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1. 发明授权

US4762869A High temperature resistant molding materials 失效
标题翻译：耐高温成型材料
公开(公告)号：US4762869A
公开(公告)日：1988-08-09
申请号：US38896
申请日：1987-04-16
申请人： Gerhard Heinz , Hermann Buchert , Juergen Koch , Georg N. Simon , Peter Ittemann , Hartmut Zeiner
发明人： Gerhard Heinz , Hermann Buchert , Juergen Koch , Georg N. Simon , Peter Ittemann , Hartmut Zeiner
IPC分类号： C08G65/40 , C08G75/00 , C08G75/23 , C08L71/00 , C08L81/06 , H05K1/03 , C08L95/00
CPC分类号： C08L71/00 , C08G65/4012 , C08G75/23 , C08L81/06 , C08L2205/05 , H05K1/0333
摘要： High temperature resistant molding materials containing(A) 5-95 mol % of blocks having the structural unit I ##STR1## (B) 5-95 mol % of blocks having the structural unit II ##STR2## (C) 0-80 mol % of blocks having the structural unit III ##STR3## the molecular weight of the blocks being within the range 2000-20,000, where X is --O--, --S--, ##STR4## (only if a or b.noteq.0), ##STR5## (R.sup.7 =R.sup.8 =CH.sub.3 only if a or b.noteq.O) or a chemical bond, R.sup.7 and R.sup.8 are each alkoxy or alkyl of 1-6 carbon atoms, aryl or hydrogen, Q and W are each ##STR6## Z is --O-- or a chemical bond and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each alkyl or alkoxy of 1-6 carbon atoms, aryl, Cl or F and p, q and r are each 0 or 1 and a, b, c, d and e are each 0, 1, 2, 3 or 4.
摘要翻译：（A）5-95摩尔％具有结构单元的嵌段（I）（B）5-95摩尔％具有结构单元II（II）的嵌段（C））0-80摩尔％的具有结构单元III的嵌段（III）嵌段的分子量在2000-20,000范围内，其中X是-O - ， - S-，（仅当a或b NOTEQUAL 0），（R7 = R8 = CH3，仅当a或b为支链O）或化学键时，R7和R8分别为烷氧基或1-6个碳原子的烷基，芳基或氢 Q和W各自为Z为-O-或化学键，且R 1，R 2，R 3，R 4，R 5和R 6各自为1-6个碳原子的烷基或烷氧基，芳基，Cl或F和p， q和r各自为0或1，a，b，c，d和e各自为0,1,2,3或4。

2. 发明授权

US5032639A Heat-resistant thermoplastic molding compositions 失效
标题翻译：耐热性热塑性成型组合物
公开(公告)号：US5032639A
公开(公告)日：1991-07-16
申请号：US523906
申请日：1990-05-16
申请人： Hermann Buchert , Gerhard Heinz , Peter Ittemann , Michael Kopietz , Juergen Koch , Wolfgang Eberle , Hartmut Zeiner
发明人： Hermann Buchert , Gerhard Heinz , Peter Ittemann , Michael Kopietz , Juergen Koch , Wolfgang Eberle , Hartmut Zeiner
IPC分类号： C08K3/18 , C08K3/16 , C08K3/20 , C08K3/22 , C08K3/24 , C08K3/32 , C08K3/34 , C08K3/38 , C08L67/00 , C08L67/02 , C08L79/08 , C08L81/00 , C08L81/02 , C08L81/06
CPC分类号： C08K3/34 , C08K3/20 , C08K3/24 , C08K3/32 , C08K3/38
摘要： Thermoplastic molding compositions suitable for producing interior components for vehicles for the conveyance of passengers, in particular aircraft, which show a low smoke gas density and low heat release characteristics in the event of a fire, are based on a heat-resistant plastic which contains as a filler from 0.5 to 50% by weight of an oxide of an element of main group III, IV or V, of a salt of an oxygen acid of an element of main group III, IV or V or of a compound which on heating forms such an oxide or salt.

