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1. 发明申请

WO1998014522A1 REACTIVE DYES WITH A HETEROCYCLIC ANCHOR 审中-公开
标题翻译：由杂环锚活性染料
公开(公告)号：WO1998014522A1
公开(公告)日：1998-04-09
申请号：PCT/EP1997005041
申请日：1997-09-15
申请人： BASF AKTIENGESELLSCHAFT , ZAMPONI, Andrea , PATSCH, Manfred , HAGEN, Helmut , WALTHER, Bernd-Peter
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C09B62/503
CPC分类号： C09B62/503 , C09B62/4403
摘要： The invention concerns reactive dyes of formula (I) in which: a designates 1 or 2; b designates 0 or 1; Y stands for vinyl or a radical of formula C2H4Q, in which Q stands for a group which can be separated in alkaline reaction conditions; Het is the radical of a 5- or 6-member aromatic heterocyclic ring, which comprises between 1 and 3 heteroatoms, selected from the group comprising oxygen, sulphur and nitrogen; W, in the first instance, is the radical of a coupling component, a monoazo dye or additionally, if b = 0, of a disazo dye which can carry further fibre-reactive groups, or, in the second instance, the radical of a chromophore which optionally comprises other fibre-reactive groups and is derived from an optionally metallized mono- or disazo dye, a triphene dioxazine, an anthraquinone, a metallized formazan or a metallized phthalocyanine; and L and L each designate a bridge member. The invention further concerns a process for dyeing or printing substrates comprising hydroxy groups or nitrogen atoms using the novel dyes.
摘要翻译：式（I），其中的活性染料：a是1或2; b为0或1; Y为乙烯基或下式基团C2H4Q，其中Q是碱性的反应条件下的可拆卸的; 的Het基团具有选自由氧，硫和氮组成的组中的1〜3个杂原子的5-或6-元芳族杂环的; W的情况下，1）基团偶联组分的，单偶氮染料的或附加地，当b = 0时，双偶氮染料，其可带有另外的纤维反应性基团，或者在情况2）的基团，其任选地具有另外的纤维反应性基团，并从发色团的任选金属化的单 - 或二重氮染料，从三苯，蒽醌，金属化的甲臜或衍生的金属化酞菁; 且L <1>和L <2>的每一个代表桥构件和用于染色或印染含羟基的或含氮的使用新的染料基板的方法。

2. 发明申请

WO1993004057A2 HERBICIDES CONTAINING 3-AMINOBENZO[B]THIOPHENES AS AN ANTIDOTE 审中-公开
标题翻译：含有3-氨基苯甲酸（B）的硫脲作为抗氧化剂
公开(公告)号：WO1993004057A2
公开(公告)日：1993-03-04
申请号：PCT/EP1992001798
申请日：1992-08-07
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , NILZ, Gerhard , ROETSCH, Thomas , WALTER, Helmut , LANDES, Andreas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D333/68
CPC分类号： A01N25/32 , C07D333/66 , C07D333/68
摘要： Disclosed are herbicides containing at least one 3-aminobenzo[b]thiophene (I) with an antagonistic action (in which R1 = -COX or -COOX; X = H, halogen, optionally substituted amino, optionally substituted C¿1?-C10 alkyl, optionally sustituted C1-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, a 5/6-membered heterocyclic aromatic, optionally substituted phenyl or optionally substituted naphthyl; R?2 and R3¿ = H, CN, NO¿2?, SH, halogen, optionally substituted amino, optionally substituted C1-C10 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C2-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, optionally substituted phenyl, optionally substituted naphthyl or a 5/6-membered heterocyclic aromatic; R?4 to R7¿ = H, optionally substituted C¿1?-C10 alkyl, optionally substituted C2-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, an optionally substituted 5/6-membered heterocyclic aromatic, optionally substituted phenyl or optionally substituted naphthyl or R?4 + R5¿ and/or R6 + R7 form, together with the N-atom to which they are bound, a 5- to 7-membered ring), plus the basic salts of those compounds of formula (I) which carry at least one carboxyl, hydroxythiocarbonyl or sulphonic acid group and the acid salts of those compounds of formula (I) which contain a basic nitrogen atom, and at least one herbicidal substance selected (A) from the group comprising the cyclohexenone derivatives or (B) from the group comprising the 4-(hetero)aryloxyphenoxyacetic acid derivatives.

