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1. 发明授权

US4258022A Continuous production of phosphine 失效
标题翻译：连续生产磷化氢
公开(公告)号：US4258022A
公开(公告)日：1981-03-24
申请号：US75001
申请日：1979-09-12
申请人： Georg Elsner , Werner Klose , Christian May , Gero Heymer
发明人： Georg Elsner , Werner Klose , Christian May , Gero Heymer
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： The invention relates to the continuous production of phosphine. To this end, elemental phosphorus is reacted with an aqueous alkali metal hydroxide solution and at least one alcohol, the reactants being used in admixture with 0.01 to 2 weight % of a surfactant, the percentage being based on the alcohol.
摘要翻译：本发明涉及磷化氢的连续生产。为此，元素磷与碱金属氢氧化物水溶液和至少一种醇反应，反应物与0.01至2重量％的表面活性剂混合使用，其百分比基于醇。

2. 发明授权

US4163760A Continuous production of organic phosphines 失效
标题翻译：连续生产有机膦
公开(公告)号：US4163760A
公开(公告)日：1979-08-07
申请号：US872250
申请日：1978-01-25
申请人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
发明人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
IPC分类号： C07F9/50 , C07F9/6568 , C07F9/54
CPC分类号： C07F9/5059 , C07F9/65683
摘要： Organic phosphines are produced by reacting an alkylene, cycloalkylene or aralkylene in the presence of a free radical-yielding catalyst. More specifically, a pressure reactor, which is provided in its interior with mixing elements, kept free from oxygen, and subdivided so as to comprise an upper cooling zone and a lower reaction zone, is continuously supplied from above with (a) a solution of the alkylene, cycloalkylene or aralkylene and the catalyst in an inert solvent, and (b) a stoichiometric excess of hydrogen phosphide, the said (a) and (b) reactants being supplied jointly with but separately from one another; the (a) and (b) reactants are mixed in the upper cooling zone of the reactor at about 0.degree. to 35.degree. C. and under a PH.sub.3 -pressure of about 80 to 300 bars; the resulting mixture, which travels downwardly in the reactor, is reacted in the lower reaction zone at about 90.degree. to 190.degree. C., the reactants being allowed to remain in the reactor for a period of time about 13 to 15 times longer than the half life period of the catalyst; the reaction mixture is removed through the bottom portion of the reactor and subjected to distillation so as to separate the organic phosphines.
摘要翻译：有机膦通过在产生自由基的催化剂存在下使亚烷基，亚环烷基或亚芳烷基反应来制备。更具体地，在其内部设置有保持无氧的并且被分为包括上部冷却区和下部反应区的混合元件的压力反应器从上方连续地供给（a）所述（a）和（b）反应物是由彼此共同供应的;（b）化学计量过量的磷酸氢盐，所述（a）和（b）（a）和（b）反应物在反应器的上部冷却区中在约0℃至35℃下混合，并在约80至300巴的PH3压力下混合; 在反应器中向下移动的所得混合物在下部反应区中在约90℃至190℃下反应，使反应物在反应器中保留约13至15倍的时间催化剂的半衰期; 将反应混合物通过反应器的底部除去并进行蒸馏以分离有机膦。