3. 发明授权

US5120784A Heat-resistant thermoplastic molding compositions 失效
标题翻译：耐热热塑性成型组合物
公开(公告)号：US5120784A
公开(公告)日：1992-06-09
申请号：US666905
申请日：1991-03-11
申请人： Hermann Buchert , Gerhard Heinz , Peter Ittemann , Michael Kopietz , Juergen Koch , Wolfgang Eberle , Hartmut Zeiner
发明人： Hermann Buchert , Gerhard Heinz , Peter Ittemann , Michael Kopietz , Juergen Koch , Wolfgang Eberle , Hartmut Zeiner
IPC分类号： C08K3/20 , C08K3/24 , C08K3/32 , C08K3/34 , C08K3/38
CPC分类号： C08K3/38 , C08K3/20 , C08K3/24 , C08K3/32 , C08K3/34
摘要： Thermoplastic molding compositions suitable for producing interior components for vehicles for the conveyance of passengers, in particular aircraft, which show a low smoke gas density and low heat release characteristics in the event of a fire, are based on a heat-resistant plastic which contains as a filler from 0.5 to 50 % by weight of an oxide of an element of main group III, IV or V, of a salt of an oxygen acid of an element of main group III, IV or V or of a compound which on heating forms such an oxide or salt.
摘要翻译：适用于生产用于运输乘客尤其是飞机的内部部件的热塑性成型组合物，其特征在于，在发生火灾时显示低烟气密度和低放热特性的车辆是基于耐热塑料，其包含主要III族，IV或V族元素的氧酸盐或加热形式的化合物的主要III族，IV或V族元素的氧化物的0.5至50重量％的填料这样的氧化物或盐。

4. 发明授权

US4981895A Heat-resistant thermoplastic molding compositions 失效
标题翻译：耐热性热塑性成型组合物
公开(公告)号：US4981895A
公开(公告)日：1991-01-01
申请号：US394970
申请日：1989-08-17
申请人： Hermann Buchert , Gerhard Heinz , Peter Ittemann , Michael Kopietz , Juergen Koch , Wolfgang Eberle , Hartmut Zeiner
发明人： Hermann Buchert , Gerhard Heinz , Peter Ittemann , Michael Kopietz , Juergen Koch , Wolfgang Eberle , Hartmut Zeiner
IPC分类号： C08K3/18 , C08K3/16 , C08K3/20 , C08K3/22 , C08K3/24 , C08K3/32 , C08K3/34 , C08K3/38 , C08L67/00 , C08L67/02 , C08L79/08 , C08L81/00 , C08L81/02 , C08L81/06
CPC分类号： C08K3/34 , C08K3/20 , C08K3/24 , C08K3/32 , C08K3/38
摘要： Thermoplastic molding compositions suitable for producing interior components for vehicles for the conveyance of passengers, in particular aircraft, which show a low smoke gas density and low heat release characteristics in the event of a fire, are based on a heat-resistant plastic which contains as a filler from 0.5 to 50% by weight of an oxide of an element of main group III, IV or V, of a salt of an oxygen acid of an element of main group III, IV or V or of a compound which on heating forms such an oxide or salt.
摘要翻译：适用于生产用于运输乘客尤其是飞机的内部部件的热塑性成型组合物，其特征在于，在发生火灾时显示低烟气密度和低放热特性的车辆是基于耐热塑料，其包含主要III族，IV或V族元素的氧酸盐或加热形式的化合物的主要III族，IV或V族元素的氧化物的0.5至50重量％的填料这样的氧化物或盐。