3. 发明申请

WO1992010094A1 HERBICIDAL AGENTS CONTAINING SUBSTITUTED 2-AMINOTHIOPHENE 审中-公开
标题翻译：含有取代的2-氨基苯基的除草剂
公开(公告)号：WO1992010094A1
公开(公告)日：1992-06-25
申请号：PCT/EP1991002287
申请日：1991-12-03
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , NILZ, Gerhard , WALTER, Helmut , LANDES, Andreas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： A01N25/32
CPC分类号： C07D409/04 , A01N25/32 , C07D333/38 , C07D333/68 , C07D409/12 , C07D417/12
摘要： Herbicidal agents contain as antagonistic compound at least one substituted 2-aminothiophene having formula (I), in which R1, R2 stand for H, CN, alkyl, halogen alkyl, if necessary substituted phenyl, CO-R?6 or R1 + R2¿ stand for a C¿3?-C6 alkylene chain, upon which a benzene ring, if necessary substituted, may be annulated, a C2-C3 alkylene chain broken by -O- or -N(R?7¿)-, which may also carry 1-4 alkenyl residues or a group CO-N(R?7)-CO; R3¿ stands for CN, if necessary substituted -C(NH¿2?)=N-C6H5, -C(NH3?+Hal-)=N-C¿6H5, CX-R6; Hal stands for halogen; R4 stands for H, alkyl, alkenyl, if necessary substituted phenyl, if necessary substituted triazin, -PX(OR8)2, -CX-R9, -SO2R10, -SO2-NHR10, -CX-N(R?7)-CY-R8¿, -CX-N(R7)-SO2-R?11 or R3=R4¿ stand for CO-O-CO; R5 stands for H, alkyl, -CX-R9, -SO2-R10; X, Y stand for O, S; R7 stands for H, phenyl, alkyl; R8 stands for H, alkyl, if necessary substituted phenyl; R9 stands for alkyl, halogen alkyl, alkenyl, halogen alkenyl, if necessary substituted cycloalkyl or cycloalkenyl, NH¿2?, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted phenyl or phenylamino; R?10¿ stands for alkyl, if necessary substituted phenyl; R11 stands for NH¿2?, alkylamino, dialkylamino, if necessary substituted pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl; R?4 + R5¿ stand for =CR12R13 or -CO-W-CO-; R12 stands for H, NH¿2?, alkylamino, cycloalkylamino; R?13¿ stands for NH¿2?, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted thienylamino, pyrrolidinyl, piperidinyl, morpholinyl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, or for an aromatic or heteroaromatic 5/6 membered cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are a basic salt of compound (I), in which R?3¿ stands for hydroxycarbonyl, hydroxythiocarbonyl, or an acid salt of compound (I) which contains a basic hydrogen atom, and at least one herbicidal active substance from (A) the group of 4-aryloxy- and 4-heteroaryloxy-phenoxyacetic acid derivates or from (B) the group of cyclohexan-1,3-dione derivates.

4. 发明申请

WO1997005124A1 BENZENE DERIVATIVES WITH A HETEROCYCLIC GROUP 审中-公开
标题翻译：由杂环REST苯衍生物
公开(公告)号：WO1997005124A1
公开(公告)日：1997-02-13
申请号：PCT/EP1996003224
申请日：1996-07-22
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , PATSCH, Manfred , WALTHER, Bernd-Peter , ZAMPONI, Andrea
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D271/06
CPC分类号： C07D271/06 , C09B62/503
摘要： The invention concerns benzene derivatives of the formula (I) in which n is 0, 1, or 2, X is nitro or amino, Z is a direct bond or optionally substituted alkylene, Y is vinyl or a group of the formula C2H4-Q in which Q is hydroxy or a group which can be split off under alkaline reaction conditions, R and R are hydrogen, C1-C4 alkyl, C1-C4 alkoxy, halogen, nitro, amino, hydroxysulphonyl or a group Z-SOn-Y in which n, Z and Y are as defined above and Het is a heterocyclic ring. Such benzene derivatives are suitable for use in the production of dyes.
摘要翻译：式（I），其中n为0，1或2所述的苯衍生物，X是硝基或氨基，Z为直接键或任选取代的C1-C6亚烷基，Y为乙烯基或下式基团C2H4-Q，其中Q为羟基，或碱性反应条件下可拆卸，R <1>和R <2>是氢，C1-C4烷基，C1-C4烷氧基，卤素，硝基，氨基，羟基磺酰基或下式基团ZS（O）n，其中的 N，Z和Y具有上述含义并且Het是基团的杂环的。新的苯衍生物应该适合在用于生产染料的有利的方式。

