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1. 发明授权

US5484830A Halogen-free, flame-resistant polymeric compositions 失效
标题翻译：无卤素，阻燃的聚合物组合物
公开(公告)号：US5484830A
公开(公告)日：1996-01-16
申请号：US187690
申请日：1994-01-26
申请人： Horst Staendeke
发明人： Horst Staendeke
IPC分类号： C08K5/521 , C08G79/04 , C08K3/32 , C08K5/52 , C08K5/529 , C08L85/02 , C08L101/00 , C09K21/14 , C08K5/3477 , C09K21/10 , C09K21/12
CPC分类号： C08K3/32 , C08G79/04 , C08K5/529 , C09K21/14
摘要： Halogen-free, flame-resistant polymeric compositions contain an intumescence flameproofing system which comprises ammonium polyphosphate and an organophosphorus nitrogen component. The organophosphorus nitrogen component here is a phosphoric acid polyester according to the formula ##STR1## In these formulae, R is CH.sub.2, C.sub.2 H.sub.4 or C.sub.3 H.sub.6, while m is 1 to 10 and n is 1 to 6.
摘要翻译：无卤素，阻燃的聚合物组合物含有包含多磷酸铵和有机磷氮组分的膨胀型防火系统。这里的有机磷氮组分是根据下式的化合物聚磷酸酯：式中，R为CH 2，C 2 H 4或C 3 H 6，m为1〜 10，n为1〜6。

2. 发明授权

US4957950A Flame-retardant polymer compositions 失效
标题翻译：阻燃聚合物组合物
公开(公告)号：US4957950A
公开(公告)日：1990-09-18
申请号：US243324
申请日：1988-09-09
申请人： Horst Staendeke , Daniel Scharf
发明人： Horst Staendeke , Daniel Scharf
IPC分类号： C08L101/00 , C08F299/04 , C08K3/22 , C08K5/05 , C08K5/16 , C08K5/49 , C08K9/08 , C08K13/02 , C08K13/06 , C08L67/06
CPC分类号： C08K9/08 , C08K13/02 , C08K13/06
摘要： Flame-retardant polymer compositions contain a flame-retardant system consisting of a phosphorus/nitrogen-component, aluminum hydroxide, and a least one synergetically active component selected from the group consisting of organic nitrogen compounds, polyalcohols or derivatives thereof, the phosphorus/nitrogen-component being ammonium polyphosphate, if desired.
摘要翻译：阻燃聚合物组合物含有由磷/氮组分，氢氧化铝和至少一种选自有机氮化合物，多元醇或其衍生物组成的组中的至少一种协同活性组分组成的阻燃体系，磷/氮 - 组分是多磷酸铵，如果需要。

3. 发明授权

US4701373A Difficultly flammable veneered or coated extruded boards 失效
标题翻译：难燃的单板或涂层挤出板
公开(公告)号：US4701373A
公开(公告)日：1987-10-20
申请号：US915493
申请日：1986-10-06
申请人： Fritz-Reichard Fuchs , Horst Staendeke
发明人： Fritz-Reichard Fuchs , Horst Staendeke
IPC分类号： B32B21/12 , C08K3/32 , C08K9/08 , C08L61/06 , C08L61/28 , C08L63/00 , C08L75/04 , C09K21/12 , C09K21/14 , C08K9/10
CPC分类号： B32B21/12 , C08K3/32 , C08K9/08 , C09K21/12 , C09K21/14 , C08L2201/02 , C08L61/06 , C08L61/28 , C08L63/00 , C08L75/04 , Y10S428/921 , Y10S525/936 , Y10T428/253 , Y10T428/254 , Y10T428/2998 , Y10T428/31594 , Y10T428/31957 , Y10T428/3196
摘要： The disclosure relates to difficulty flammable wooden articles, especially chip boards comprising solid and pipe boards, prepared by extrusion from wooden chips and/or woody fibrous materials. The articles contain as a flame-retarding addend a product of(a) 50 to 99.5 weight % of a flame-retarding agent physically and chemically stable under extrusion conditions, preferably 75 to 99.5 weight % of a pulverulent, free-flowing ammonium polyphosphate of the general formulaH.sub.(n-m)+2 (NH.sub.4).sub.m P.sub.n O.sub.3n+1in which n stands for a whole number with an average value of about 20 to 800 and the ratio of m/n is about 1, and(b) about 0.5 to 50 weight % of a cured water-insoluble artificial resin encapsulating the individual particles of the flame-retarding agent or ammonium polyphosphate.The disclosure also relates to difficulty flammable boards veneered with wood or a laminate.
摘要翻译：本公开涉及难易易燃的木制品，特别是包括固体和管板的芯板，其通过从木屑和/或木质纤维材料挤出而制备。这些制品作为阻燃剂添加了（a）50-99.5重量％的阻燃剂在挤出条件下物理和化学稳定的产物，优选75-99.5重量％的粉末状，自由流动的多磷酸铵通式为H（nm）+2（NH4）mPnO3n + 1，其中n代表整数，平均值约为20〜800，m / n的比例约为1，（b）约为0.5〜 50重量％的固化的不溶于水的人造树脂，其包封阻燃剂或多磷酸铵的各个颗粒。本公开还涉及用木材或层压板镶嵌的易燃板材的难易程度。