5. 发明授权

US4867912A Highly heat-resistant polyaryl ether ketones 失效
标题翻译：高耐热聚芳醚酮
公开(公告)号：US4867912A
公开(公告)日：1989-09-19
申请号：US142715
申请日：1988-01-11
申请人： Gerhard Heinz , Juergen Koch , Manfred Eggersdorfer , Jochem Henkelmann , Helmut Muenstedt , Peter Ittemann
发明人： Gerhard Heinz , Juergen Koch , Manfred Eggersdorfer , Jochem Henkelmann , Helmut Muenstedt , Peter Ittemann
IPC分类号： C08G65/40 , C08L71/00 , C08L81/06
CPC分类号： C08L71/00 , C08G65/4012 , C08L81/06
摘要： Highly heat-resistant polyaryl ether ketones are composed of(A) from 50 to 100 mol % of repeat units of the general formula I ##STR1## or a ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivative thereof and(B) from 0 to 50 mol % of repeat units, different from I, of the general formulae II and/or III ##STR2## or a ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivative thereof, where Q, Q', Y, Y', T, T', Z and Z' are each --O--, --CO-- or a chemical bond, one or more of these substituents is a --CO-- group, and s, t and u are each 0 or 1.
摘要翻译：高耐热聚芳醚酮由（A）50-100摩尔％的通式I重复单元或环取代的C 1 -C 8烷基，C 1 -C 8 - 烷氧基，芳基，氯或氟衍生物和（B）0至50摩尔％的通式II和/或III与I不同的重复单元，或环 - 取代的C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基，芳基，氯或氟衍生物，其中Q，Q'，Y，Y'，T，T'，Z和Z'各自为-O - ， - 或化学键，这些取代基中的一个或多个是-CO-基团，s，t和u各自为0或1。

6. 发明授权

US5334642A Stabilized polyaryl ether ketone molding compositions 失效
标题翻译：稳定的聚芳醚酮模塑组合物
公开(公告)号：US5334642A
公开(公告)日：1994-08-02
申请号：US998730
申请日：1992-12-30
申请人： Juergen Koch , Gerhard Heinz
发明人： Juergen Koch , Gerhard Heinz
IPC分类号： C08K5/34 , C08K5/00 , C08K7/02 , C08L71/08 , C08L71/10 , C08K5/45 , C08K5/48
CPC分类号： C08K5/005
摘要： Stabilized polyaryl ether ketone molding compositions containing as essential componentsA) from 50 to 99.99% by weight of a polyaryl ether ketone prepared by electrophilic polycondensation and composed to an extent of not less than 50 mol % of units of the formula I' ##STR1## where s and t are each 0, 1, 2 or 3, T and T' are each --O-- or --CO-- and Ar is meta-phenylene, paraphenylene or two aromatic rings linked to each other in the meta or para position by a chemical bond, or the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.6 -C.sub.20 -aryl or halogen derivatives thereof,B) from 0.01 to 4% by weight of at least one organic compound which has a base constant pk.sub.b within the range from 2 to 12 and a boiling point of higher than 300.degree. C.,C) from 0 to 50% by weight of a further thermoplastic other than A), andD) from 0 to 45% by weight of fibrous or particulate fillers or mixtures thereof.
摘要翻译：含有作为基本成分的稳定化的聚芳基醚酮成型组合物A）50〜99.99重量％的通过亲电缩聚反应制备的聚芳基醚酮，其量为不低于50摩尔％的式I'单元，其中s和t各自为0,1,2或3，T和T'各自为-O-或-CO-，Ar为间位亚苯基，对亚苯基或两个在间位或对位相互连接的芳环，化学键或环取代的C 1 -C 8 - 烷基，C 6 -C 20 - 芳基或其卤素衍生物，B）0.01至4重量％的至少一种有机化合物，其碱值常数pkb在 2至12，沸点高于300℃，C）0至50重量％的除A）以外的其它热塑性塑料，D）0至45重量％的纤维或颗粒填料或混合物其中。

