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1. 发明申请

US20070003766A1 Hardeners for coating compositions (III) 审中-公开
标题翻译：涂料组合物硬化剂（III）
公开(公告)号：US20070003766A1
公开(公告)日：2007-01-04
申请号：US11452171
申请日：2006-06-13
申请人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
发明人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
IPC分类号： B32B27/38 , C08L63/00 , C08G65/00 , C08G59/50
CPC分类号： C08G59/184 , C08G59/226 , C09D163/00 , Y10T428/31511
摘要： The invention relates to hardeners for water-based epoxy resin systems providing a longer resin pot life, incorporating particular compounds (F) and being obtainable by (i) reacting a mixture of (A) at least one epoxidized polyalkylene oxide (A), (B) at least one epoxidized aromatic hydroxy compound (B); (C) at least one aromatic hydroxy compound (C); and (D) optionally, at least one di- or tri-glycidyl ether compound (D), to form a first intermediate product (Z1) having an epoxy value of less than 10%; (ii) reacting the intermediate product (Z1) with a polyamine (E) to form a second intermediate product (Z2); and (iii) reacting the intermediate product (Z2) with a compound (F) selected from (a) monofunctional epoxy compounds, and (b) glycidyl ethers of aliphatic and aromatic hydrocarbons. The resin mixtures have pot lives in excess of one hour and, after curing, provide clear floor coatings with less than 3% shrinkage.
摘要翻译：本发明涉及提供更长的树脂适用期的水基环氧树脂体系的硬化剂，其中加入特定的化合物（F），可通过（i）使（A）至少一种环氧化聚环氧烷（A），（ B）至少一种环氧化芳族羟基化合物（B）; （C）至少一种芳族羟基化合物（C）; 和（D）任选的至少一种二缩水甘油醚化合物（D），以形成环氧值小于10％的第一中间产物（Z1）; （ii）使中间产物（Z1）与多胺（E）反应以形成第二中间产物（Z2）; 和（iii）使中间产物（Z2）与选自（a）单官能环氧化合物的化合物（F）和（b）脂族和芳族烃的缩水甘油醚反应。树脂混合物的使用寿命超过1小时，并且在固化后，提供具有小于3％收缩率的透明地板涂料。

2. 发明申请

US20070073009A1 Hardeners for coating compositions (II) 审中-公开
标题翻译：涂料组合物硬化剂（II）
公开(公告)号：US20070073009A1
公开(公告)日：2007-03-29
申请号：US11451938
申请日：2006-06-13
申请人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
发明人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
IPC分类号： C08G59/14
CPC分类号： C08G59/182 , C08G59/184 , C08G59/4057 , C09D163/00
摘要： The invention relates to hardeners for water-based epoxy resin systems providing a longer resin pot life, incorporating particular carbonyl compounds (F) and being obtainable by (i) reacting a mixture of (A) at least one epoxidized polyalkylene oxide (A), (B) at least one epoxidized aromatic hydroxy compound (B); (C) at least one aromatic hydroxy compound (C); and (D) optionally, at least one di- or tri-glycidyl ether compound (D), to form a first intermediate product (Z1) having an epoxy value of less than 10%; (ii) reacting the intermediate product (Z1) with a polyamine (E) to form a second intermediate product (Z2); and (iii) reacting the intermediate product (Z2) with a carbonyl compound (F) having the general formula (I): wherein R1 and R2 independently represent hydrogen, a C1-22 alkyl group or a C6H5, OH, OR3 group, where R3 is a C1-22 alkyl group; among others. The resin mixtures provide clear floor coatings.
摘要翻译：本发明涉及提供更长的树脂适用期的水基环氧树脂体系的固化剂，其中加入了特定的羰基化合物（F），可通过（i）使（A）至少一种环氧化聚环氧烷（A），（B）至少一种环氧化芳族羟基化合物（B）; （C）至少一种芳族羟基化合物（C）; 和（D）任选的至少一种二缩水甘油醚化合物（D），以形成环氧值小于10％的第一中间产物（Z1）; （ii）使中间产物（Z1）与多胺（E）反应以形成第二中间产物（Z2）; 和（iii）使中间产物（Z2）与具有通式（I）的羰基化合物（F）反应：其中R 1和R 2独立代表氢， C 1-22烷基或C 6 H 5，OH，OR 3，其中R 3是一个C 1-22烷基; 等等树脂混合物提供清晰的地板涂层。