5. 发明申请

WO1992010480A1 SUBSTITUTED 5-AMINOPYRAZOLS 审中-公开
标题翻译：取代的5-AMINOPYRAZOLS
公开(公告)号：WO1992010480A1
公开(公告)日：1992-06-25
申请号：PCT/EP1991002286
申请日：1991-12-03
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , NILZ, Gerhard , WALTER, Helmut , LANDES, Andreas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D231/38
CPC分类号： C07D403/04 , A01N25/32 , C07D231/40
摘要： Substituted 5-aminopyrazols have formula (I), in which R1 stands for C¿1?-C8-alkyl, C1-C8-hydroxyalkyl, phenyl, that can also carry 1-3 of the following residues: halogen, nitro, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio or -NR?6R7¿, and that can in addition carry as many halogen atoms as necessary for the total number of residues to be 5; R6, R7 stand for H, C¿1?-C4-alkyl; R?2¿ stands for H, C¿1?-C4-alkyl, C1-C4-halogen alkyl; R?3¿ stands for CN, -CO-R?8, -CS-R8; R8¿ stands for OH, C¿1?-C4-alkoxy, NH2, C1-C4-alkylamino, di-(C1-C4)-alkylamino; R?4, R5¿ stand for H, C¿1?-C4-alkyl, -PX(OR?9)¿2, -SO2-R?9, -CX-R10¿, -CX-NH-CY-R9, CX-NH-SO¿2-R?11; X, Y stand for O, S; R9 stands for one of the substituents named under R1; R10 stands for C¿1?-C20-alkyl, C1-C4-alkoxy, if necessary substituted phenyl, NH2; R?11¿ stands for NH¿2?, C1-C4-alkylamino, di-(C1-C4)-alkylamino, pyrolidinyl, piperidinyl, morpholinyl; R?4 and R5¿ together represent a group =CR12R13 or -CO-W-CO; R12 stands for H, NH¿2?, C1-C4-alkylamino or C3-C8-cycloalkylamino; R?13¿ stands for NH¿2?, C1-C4-alkylamino, di-(C1-C4)alkylamino, C3-C8-cacloalkylamino, pyrrolidin-1-yl, pipieridin-1-yl, morpholin-4-yl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, a 5 or 6 membered, 1,2-C linked aromatic or heteroaromatic bridge, if necessary substituted, or a 5 or 6 membered, 1,2-C linked cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are the basic salts of such compounds (I), in which R?3¿ stands for a hydroxycarbonyl or hydroxythiocarbonyl group, and the acid salts of such compounds (I), containing a basic nitrogen atom, with the exception of 1-phenyl- and 1-methyl-4-cyano-5-(acylamino)-pyrazol, 1-methyl-4-cyano-5-(chloromethylcarbonylamino)-pyrazol, 1-methyl-4-cyano-5-(phenylcarbonylamino)-pyrazol, 1-methyl-4-cyano-5-(p-chlorophenylcarbonylamino)-pyrazol, as well as the compounds (I), in which R1 stands for a methyl, phenyl, 4-chlorophenyl or 4-nitrophenyl group, R2 stands for hydrogen, a methyl or trifluoromethyl group, R3 stands for a cyano group and R?4 and R5¿ simultaneously stand for hydrogen. Also disclosed are herbicides that contain 2-(4-heteroaryloxy)- and 2-(4-aryloxy)- phenoxyacetic acid or propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active substances and substituted 5-aminopyrazols I' as antidotes, as well as the salts of I', if acid terminal groups or basic nitrogen atoms are present.