7. 发明授权

US4997902A Polyaryl ethers which are stable at high temperatures and have improved processibility 失效
标题翻译：在高温下稳定且具有改善的加工性的聚芳醚
公开(公告)号：US4997902A
公开(公告)日：1991-03-05
申请号：US308638
申请日：1989-02-10
申请人： Juergen Koch , Robert R. Lieder , Gerhard Heinz
发明人： Juergen Koch , Robert R. Lieder , Gerhard Heinz
IPC分类号： C08L71/12 , C08G61/12 , C08G65/40 , C08G75/23 , C08L65/00 , C08L71/00 , C08L81/00 , C08L81/06 , D01F6/66
CPC分类号： C08L65/00 , C08G61/127 , C08G65/4012 , C08G75/23 , C08L71/00 , C08L2205/05
摘要： Polyaryl ethers which are stable at high temperatures essentially consist of(A) from 60 to 97 mol % of repeating units of the general formula I ##STR1## where l and m are each 1 or 2, or their C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl, chlorine or fluorine derivatives which are substituted in the nucleus,(B) from 3 to 40 mol % of repeating units of the general formula II ##STR2## where n is 1 or 2, or their C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl, chlorine or fluorine derivatives which are substituted in the nucleus, and furthermore(C) from 0 to 15 mol % of repeating units of the general formulae III and/or IV ##STR3## where Ar is ##STR4## or a C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, chlorine or fluorine derivative thereof, r is 0 or 1 and p, q and s are each 1 or 2, or their C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl, chlorine or fluorine derivatives which are substituted in the nucleus.
摘要翻译：在高温下稳定的聚芳基醚基本上由（A）60至97摩尔％的通式I（I）的重复单元，其中l和m各自为1或2，或其C1-C6- 烷基，C 1 -C 6 - 烷氧基，芳基，氯或氟衍生物，（B）3-40摩尔％的通式II（II）的重复单元，其中n为1或2 或它们在核中被取代的C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基，芳基，氯或氟衍生物，此外（C）0至15摩尔％的通式III和/或（IV）其中Ar是其中Ar是其中Ar是0或1的C1-C6烷基，C1-C6-烷氧基，氯或氟衍生物，其中Ar是和p，q和s各自为1或2，或其在核中被取代的C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基，芳基，氯或氟衍生物。

8. 发明授权

US5081215A Preparation of polyaryleneetherketones 失效
标题翻译：聚乙二醇的制备
公开(公告)号：US5081215A
公开(公告)日：1992-01-14
申请号：US393793
申请日：1989-08-15
申请人： Juergen Koch , Wolfgang Stegmaier , Gerhard Heinz
发明人： Juergen Koch , Wolfgang Stegmaier , Gerhard Heinz
IPC分类号： C08G65/40 , C08G61/12
CPC分类号： C08G61/127
摘要： Polyaryleneetherketones are prepared by a quasicontinuous process, by Friedel-Crafts polycondensation of a reaction mixture containingA. a monomer system of(a)(1) an aromatic dicarboxylic acid chloride or phosgene and(2) a polynuclear aromatic having two exchangeable hydrogen atoms and/or(b) a polynuclear aromatic carboxylic acid chloride having one exchangeable hydrogen atom,B. a Lewis acid,C. if necessary, a Lewis base andD. an inert solvent.The reaction mixture is subjected to polycondensation in a first zone, with stirring, to a viscosity of not more than 2,000 mPa.s, then conveyed through a second, vertical, unstirred zone with plug flow by means of gas pressure, where the polycondensation is completed, and is finally discharged continuously.
摘要翻译：聚芳醚醚通过准连续法制备，通过Frieder-Crafts缩聚反应混合物，该反应混合物含有（a）（1）芳族二羧酰氯或光气的单体体系，和（2）具有两个可交换氢原子的多核芳烃和 /或（b）具有一个可交换氢原子的多核芳族羧酰氯，B.路易斯酸，C.如果需要，路易斯碱和D.惰性溶剂。反应混合物在搅拌下在第一区域进行缩聚，粘度不大于2,000mPa.s，然后通过气体压力通过气流压力输送通过第二垂直的未搅拌区域，其中缩聚反应完成，终于不停地出院。