3. 发明申请

US20070066789A1 Hardeners for coating compositions (I) 审中-公开
标题翻译：涂料组合物硬化剂（I）
公开(公告)号：US20070066789A1
公开(公告)日：2007-03-22
申请号：US11452152
申请日：2006-06-13
申请人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
发明人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
IPC分类号： C08G65/26
CPC分类号： C09D163/00 , C08G59/182 , C08G59/226
摘要： The invention relates to hardeners for water-based epoxy resin systems providing a longer resin pot life, incorporating particular carbonyl compounds (F) and being obtainable by (i) reacting a mixture of (A) at least one epoxidized polyalkylene oxide (A), (B) at least one epoxidized aromatic hydroxy compound (B); (C) at least one aromatic hydroxy compound (C); and (D) optionally, at least one di- or tri-glycidyl ether compound (D), to form a first intermediate product (Z1) having an epoxy value of less than 10%; (ii) reacting the intermediate product (Z1) with a polyamine (E) to form a second intermediate product (Z2); and (iii) reacting the intermediate product (Z2) with an α,β-unsaturated carbonyl compound or nitrile (F) having the general formula (I). The resin mixtures have pot lives in excess of one hour and, after curing, provide clear floor coatings with less than 3% shrinkage.
摘要翻译：本发明涉及提供更长的树脂适用期的水基环氧树脂体系的固化剂，其中加入了特定的羰基化合物（F），可通过（i）使（A）至少一种环氧化聚环氧烷（A），（B）至少一种环氧化芳族羟基化合物（B）; （C）至少一种芳族羟基化合物（C）; 和（D）任选的至少一种二缩水甘油醚化合物（D），以形成环氧值小于10％的第一中间产物（Z1）; （ii）使中间产物（Z1）与多胺（E）反应以形成第二中间产物（Z2）; 和（iii）使中间产物（Z2）与具有通式（I）的α，β-不饱和羰基化合物或腈（F）反应。树脂混合物的使用寿命超过1小时，并且在固化后，提供具有小于3％收缩率的透明地板涂料。

4. 发明授权

US07300963B2 Hardeners for water-based epoxy resin systems and processes for using the same 有权
标题翻译：用于水性环氧树脂体系的硬化剂及其使用方法
公开(公告)号：US07300963B2
公开(公告)日：2007-11-27
申请号：US10939681
申请日：2004-09-13
申请人： Paul Birnbrich , Thorsten Roloff , Giorgio Sabbadini , Hans-Josef Thomas
发明人： Paul Birnbrich , Thorsten Roloff , Giorgio Sabbadini , Hans-Josef Thomas
IPC分类号： B32B17/10 , B32B28/38 , C08K3/20 , C08L63/00 , C08L63/02
CPC分类号： C09D163/00 , C08G59/066 , C08G59/184 , Y10T428/31511 , Y10T428/31525
摘要： Hardeners for water-based epoxy resin systems, the hardeners being obtainable by reacting a mixture of: (A) at least one epoxidized polyalkylene oxide selected from the group of epoxidized polyethylene oxides, epoxidized polypropylene oxides and polyethylene propylene oxides, (B) at least one epoxidized aromatic hydroxy compound selected from the group of bisphenol A epoxides and bisphenol F epoxides and (C) at least one aromatic hydroxy compound selected from the group of bisphenol A and bisphenol F, to form an intermediate product and subsequently reacting this intermediate product with a polyamine (E), are disclosed.
摘要翻译：用于水性环氧树脂体系的硬化剂，所述硬化剂可通过以下混合物反应获得：（A）至少一种选自环氧化聚环氧乙烷，环氧化聚环氧丙烷和聚环氧乙烷的环氧化聚环氧烷烃，（B）至少一种选自双酚A环氧化物和双酚F环氧化物的环氧化芳族羟基化合物和（C）至少一种选自双酚A和双酚F的芳族羟基化合物，以形成中间产物，随后使该中间产物与多胺（E）。