3. 发明授权

US4639331A Process for making pulverulent ammonium polyphosphates stable to hydrolysis 失效
标题翻译：制备粉末状聚磷酸铵稳定水解的方法
公开(公告)号：US4639331A
公开(公告)日：1987-01-27
申请号：US603120
申请日：1984-04-23
申请人： Georg Elsner , Horst Staendeke , Gero Heymer
发明人： Georg Elsner , Horst Staendeke , Gero Heymer
IPC分类号： C08L1/00 , A62D1/00 , C01B25/40 , C08G18/00 , C08K3/32 , C08K9/04 , C08K9/08 , C08K9/10 , C08L75/00 , C08L75/04 , C09K21/02 , C09K21/04 , C09K21/12 , D06M11/00 , D06M11/72 , D06M15/423 , D06M23/12 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D21H17/10 , D21H17/47 , D21H17/51 , D21H17/63 , D21H21/34 , D21H27/00 , C08K3/28 , C09K21/10
CPC分类号： C01B25/405 , C08K3/32 , C08K9/08 , C08K9/10 , C09K21/02 , C09K21/12 , D21H5/0002 , D21H21/34 , Y10S521/907
摘要： The disclosure relates to a process for making a particulate agent stable to hydrolysis based on free-flowing, pulverulent ammonium polyphosphate by treating the ammonium polyphosphate with a thermosetting, artificial resin being water-insoluble when cured. More specifically, the disclosure provides for the ammonium polyphosphate, an aliphatic alcohol as a diluent, and a melamine/formaldehyde-resin or phenol/formaldehyde-resin to be placed in an autoclave and intimately mixed at room temperature; for the mixture to be heated to a temperature of about 80.degree. to about 180.degree. C. and allowed to remain over a period of 15 to 240 minutes at that temperature and under the pressure corresponding to the vapor pressure of the diluent; for the diluent to be separated and for the product so obtained to be dried.
摘要翻译：本公开涉及一种通过在固化时用热固性人造树脂处理水不溶性的方法，通过用聚酰亚胺铵处理聚磷酸铵来制备基于自由流动的多磷酸铵的水解稳定的颗粒剂的方法。更具体地，本公开内容提供了多磷酸铵，脂肪醇作为稀释剂，将三聚氰胺/甲醛树脂或酚/甲醛树脂置于高压釜中并在室温下充分混合; 将混合物加热到约80℃至约180℃的温度，并在该温度和在与稀释剂的蒸汽压力相对应的压力下保持15至240分钟的时间; 用于分离稀释剂和所得产品进行干燥。

4. 发明授权

US4351960A Production of an isomeric mixture of secondary phosphines 失效
标题翻译：生产次膦的异构体混合物
公开(公告)号：US4351960A
公开(公告)日：1982-09-28
申请号：US190448
申请日：1980-09-24
申请人： Georg Elsner , Hartfrid Vollmer , Gero Heymer
发明人： Georg Elsner , Hartfrid Vollmer , Gero Heymer
IPC分类号： C07F9/50
CPC分类号： C07F9/5018
摘要： The invention relates to a process for making an isomeric mixture of secondary phosphines with the summation formula C.sub.20 H.sub.27 P. To this end, hydrogen phosphide is reacted with dicyclopentadiene in the presence of an agent yielding free radicals. More specifically, hydrogen phosphide and dicyclopentadiene are used in a molar ratio of 1 to at least 2 and the reaction is effected under a pressure of 5 to 90 bars. The mixture is used in the production of flotation aids and as an ingredient of catalytically active transition metal complexes.
摘要翻译：本发明涉及一种制备仲膦与异构体混合物的方法，其中R为总和式C20H27P。为此，在产生自由基的试剂存在下，磷化氢与二环戊二烯反应。更具体地，使用磷化氢和二环戊二烯的摩尔比为1至至少2，反应在5至90巴的压力下进行。该混合物用于生产浮选助剂和作为催化活性过渡金属络合物的成分。

5. 发明授权

US4143121A Continuous production of pure phosphine 失效
标题翻译：连续生产纯磷酸盐
公开(公告)号：US4143121A
公开(公告)日：1979-03-06
申请号：US815161
申请日：1977-07-13
申请人： Jurgen Stenzel , Gero Heymer , Christian May
发明人： Jurgen Stenzel , Gero Heymer , Christian May
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： Phosphine is continuously produced by reacting yellow phosphorus with an aqueous alkali metal hydroxide solution in the presence of an alcohol, with the exclusion of oxygen, at 44 to 90.degree. C. To this end, the reaction is effected in two separate reaction stages. In the first reaction stage, the alkali metal hydroxide solution and phosphorus are reacted with agitation in a molar ratio of 0.7:1 to 0.9:1 and the resulting gaseous phosphine is collected. Resulting liquid phase material containing unreacted phosphorus is delivered to the second reaction stage in which the unreacted phosphorus is reacted with further aqueous alkali metal hydroxide solution. The resulting gaseous reaction products are collected separately from the gaseous phosphine collected in the first reaction stage.