6. 发明申请

WO1992010500A1 PYRIDO-ANELLATED 4-OXO-4H-BENZOPYRANS, A METHOD OF PREPARING THEM, AND THEIR USE AS ANTIDOTES 审中-公开
标题翻译：吡咯烷-4-氧代-4H-苯并噻吩，其制备方法及其作为抗体的使用
公开(公告)号：WO1992010500A1
公开(公告)日：1992-06-25
申请号：PCT/EP1991002267
申请日：1991-11-29
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , NILZ, Gerhard , WALTER, Helmut , LANDES, Andreas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D491/052
CPC分类号： C07D491/04 , A01N25/32
摘要： Disclosed are pyrido-anellated 4-oxo-4H-benzopyrans (I) (in which m = 0, 1 or 2; and R?1, R6 and R7¿ are as defined in the description), as well as salts of compound (I), and herbicides containing the 2-(4-heteroaryloxy)- and 2-(4-aryloxy)phenoxyacetic acid derivatives or cyclohexenone derivatives as herbicidally active substances and pyrido-anellated 4-oxo-4H-benzopyrans (I') as antidotes.

7. 发明申请

WO1992010489A1 2-AMINO-4-OXO-4H-BENZOPYRANS, A METHOD FOR PREPARING THEM, AND THEIR USE AS ANTIDOTES 审中-公开
标题翻译： 2-氨基-4-氧代-4H-苯并吡喃，其制备方法及其作为抗体使用
公开(公告)号：WO1992010489A1
公开(公告)日：1992-06-25
申请号：PCT/EP1991002268
申请日：1991-11-29
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , NILZ, Gerhard , WALTER, Helmut , LANDES, Andreas , FREUND, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D311/22
CPC分类号： C07D311/22 , A01N25/32
摘要： Disclosed are 2-amino-4-oxo-4H-benzopyrans (I) (in which m = 0, 1 or 2; and R1 to R4 are as defined in the description), as well as salts of compound (I), and herbicides containing the 2-(4-heteroaryloxy)- and 2-(4-aryloxy) phenoxyacetic acid derivatives and/or cyclohexenone derivatives as herbicidally active substances, and 2-amino-4-oxo-4H-benzopyrans (I') as antidotes.

8. 发明申请

WO1992008719A1 SUBSTITUTED PYRIDO[2,3-d]PYRIMIDIN-2,4(1H,3H)-DIONES 审中-公开
标题翻译：取代的吡啶并[2,3-d]嘧啶-2,4（1H，3H） - 酮
公开(公告)号：WO1992008719A1
公开(公告)日：1992-05-29
申请号：PCT/EP1991002055
申请日：1991-10-30
申请人： BASF AKTIENGESELLSCHAFT , HAGEN, Helmut , RAATZ, Peter , WALTER, Helmut , LANDES, Andreas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D471/04
CPC分类号： C07D471/04 , A01N25/32
摘要： Pyrido[2,3-d]pyrimidin-2,4(1H,3H)-diones are disclosed, having formulas (Ia) and (Ib), in which R?1 and R2¿ stand for H, substituted or unsubstituted alkyl, cycloalkyl; R3 stands for H, substituted or unsubstituted alkyl; R4 stands for H, alkyl, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, cyano or aminocarbonyl; or R?3 and R4¿ represent together alkylene, alkenylene or 1,2-phenylene; R5 stands for H, alkyl, cyano, C(O)R7; R6 stands for alkyl, possibly substituted aralkenyl, aryl or hetaryl, CH¿2R?8, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, OH, SH, alkoxy, alkylthio, NH¿2?, alkylamino, NHCXR?9¿, NHSO¿2?R?10; R5 and R6¿ represent together substituted alkylene, alkenylene or 1,2-phenylene, which may also contain carbonyl or thiocarbonyl groups; R7 stands for H, alkyl, OH, SH, alkoxy, alkylthio, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, NH¿2? alkylamino, dialkylamino, possibly substituted aryl or arylamino; R?8¿ stands for halogen, OH, SH, alkoxy, alkylthio, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl or the formula (a); R9 stands for alkyl, halogen alkyl, NR?1R2 or OR1; R10¿ stands for alkyl, substituted or unsubstituted aryl; R11 stands for halogen, OH, SH, alkoxy, alkylthio, alkyl, nitro or amino; X stands for oxygen or sulphur. Also disclosed are the salts of compounds (Ia) and (Ib) that can be used in agriculture and that contain nitrogen or hydroxy substituants, as well as herbicides that contain 2-[4-(hetero)-aryloxy]-phenoxyacetic acid or propionic acid derivates and/or cyclohexenone derivates as active herbicidal substances and substituted pyrido[2,3-d[pyrimidin-2,4(1H, 3H)-diones, as well as the salts of (Ia) or (Ib) as antidotes when acid end groups or basic nitrogen atoms are present.

