公开(公告)日：1991-11-10
申请号：CA2042111
申请日：1991-05-08
申请人： SAUPE THOMAS , KAST JUERGEN , MISSLITZ ULF , HAGEN HELMUT , NILZ GERHARD , PFISTER JUERGEN , WALTER HELMUT , LANDES ANDREAS
发明人： SAUPE THOMAS , KAST JUERGEN , MISSLITZ ULF , HAGEN HELMUT , NILZ GERHARD , PFISTER JUERGEN , WALTER HELMUT , LANDES ANDREAS
IPC分类号： A01N25/32 , A01N35/10 , A01N37/34 , A01N37/44 , A01N43/08 , A01N43/10 , A01N43/16 , A01N43/18 , A01N43/28 , A01N43/653 , A01N43/80 , A01N43/836 , A01N43/82 , A01N37/02 , A01N41/02 , A01N37/16 , A01N43/36
摘要： 900243 O.Z. 0050/41599 Herbicides which contain cyclohexenone derivatives as herbicidal active ingredients and naphthalene derivatives as antidotes Summary Herbicidal agents containing a naphthalene derivative I I (R = alkyl, alkylthio, haloalkyl, alkoxy, halogen, OH, NO2 and/or benzyl; m = 0, 1, 2 or 3; R3 = -CN, -C(NH2)NOH, -C(Z)TR5, , oder ; R4 = halogen, -NR7R9, -N=CH-R7, -NR7-SO2R9, COOR5, OH, or ; Z = O; S; T = O, -NR5; R5 = H, substituted or unsubstituted alkyl, phenyl or benzyl; R6 = substituted or unsubstituted phenyl; R7 = H, substituted or unsubstituted alkyl or phenyl; R8 = H, substituted or unsubstituted alkyl; R9 = substituted or unsubstituted alkyl, phenyl or a substituted or unsubstituted heteroaromatic structure; R10 = substituted or unsubstituted alkyl or phenyl, or together are a substituted alkylene or alkenylene chain, or a substituted or unsubstituted, fused benzene ring; R11, R12 = alkyl or, together with the common carbon atom, are cycloalkyl; B = H, substituted or unsubstituted alkyl, alkoxycarbonyl, phenyl or -NR7R8-) as antidote and one or more herbicidal active ingredient from the group of cyclohexenone derivatives.

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