6. 发明授权

US4091078A Production of phosphine 失效
标题翻译：生产磷化氢
公开(公告)号：US4091078A
公开(公告)日：1978-05-23
申请号：US736556
申请日：1976-10-28
申请人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
发明人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： Phosphine is produced from elementary yellow phosphorus and an aqueous alkali metal hydroxide solution in the presence of an alcohol. The phosphine is more particularly made by using an alcohol having from 5 to 10 carbon atoms and a dissolving power for yellow phosphorus of more than 5 g/l; suspending the phosphorus with agitation in the said alcohol in a reaction zone; reacting the resulting suspension with the alkali metal hydroxide solution at temperatures lower than the boiling point of the alcohol; and collecting the resulting issuing gaseous phosphine.
摘要翻译：在醇的存在下，由元素黄磷和碱金属氢氧化物水溶液生产磷化氢。膦更特别地通过使用具有5至10个碳原子的醇和大于5g / l的黄磷的溶解力来制备; 在反应区内搅拌将磷悬浮在所述醇中; 在低于醇的沸点的温度下使得到的悬浮液与碱金属氢氧化物溶液反应; 并收集产生的发出的气态膦。

7. 发明授权

US4923691A Aluminum nitride powder and a process for the preparation thereof 失效
标题翻译：氮化铝粉末及其制备方法
公开(公告)号：US4923691A
公开(公告)日：1990-05-08
申请号：US364013
申请日：1989-06-09
申请人： Dieter Peters , Gero Heymer , Christian May
发明人： Dieter Peters , Gero Heymer , Christian May
IPC分类号： C01B21/072
CPC分类号： C01B21/072 , C01P2002/60 , C01P2004/62 , C01P2006/12 , C01P2006/60
摘要： An aluminum nitride powder has a crystallite size of 40 to 150 nm, measured by powder diffractometry and evaluated by the method of Scherrer, a primary particle size of 0.1 to 0.5 .mu.m, a specific surface according to BET of 5 to 50 m.sup.2 /g and a degree of whiteness of more than 91%, measured using light of a 400 to 700 nm wavelength against barium sulfate analytical reagent as standard of whitness.To prepare this aluminum nitride powder, metallic aluminum and monoamminealuminum chloride [AlCl.sub.3 (NH.sub.3)] are first molten together in an inert gas atmosphere at temperatures above 125.degree. C. and allowed to react with one another with evolution of hydrogen. 8 to 20 g of ammonia are then introduced per hour per mol of monoamminealuminum chloride into the aluminum-containing monoamminealuminum chloride melt at temperatures between 250.degree. and 400.degree. C., aluminum nitride being precipitated as a solid until the conversion of the aluminum is complete. The temperature of the melt is finally raised to more than 400.degree. C.
摘要翻译：氮化铝粉末的微晶尺寸为40〜150nm，用粉末衍射法测定，用Scherrer法评价，一次粒径为0.1〜0.5μm，BET比表面积为5〜50m 2 / g 白度为91％以上，采用400〜700nm波长的光作为白度标准测定硫酸钡分析试剂。为了制备这种氮化铝粉末，首先在惰性气体气氛中，在高于125℃的温度下将金属铝和一氯化铝[AlCl 3（NH 3）]熔融在一起，并使其彼此发生氢气反应。然后在250-400℃的温度下将8至20g的氨每小时每摩尔氯化单铝酸铵引入含铝单胺氯化铝熔体中，将氮化铝作为固体沉淀直到铝的转化完全。熔体的温度最终升至400℃以上。