9. 发明授权

US4837296A Preparation of polyaryl ether ketones 失效
标题翻译：聚芳醚酮的制备
公开(公告)号：US4837296A
公开(公告)日：1989-06-06
申请号：US141726
申请日：1988-01-11
申请人： Gerhard Heinz , Juergen Koch , Manfred Eggersdorfer , Jochem Henkelmann
发明人： Gerhard Heinz , Juergen Koch , Manfred Eggersdorfer , Jochem Henkelmann
IPC分类号： C08G65/40
CPC分类号： C08G65/4087 , C08G65/4012
摘要： Polyaryl ether ketones are prepared by reacting aromatic dihydroxy compounds with aromatic dihalogen compounds in polar aprotic solvents in the presence of alkali metal carbonates, in particular by reacting aromatic dihydroxy compounds I ##STR1## or ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof, n and m each being 0 or 1, with aromatic dihalogen compounds ##STR2## or ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or fluorine derivatives thereof, r and s each being 0 or 1, A being oxygen or a chemical bond and X being chlorine or fluorine.
摘要翻译：聚芳基醚酮通过芳族二羟基化合物与芳族二卤代化合物在极性非质子溶剂中在碱金属碳酸盐存在下反应来制备，特别是通过使芳族二羟基化合物（I）和/或环取代的C1-C8 - 烷基，C 1 -C 8 - 烷氧基，芳基，氯或氟衍生物，n和m各自为0或1，与芳族二卤化合物（II）或环取代的C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基，芳基，氯或氟衍生物，r和s各自为0或1，A为氧或化学键，X为氯或氟。

10. 发明授权

US5208278A Stabilized polyaryl ether ketone molding compositions 失效
标题翻译：稳定的聚醚醚酮模塑组合物
公开(公告)号：US5208278A
公开(公告)日：1993-05-04
申请号：US677336
申请日：1991-03-29
申请人： Juergen Koch , Gerhard Heinz
发明人： Juergen Koch , Gerhard Heinz
IPC分类号： C08K5/34 , C08K5/00 , C08K7/02 , C08L71/08 , C08L71/10
CPC分类号： C08K5/005
摘要： Stabilized polyaryl ether ketone molding compositions containing as essential componentsA) from 50 to 99.99% by weight of a polyaryl ether ketone prepared by electrophilic polycondensation and composed to an extent of not less than 50 mol % of units of the formula I' ##STR1## where s and t are each 0, 1, 2 or 3, T and T' are each --0-- or --CO-- and Ar is meta-phenylene, paraphenylene or two aromatic rings linked to each other in the meta or para position by a chemical bond, or the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.6 -C.sub.20 -aryl or halogen derivatives thereof,B) from 0.01 to 4% by weight of at least one organic compound which has a base constant pk.sub.b within the range from 2 to 12 and a boiling point of higher than 300.degree. C.,C) from 0 to 50% by weight of a further thermoplastic other than A), andD) from 0 to 45% by weight of fibrous or particulate fillers or mixtures thereof.
摘要翻译：含有作为基本成分的稳定化的聚芳基醚酮成型组合物A）50〜99.99重量％的通过亲电缩聚反应制备的聚芳基醚酮，其量为不低于50摩尔％的式I'单元， I'其中s和t各自为0,1,2或3，T和T'各自为-O-或-CO-，Ar为间亚苯基，对亚苯基或两个在元或对位中彼此连接的芳环。或其环取代的C 1 -C 8 - 烷基，C 6 -C 20 - 芳基或其卤素衍生物，B）0.01至4重量％的至少一种有机化合物，所述有机化合物在范围为2至12，沸点高于300℃，C）0至50重量％的除A）之外的另外的热塑性塑料，D）0至45重量％的纤维或颗粒填料或其混合物。

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