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    • 4. 发明授权
    • Aqueous dispersions, which can be hardened thermally and by using actinic radiation, method for the production thereof and their use
    • 水分散体,其可以热和通过使用光化辐射固化,其制备方法及其用途
    • US07022748B2
    • 2006-04-04
    • US10468886
    • 2002-03-21
    • Guido WilkeUlrike Röckrath
    • Guido WilkeUlrike Röckrath
    • C08L75/04C08L75/14C09D175/04C09J175/04C08J3/03
    • C09D175/16C08G18/6254C08G18/7837C08G18/807C08G18/8175C08G2150/20
    • Aqueous dispersions curable thermally and with actinic radiation, comprising (I) liquid, and/or highly viscous solid particles dimensionally stable under storage and application conditions, comprising (IA) a binder free of carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and at least one dispersive functional group, and (IB) at least one blocked polyisocyanate; (II) liquid, highly viscous and/or solid particles dimensionally stable under storage and application conditions, comprising at least one polyurethane (II) containing at least one isocyanate-reactive functional group, at least one functional group having at least one bond activatable with actinic radiation, and at least one dispersive functional group, and (III) at least one unsaturated constituent which is free of isocyanate-reactive functional groups and contains on average per molecule more than one carbon-carbon double bond activatable with actinic radiation; processes for preparing them, and their use.
    • 包括(I)在储存和使用条件下尺寸稳定的(I)液体和/或高粘度固体颗粒的水分散体,其包含(IA)不含可活化光化辐射的碳 - 碳双键的粘合剂,其包含: 至少一种平均每分子含有至少一个异氰酸酯反应性官能团和至少一个分散官能团的(甲基)丙烯酸酯共聚物,和(IB)至少一种封端多异氰酸酯; (II)在储存和使用条件下尺寸稳定的液体,高粘度和/或固体颗粒,包含至少一种含有至少一个异氰酸酯反应性官能团的聚氨酯(II),至少一个具有至少一个能与 光化辐射和至少一种分散官能团,和(III)至少一种不含异氰酸酯反应性官能团的不饱和组分,并且每分子平均含有多于一个可用光化辐射活化的碳 - 碳双键; 制备它们的过程及其用途。
    • 5. 发明申请
    • Powder Slurries Which can be Thermally Hardened with Actinic Radiation and Method for the Production and Use Thereof
    • 可以用光化辐射热固化的粉末浆料及其生产和使用方法
    • US20080255308A1
    • 2008-10-16
    • US10595209
    • 2004-10-12
    • Berthold AustrupHubert BaumgartGuido Wilke
    • Berthold AustrupHubert BaumgartGuido Wilke
    • C08L75/04
    • C09D175/16C08G18/6229C08G18/6254C08G18/671C08G18/807C08G18/8096C08G18/8116C08G18/8175C08G18/62
    • Powder slurries curable thermally and with actinic radiation and comprising solid and/or highly viscous particles dimensionally stable under storage and application conditions, including at least one binder free of carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and at least one ion-forming group; at least one blocked and/or part-blocked polyisocyanate; and at least one olefinically unsaturated constituent which is free of isocyanate-reactive functional groups and contains on average per molecule at least one isocyanate group blocked with pyrazole or with at least one substituted pyrazole and at least two carbon-carbon double bonds which can be activated with actinic radiation, prepared by reacting at least one polyisocyanate with pyrazole and/or with at least one substituted pyrazole and also with at least one compound containing an isocyanate-reactive functional group and at least two carbon-carbon double bonds activatable with actinic radiation, processes for preparing them, and their use.
    • 粉末浆料可热固化并具有光化辐射,并且在储存和使用条件下包括固体和/或高粘度颗粒尺寸稳定,包括至少一种不含可活化光化辐射的碳 - 碳双键的粘合剂,其包含至少一种(甲基)丙烯酸酯 每个分子平均含有至少一个异氰酸酯反应性官能团和至少一个离子形成基团的共聚物; 至少一种封端和/或部分封端的多异氰酸酯; 和至少一种不含异氰酸酯反应性官能团的烯属不饱和组分,平均每分子含有至少一个被吡唑或至少一个取代的吡唑封端的异氰酸酯基团和至少两个可被活化的碳 - 碳双键 通过使至少一种多异氰酸酯与吡唑和/或与至少一种取代的吡唑反应制备,并且还含有至少一种含有异氰酸酯反应性官能团的化合物和至少两种可用光化辐射活化的碳 - 碳双键, 制备它们的过程及其用途。
    • 6. 发明授权
    • Process for preparing an aqueous dispersion of a polyacrylate-modified
polyurethane-alkyd resin and the use of such a dispersion
    • 制备聚丙烯酸酯改性聚氨酯 - 醇酸树脂的水性分散体的方法和使用这种分散体
    • US6166150A
    • 2000-12-26
    • US269394
    • 1999-05-25
    • Guido WilkeUlrich PothRolf SeidemannVijay Kadambande
    • Guido WilkeUlrich PothRolf SeidemannVijay Kadambande
    • C08G18/67C08F283/00C08G18/08C08G18/42C08G18/80C08G63/49C09D175/06C09D175/14C08F283/04C09D175/16
    • C08G18/8048C08F283/002C08G18/0823C08G18/4288C09D175/14
    • A process for preparing binders for one-component paint systems has the following steps: (I) preparation of a polyurethane-alkyd resin component (A) composed of a mixture (a) of (a1) an unsaturated C.sub.6 -C.sub.30 fatty acid with at least two non-conjugated double bonds, and (a2) an unsaturated C.sub.6 -C.sub.30 fatty acid with at least two conjugated double bonds as esterified side polymer chains of the polyurethane-alkyd component (A); and (b) polyurethane units with anionic groups and/or groups which can be converted into anionic groups as main polymer chains of the polyurethane-alkyd resin component (A); (II) optional neutralisation of the groups in the polyurethane-alkyd resin component (A) which can be converted into anionic groups and their transfer into the aqueous dispersion or solution; and (III) polymerising at least one ethylenically unsaturated, radically polymerisable monomer (c) which has substantially no other reactive functional groups besides the C--C-- double bond in the dispersion prepared as under step (II) in the presence of a radical builder as polymerisation initiator.
    • PCT No.PCT / EP97 / 04951 Sec。 371日期1999年5月25日 102(e)日期1999年5月25日PCT提交1997年9月10日PCT公布。 公开号WO98 / 13404 日期:1998年4月2日制备用于单组分涂料体系的粘合剂的方法具有以下步骤:(I)由(a1)不饱和C6-烷氧基化合物的混合物(a)制备聚氨酯 - 醇酸树脂组分(A) 具有至少两个非共轭双键的C30脂肪酸,和(a2)具有至少两个共轭双键的不饱和C6-C30脂肪酸作为聚氨酯 - 醇酸组分(A)的酯化侧聚合物链; 和(b)具有可以转化为阴离子基团的阴离子基团和/或基团的聚氨酯单元作为聚氨酯 - 醇酸树脂组分(A)的主要聚合物链; (II)任选地中和聚氨酯 - 醇酸树脂组分(A)中的基团,其可以转化成阴离子基团并将其转移到水分散体或溶液中; 聚合至少一种烯键式不饱和的可自由基聚合的单体(c),其在根据步骤(II)制备的分散体中,在自由基助洗剂作为聚合反应存在下,除了CC-双键之外基本上没有其它反应性官能团 发起人