5. 发明申请

US20070003767A1 Hardeners for coating compositions (IV) 审中-公开
标题翻译：涂料组合物硬化剂（IV）
公开(公告)号：US20070003767A1
公开(公告)日：2007-01-04
申请号：US11452179
申请日：2006-06-13
申请人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
发明人： Giorgio Sabbadini , Thorsten Roloff , Paul Birnbrich , Hans-Josef Thomas
IPC分类号： B32B27/38 , C08L63/00 , C08G65/00 , C08G59/50
CPC分类号： C09D163/00 , C08G59/184 , C08G59/226 , C08G59/56 , Y10T428/31511 , C08L2666/04
摘要： The invention relates to hardeners for water-based epoxy resin systems providing a longer resin pot life, incorporating particular compounds (F) and being obtainable by (i) reacting a mixture of (A) at least one epoxidized polyalkylene oxide (A), (B) at least one epoxidized aromatic hydroxy compound (B); (C) at least one aromatic hydroxy compound (C); and (D) optionally, at least one di- or tri-glycidyl ether compound (D), to form a first intermediate product (Z1) having an epoxy value of less than 10%; (ii) reacting the intermediate product (Z1) with a polyamine (E) to form a second intermediate product (Z2); and (iii) reacting the intermediate product (Z2) with a compound (F) selected from Lewis acids. The resin mixtures have pot lives in excess of one hour and, after curing, provide clear floor coatings with less than 3% shrinkage.
摘要翻译：本发明涉及提供更长的树脂适用期的水基环氧树脂体系的硬化剂，其中加入特定的化合物（F），可通过（i）使（A）至少一种环氧化聚环氧烷（A），（ B）至少一种环氧化芳族羟基化合物（B）; （C）至少一种芳族羟基化合物（C）; 和（D）任选的至少一种二缩水甘油醚化合物（D），形成环氧值小于10％的第一中间产物（Z1）; （ii）使中间产物（Z1）与多胺（E）反应以形成第二中间产物（Z2）; 和（iii）使中间产物（Z2）与选自路易斯酸的化合物（F）反应。树脂混合物的使用寿命超过1小时，并且在固化后，提供具有小于3％收缩率的透明地板涂料。

6. 发明申请

US20050113553A1 Hardeners for water-based epoxy resin systems and processes for using the same 有权
标题翻译：用于水性环氧树脂体系的硬化剂及其使用方法
公开(公告)号：US20050113553A1
公开(公告)日：2005-05-26
申请号：US10939681
申请日：2004-09-13
申请人： Paul Birnbrich , Thorsten Roloff , Giorgio Sabbadini , Hans-Josef Thomas
发明人： Paul Birnbrich , Thorsten Roloff , Giorgio Sabbadini , Hans-Josef Thomas
IPC分类号： C08G59/06 , C08G59/18 , C09D163/00 , C08L63/00
CPC分类号： C09D163/00 , C08G59/066 , C08G59/184 , Y10T428/31511 , Y10T428/31525
摘要： Hardeners for water-based epoxy resin systems, the hardeners being obtainable by reacting a mixture of: (A) at least one epoxidized polyalkylene oxide selected from the group of epoxidized polyethylene oxides, epoxidized polypropylene oxides and polyethylene propylene oxides, (B) at least one epoxidized aromatic hydroxy compound selected from the group of bisphenol A epoxides and bisphenol F epoxides and (C) at least one aromatic hydroxy compound selected from the group of bisphenol A and bisphenol F, to form an intermediate product and subsequently reacting this intermediate product with a polyamine (E), are disclosed.
摘要翻译：用于水性环氧树脂体系的硬化剂，所述硬化剂可通过以下混合物反应获得：（A）至少一种选自环氧化聚环氧乙烷，环氧化聚环氧丙烷和聚环氧乙烷的环氧化聚环氧烷烃，（B）至少一种选自双酚A环氧化物和双酚F环氧化物的环氧化芳族羟基化合物和（C）至少一种选自双酚A和双酚F的芳族羟基化合物，以形成中间产物，随后使该中间产物与多胺（E）。