4. 发明授权

US4122123A Production of quaternary phosphonium halides 失效
标题翻译：生产季鏻卤化物
公开(公告)号：US4122123A
公开(公告)日：1978-10-24
申请号：US635587
申请日：1975-11-28
申请人： Klaus Hestermann , Horst Staendeke , Bernd Lippsmeier
发明人： Klaus Hestermann , Horst Staendeke , Bernd Lippsmeier
IPC分类号： B01J21/18 , B01J23/00 , B01J23/38 , C07F9/50 , C07F9/53 , C07F9/54
CPC分类号： C07F9/5004 , B01J21/18 , B01J23/38 , C07F9/53 , C07F9/5407
摘要： Production of quaternary phosphonium halides of the general formula:[R.sup.1 R.sup.2 R.sup.3 R.sup.4 P]X,in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 stand for identical or different alkyl groups having from 1 to 4 carbon atoms and X stands for halogen, especially for chlorine or bromine. The compounds are more especially made by flowing hydrogen phosphide or a primary phosphine R.sup.1 PH.sub.2 or secondary phosphine R.sup.1 R.sup.2 PH or tertiary phosphine R.sup.1 R.sup.2 R.sup.3 P and an alkyl halide R.sup.4 X in a molar ratio from 0.02 to 10, at a temperature from 100.degree. to 500.degree. C, under a pressure of up to 10 atmospheres gauge and for a period from 0.5 to 500 seconds over a catalyst and separating the resulting quaternary phosphonium halides from the reaction gas.The halides so made are used for making trialkylphosphine oxides and trialkylphosphines.
摘要翻译：制备以下通式的季鏻卤化物：

5. 发明授权

US4115522A Stabilized red phosphorus and process for making it 失效
标题翻译：稳定的红磷及其制备方法
公开(公告)号：US4115522A
公开(公告)日：1978-09-19
申请号：US814464
申请日：1977-07-11
申请人： Horst Staendeke , Franz-Josef Dany , Joachim Kandler
发明人： Horst Staendeke , Franz-Josef Dany , Joachim Kandler
IPC分类号： C01B25/00 , C01B25/01 , C01B25/02 , C01B25/04
CPC分类号： C01B25/006
摘要： The invention provides stabilized pulverulent red phosphorus. It comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the neutral aluminum, magnesium, calcium or zinc salt of orthophosphoric acid, the metal compound being present in the homogeneous blend in a proportion of about 0.5 to 5 weight %.
摘要翻译：本发明提供稳定的粉红磷。它包括大小为至多约2mm的红磷颗粒的均匀混合物，以及作为氧化稳定剂的周期系统的第二组或第三组的金属化合物，其中金属化合物是中性铝，镁，钙或正磷酸锌盐，金属化合物以约0.5至5重量％的比例存在于均匀共混物中。

6. 发明授权

US5985965A Flame-resistant polyurethanes 失效
标题翻译：耐火聚氨酯
公开(公告)号：US5985965A
公开(公告)日：1999-11-16
申请号：US798783
申请日：1997-02-11
申请人： Martin Sicken , Horst Staendeke
发明人： Martin Sicken , Horst Staendeke
IPC分类号： C08G18/38 , C08G18/64 , C08G79/04 , C08K5/521 , C08L75/00 , C08L75/04 , C08L85/02 , C08K5/52
CPC分类号： C08G79/04 , C08G18/3878 , C08G18/6461 , C08K5/521 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： The flame-resistant polyurethanes of the invention comprise, as flameproofing agents, mixtures of oligomeric phosphoric acid esters which carry hydroxyalkoxy groups, of the formula I ##STR1## in which q denotes an average chain length of 0.5 to 10, R.sub.1 is a hydroxyl-containing radical of the formula II a,R.sub.2 is a radical of the formula III ##STR2## R.sub.3 is a radical of the formula II b, R.sub.4 is R.sub.1 or R.sub.3 ; R.sub.5,R.sub.6 and R.sub.7 are an H atom or an alkyl radical having 1 to 6 carbon atoms, m is 0 to 4 and n is 1 to 4.
摘要翻译：作为防火剂，本发明的阻燃聚氨酯包含式I中携带羟基烷氧基的低聚磷酸酯的混合物，其中+ E，ovs q + EE表示平均链长为0.5至10，R 1为式IIa的含羟基的基团，R2是式III的基团R3是式IIb的基团，R4是R1或R3; R5，R6和R7是H原子或碳原子数为1〜6的烷基，m为0〜4，n为1〜4。