9. 发明专利

CA1297879C FLUORALKYL-SUBSTITUTED QUINOLINE DERIVATIVES AND THEIR USE FOR CONTROLLING UNDESIRABLE PLANT GROWTH 未知
公开(公告)号：CA1297879C
公开(公告)日：1992-03-24
申请号：CA539314
申请日：1987-06-10
申请人： HAGEN HELMUT
发明人： HAGEN HELMUT , EICHENAUER ULRICH , KOHLER ROLF-DIETER , PLATH PETER , LIESE-SAUER THOMAS , EICKEN KARL , WUERZER BRUNO , MEYER NORBERT
IPC分类号： A01N43/42 , C07D215/48 , A01N43/38
摘要： BASF Aktiengesellschaft O.Z. 0050/38498 Fluoroalkyl-substituted quinoline derivatives of the formula where R1 is chlorine. fluorine, hydroxyl, O?Met?, C1-C4-alkoxy or a radical of the formula , R2 and R3 independently of one another are each hydrogen, C1-C3-alkyl or C1-C3-fluoroalkyl, R4 is fluorine, chlorine or bromine, with the proviso that one or both of the radicals R2 and R3 are C1-C3-fluoroalkyl. herbicides containing these compounds as active ingredients, and their use for controlling unwanted plant growth.

10. 发明专利

CA2040939A1 2-AMINO-4-TRICHLOROPYRIDINE DERIVATIVES 未知
公开(公告)号：CA2040939A1
公开(公告)日：1991-10-24
申请号：CA2040939
申请日：1991-04-22
申请人： HAGEN HELMUT , ZIEGLER HANS , PFISTER JUERGEN , NILZ GERHARD , LORENZ GISELA , DRESSEL JUERGEN
发明人： HAGEN HELMUT , ZIEGLER HANS , PFISTER JUERGEN , NILZ GERHARD , LORENZ GISELA , DRESSEL JUERGEN
IPC分类号： C05G3/90 , C07D213/74 , C07D213/75 , C07D213/76 , C07D401/04 , C07F9/58 , C07D213/72 , C05C1/00 , C07D413/12
摘要： O.Z. 0050/41556 2-Amino-4-trichloromethyl-pyridines of the general formula I I, where R1 is hydrogen or C1-C8-alkyl, R2 is C1-C8-alkyl, C5-C8-cycloalkyl, C2-C4-alkenyl or phenyl, benzyl or phenylsulfonyl, -CX-R3, -SO2R3 or -PX(OR4)2 or R1 and R2 together form =CR5R6 or -CO-Z-CO-, X is oxygen or sulfur, R3 is C1-C20-alkyl, C2-C6-alkenyl, amino, C1-C6-alkylamino, di-C1-C6-alkylamino, morpholino, piperidino, pyrazolidino or C1-C8-alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino, R4 is C1-C8-alkyl, C1-C8-haloalkyl or substituted or unsubstituted phenyl, R5 is hydrogen, C1-C4-alkyl or substituted or unsubstituted phenyl, R6 is substituted or unsubstituted phenyl, Z is substituted or unsubstituted ethylene which may be part of a substituted or unsubstituted cycloalkyl or cycloalkylene radical, substituted or unsubstituted ethenylene which may be part of a substituted or unsubstituted aromatic or heteroaromatic ring, and Z is not part of an unsubskituted phenyl radical, agriculturally useful salts thereof, processes for their preparation and the use thereof as nitrification inhibitors.

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