7. 发明申请

US20080171833A1 Viscosity Reducer For Highly Viscous Polyols 有权
标题翻译：用于高粘度多元醇的粘度降低剂
公开(公告)号：US20080171833A1
公开(公告)日：2008-07-17
申请号：US11571440
申请日：2005-06-22
申请人： Thorsten Roloff , Rainer Hoefer
发明人： Thorsten Roloff , Rainer Hoefer
IPC分类号： C08F291/08 , C08G18/00
CPC分类号： C08G18/36 , C08G18/6547 , C08G65/2696
摘要： Ring opening products of epoxides with fatty acid methyl esters with alkanols or water are eminently suitable as viscosity adjusters for high-viscosity polyols.
摘要翻译：环氧化物与脂肪酸甲酯与链烷醇或水的开环产物非常适合用作高粘度多元醇的粘度调节剂。

8. 发明申请

US20080262132A1 NONIONIC SURFACTANTS 审中-公开
标题翻译：非离子表面活性剂
公开(公告)号：US20080262132A1
公开(公告)日：2008-10-23
申请号：US12048287
申请日：2008-03-14
申请人： Thorsten Roloff , Katharina Hoemberg , Thomas Schliwka , Thomas Mausberg , Wolfgang H. Breuer , Doug Rhubright , Mike Wiggins
发明人： Thorsten Roloff , Katharina Hoemberg , Thomas Schliwka , Thomas Mausberg , Wolfgang H. Breuer , Doug Rhubright , Mike Wiggins
IPC分类号： C08K5/1515
CPC分类号： C08F2/30 , C08K5/06
摘要： A nonionic surfactant for emulsion polymerization is provided, and includes products from the addition of 3 to 20 mols of ethylene and/or propylene oxide onto 1 mol of one or more diterpene alcohols selected from the group consisting of abietyl alcohol, dihydroabietyl alcohol, tetrahydroabietyl alcohol and dehydroabietyl alcohol, wherein the surfactant is included as an emulsifier in a polymer emulsion. A method for stabilizing an emulsion polymer or polymer dispersion is also provided, including the steps of adding an emulsifier, to an emulsion polylmer or polymer dispersion comprising monomers, in an amount of from about 0.5 to about 10% by weight, based on the total quantity of monomers present, the emulsifier including products from the addition of 3 to 20 mols of ethylene and/or propylene oxide onto 1 mol of one or more diterpene alcohols selected from the group consisting of abietyl alcohol, dihydroabietyl alcohol, tetrahydroabietyl alcohol and dehydroabietyl alcohol.
摘要翻译：提供了用于乳液聚合的非离子表面活性剂，并且包括在1摩尔一种或多种选自以下的二萜烯醇中加入3至20摩尔的乙烯和/或环氧丙烷的产物：选自二醇，二氢枞醇，四氢枞醇和脱氢松香醇，其中表面活性剂作为乳化剂包含在聚合物乳液中。还提供了一种用于稳定乳液聚合物或聚合物分散体的方法，包括以下步骤：将乳化剂加入到包含单体的乳液聚合物或聚合物分散体中，其量为约0.5至约10重量％存在的单体的量，乳化剂包括从1至1摩尔选自下列的一种或多种二萜醇中加入3-20摩尔的乙烯和/或环氧丙烷的产物：二醇，二氢枞醇，四氢松香醇和脱氢枞醇。

9. 发明授权

US08153750B2 Viscosity reducer for highly viscous polyols 有权
标题翻译：用于高粘度多元醇的粘度降低剂
公开(公告)号：US08153750B2
公开(公告)日：2012-04-10
申请号：US11571440
申请日：2005-06-22
申请人： Thorsten Roloff , Rainer Hoefer
发明人： Thorsten Roloff , Rainer Hoefer
IPC分类号： C08G18/30 , C08G18/42 , C08G18/48 , C08G18/65 , C07C69/66
CPC分类号： C08G18/36 , C08G18/6547 , C08G65/2696
摘要： Ring opening products of epoxides with fatty acid methyl esters with alkanols or water are eminently suitable as viscosity adjusters (reducers) for high-viscosity polyols.
摘要翻译：环氧化物与脂肪酸甲酯与链烷醇或水的开环产物非常适合用作高粘度多元醇的粘度调节剂（还原剂）。

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