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    • 8. 发明授权
    • Methods for forming a metallic damascene structure
    • 形成金属镶嵌结构的方法
    • US07319071B2
    • 2008-01-15
    • US10767764
    • 2004-01-29
    • Max F. HinemanStephen W. Russell
    • Max F. HinemanStephen W. Russell
    • H01L21/44
    • H01L21/76843H01L21/76807H01L21/76814H01L21/76879
    • In damascene process integration, a reducing plasma is applied after the etch stop or barrier layer is opened over a copper layer. Currently known methods for opening barrier layers suffer from the disadvantage that they cause at least some of the underlying copper to oxidize to copper oxide. Because copper oxide is selectively removed by subsequent wet cleaning, voids can form where damaged copper (e.g., copper oxide) is removed, thus compromising the reliability of metal-to-metal contact in vias. The present invention advantageously overcomes this and other disadvantages of the prior art through the use of a hydrogen plasma following the barrier layer opening step, which repairs damaged copper (e.g., reduces copper oxide to copper), thus preventing and/or diminishing defects in metal-to-metal contacts in vias and concomitantly improving the reliability of the same.
    • 在镶嵌工艺集成中,在蚀刻停止或阻挡层在铜层上打开之后施加还原等离子体。 目前已知的用于打开阻挡层的方法的缺点在于它们使至少一些下面的铜氧化成氧化铜。 由于随后的湿法清洗有选择地除去了氧化铜,所以可以在损坏的铜(例如氧化铜)被除去的地方形成空隙,从而损害通孔中金属对金属接触的可靠性。 本发明有利地通过在阻挡层开启步骤之后使用氢等离子体来克服现有技术的这个和其他缺点,其修复损坏的铜(例如,将铜氧化物还原为铜),从而防止和/或减少金属中的缺陷 金属触点,同时提高了其可靠性。
    • 9. 发明授权
    • Plasma reaction chamber liner consisting essentially of osmium
    • 基本上由锇组成的等离子体反应室衬里
    • US07293526B2
    • 2007-11-13
    • US11009282
    • 2004-12-10
    • Max F. HinemanLi Li
    • Max F. HinemanLi Li
    • H01L21/00
    • H01J37/32623H01J37/32633H01L21/31116H01L28/65Y10S156/916Y10S438/909
    • The invention encompasses a method of enhancing selectivity of etching silicon dioxide relative to one or more organic substances. A material comprising one or more elements selected from Group VIII of the periodic table is provided within a reaction chamber; and a substrate is provided within the reaction chamber. The substrate has both a silicon-oxide-containing composition and at least one organic substance thereover. The silicon-oxide-containing composition is plasma etched within the reaction chamber. The plasma etching of the silicon-oxide-containing composition has increased selectivity for the silicon oxide of the composition relative to the at least one organic substance than would plasma etching conducted without the material in the chamber. The invention also encompasses a plasma reaction chamber assembly. The assembly comprises at least one interior wall, and at least one liner along the at least one interior wall. The liner comprises one or more of Ru, Fe, Co, Ni, Rh, Pd, Os, W, Ir, Pt and Ti.
    • 本发明包括提高二氧化硅相对于一种或多种有机物质的选择性的方法。 包含选自元素周期表第Ⅷ族中的一种或多种元素的材料设置在反应室内; 并且在反应室内设置基板。 该基底具有含氧化硅的组合物和至少一种有机物质。 含氧化硅的组合物在反应室内进行等离子体蚀刻。 含有氧化硅的组合物的等离子体蚀刻相对于至少一种有机物质的组合物的氧化硅的选择性高于在室内没有材料进行的等离子体蚀刻。 本发明还包括等离子体反应室组件。 所述组件包括至少一个内壁和沿所述至少一个内壁的至少一个衬套。 衬套包括Ru,Fe,Co,Ni,Rh,Pd,Os,W,Ir,Pt和Ti中的一种或多种。
    • 10. 发明授权
    • Plasma reaction chamber liner comprising ruthenium
    • 包含钌的等离子体反应室衬里
    • US07131391B2
    • 2006-11-07
    • US10247971
    • 2002-09-20
    • Max F. HinemanLi Li
    • Max F. HinemanLi Li
    • H01L21/00C23C16/00
    • H01J37/32623H01J37/32633H01L21/31116H01L28/65Y10S156/916Y10S438/909
    • The invention encompasses a method of enhancing selectivity of etching silicon dioxide relative to one or more organic substances. A material comprising one or more elements selected from Group VIII of the periodic table is provided within a reaction chamber; and a substrate is provided within the reaction chamber. The substrate has both a silicon-oxide-containing composition and at least one organic substance thereover. The silicon-oxide-containing composition is plasma etched within the reaction chamber. The plasma etching of the silicon-oxide-containing composition has increased selectivity for the silicon oxide of the composition relative to the at least one organic substance than would plasma etching conducted without the material in the chamber. The invention also encompasses a plasma reaction chamber assembly. The assembly comprises at least one interior wall, and at least one liner along the at least one interior wall. The liner comprises one or more of Ru, Fe, Co, Ni, Rh, Pd, Os, W, Ir, Pt and Ti.
    • 本发明包括提高二氧化硅相对于一种或多种有机物质的选择性的方法。 包含选自元素周期表第Ⅷ族中的一种或多种元素的材料设置在反应室内; 并且在反应室内设置基板。 该基底具有含氧化硅的组合物和至少一种有机物质。 含氧化硅的组合物在反应室内进行等离子体蚀刻。 含有氧化硅的组合物的等离子体蚀刻相对于至少一种有机物质的组合物的氧化硅的选择性高于在室内没有材料进行的等离子体蚀刻。 本发明还包括等离子体反应室组件。 所述组件包括至少一个内壁和沿所述至少一个内壁的至少一个衬套。 衬套包括Ru,Fe,Co,Ni,Rh,Pd,Os,W,Ir,Pt和Ti中的一种或多种。