8. 发明授权

US4392962A Process for separating metals from aqueous solutions 失效
标题翻译：从水溶液中分离金属的工艺
公开(公告)号：US4392962A
公开(公告)日：1983-07-12
申请号：US318736
申请日：1981-11-06
申请人： Klaus Lehr , Gero Heymer , Christian May , Hermann Klein
发明人： Klaus Lehr , Gero Heymer , Christian May , Hermann Klein
IPC分类号： B01D15/04 , B01J20/20 , C01B25/08 , C01G5/00 , C01G7/00 , C01G55/00 , C02F1/62 , C22B3/00 , C22B3/24 , C22B3/44 , C22B11/00 , C22B15/00 , C22B43/00
CPC分类号： C22B11/04 , C01G5/003 , C01G55/001 , C01G7/003 , C22B15/0089 , C22B3/24 , C22B43/00 , Y02P10/234 , Y02P10/236 , Y10S210/912 , Y10S210/914
摘要： The invention relates to a process for separating seminoble and/or noble metals from an aqueous solution having compounds of these metals dissolved therein by subjecting the solution to reaction with red phosphorus. More particularly, the solution is conveyed through a zone containing a layer of granular red phosphorus particles with a size of 0.01 to 10 mm, which may be used in admixture with active carbon.
摘要翻译：本发明涉及一种通过使溶液与红磷反应从其中溶解有这些金属的化合物的水溶液中分离出半金属和/或贵金属的方法。更具体地说，该溶液被输送通过含有0.01至10mm尺寸的粒状红磷颗粒层的区域，其可与活性炭混合使用。

9. 发明授权

US4705529A Process for reducing the reactivity and improving the flow behavior of phosphorus pentoxide 失效
标题翻译：减少五氧化二磷的反应活性和改善流动行为的方法
公开(公告)号：US4705529A
公开(公告)日：1987-11-10
申请号：US818719
申请日：1986-01-14
申请人： Gunther Schimmel , Werner Kowalski , Gero Heymer , Reinhard Gradl
发明人： Gunther Schimmel , Werner Kowalski , Gero Heymer , Reinhard Gradl
IPC分类号： C01B25/12
CPC分类号： C01B25/12
摘要： The reactivity of phosphorus pentoxide is reduced and its flow behavior improved. To this end, phosphorus pentoxide in the form of its hexagonal modification is annealed over a period of 0.5 to 8 hours at temperatures of 200.degree. to 390.degree. C.
摘要翻译：五氧化二磷的反应性降低，流动性提高。为此，以六角形改性形式的五氧化二磷在200〜390℃的温度下退火0.5〜8小时。

10. 发明授权

US4678650A Process for making an alkali phosphate solution 失效
标题翻译：碱式磷酸盐溶液的制备方法
公开(公告)号：US4678650A
公开(公告)日：1987-07-07
申请号：US715167
申请日：1985-03-22
申请人： Reinhard Gradl , Gero Heymer
发明人： Reinhard Gradl , Gero Heymer
IPC分类号： C01B25/46 , C01B15/16
CPC分类号： C01B25/46
摘要： An aqueous alkali phosphate solution is made. An organic phase is countercurrently mixed with an aqueous phase, the two phases being used in a volume ratio larger than 1:1 and formed aqueous alkali phosphate solution is separated from the remaining organic phase. The two phases are mixed and reacted in a reaction zone comprised of a mixing and separating zone. The organic phase is continuously dispersed in the aqueous phase. A volume excess of aqueous phase is maintained in the mixing zone and the two phases are used in an overall quantity sufficient to provide a volume ratio of organic to aqueous phase of 4:6 to 2:8.
摘要翻译：制备磷酸碱水溶液。有机相与水相逆流混合，两相以体积比大于1:1使用，形成的碱式磷酸碱水溶液与剩余的有机相分离。将两相混合并在由混合和分离区组成的反应区中反应。有机相连续分散在水相中。在混合区中维持体积过量的水相，并且两相的使用量足以提供4:6至2:8的有机相与水相的体积比。

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