7. 发明授权

US5312853A Flame retardant polymeric compositions 失效
标题翻译：阻燃聚合物组合物
公开(公告)号：US5312853A
公开(公告)日：1994-05-17
申请号：US126142
申请日：1993-09-23
申请人： Horst Staendeke , Daniel J. Scharf
发明人： Horst Staendeke , Daniel J. Scharf
IPC分类号： C08K3/32 , C08K5/3477 , C08K9/08 , C08K5/3492
CPC分类号： C08K9/08 , C08K3/32 , C08K5/3477
摘要： Flame-retardant polymeric compositions, preferably thermoplastic and especially polyolefin-based compositions, containing an intumescent flame-retardant system substantially comprised of a phosphorus component and an organic nitrogen component. The flame-retardant system is more particularly comprised of ammonium polyphosphate and tris-(2-hydroxyethyl) isocyanurate.
摘要翻译：阻燃聚合物组合物，优选热塑性的，尤其是基于聚烯烃的组合物，其包含基本上由磷组分和有机氮组分组成的膨胀型阻燃体系。阻燃体系更具体地由多磷酸铵和三（2-羟乙基）异氰脲酸酯组成。

8. 发明授权

US4670484A Difficulty flammable extruded articles, especially extruded boards, and a process for making them 失效
标题翻译：困难的易燃挤压制品，特别是挤压板，以及制造它们的过程
公开(公告)号：US4670484A
公开(公告)日：1987-06-02
申请号：US667580
申请日：1984-11-02
申请人： Fritz-Reichard Fuchs , Horst Staendeke
发明人： Fritz-Reichard Fuchs , Horst Staendeke
IPC分类号： B27N3/28 , B27N9/00 , B32B21/12 , C08K3/32 , C08K9/08 , C08L61/06 , C08L61/28 , C08L63/00 , C08L75/04 , C08L97/02 , C09K21/12 , C09K21/14 , C08K3/28 , C08K9/10 , C08L1/02
CPC分类号： B27N9/00 , B27N3/28 , B32B21/12 , C08K3/32 , C08K9/08 , C08L97/02 , C09K21/12 , C09K21/14 , C08L2201/02 , C08L61/06 , C08L61/28 , C08L63/00 , C08L75/04 , Y10S428/921 , Y10S525/936 , Y10T428/2998
摘要： The disclosure relates to difficultly flammable wooden articles, especially chip boards comprising solid and pipe boards, prepared by extrusion from wooden chips and/or woody fibrous materials. The articles contain as a flame-retarding addend a product of(a) 50 to 99.5 weight % of a flame-retarding agent physically and chemically stable under extrusion conditions, preferably 75 to 99.5 weight % of a pulverulent, free-flowing ammonium polyphosphate of the general formulaH.sub.(n-m)+2 (NH.sub.4).sub.m P.sub.n O.sub.3n+1in which n stands for a whole number with an average value of about 20 to 800 and the ratio of m/n is about 1, and(b) about 0.5 to 50 weight % of a cured water-insoluble artificial resin encapsulating the individual particles of the flame-retarding agent or ammonium polyphosphate.The disclosure also relates to difficultly flammable boards veneered with wood or a laminate.
摘要翻译：本公开涉及难以易燃的木制品，特别是包括固体和管板的芯片板，其通过从木屑和/或木质纤维材料挤出而制备。这些制品作为阻燃剂添加了（a）50-99.5重量％的阻燃剂在挤出条件下物理和化学稳定的产物，优选75-99.5重量％的粉末状，自由流动的多磷酸铵通式为H（nm）+2（NH4）mPnO3n + 1，其中n代表整数，平均值约为20〜800，m / n的比例约为1，（b）约为0.5〜 50重量％的固化的不溶于水的人造树脂，其包封阻燃剂或多磷酸铵的各个颗粒。本公开还涉及用木材或层压板镶嵌的难易燃的板。

9. 发明授权

US4113841A Stabilized red phosphorus and process for making it 失效
公开(公告)号：US4113841A
公开(公告)日：1978-09-12
申请号：US815160
申请日：1977-07-13
申请人： Horst Staendeke , Franz-Josef Dany , Joachim Kandler , Theodor Auel , Werner Kloss
发明人： Horst Staendeke , Franz-Josef Dany , Joachim Kandler , Theodor Auel , Werner Kloss
IPC分类号： C01B25/023 , C01B25/00
CPC分类号： C01B25/006
摘要： The invention provides stabilized pulverulent red phosphorus. It comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the aluminum, magnesium, calcium or zinc salt of an alkyl-, cycloalkyl-, aryl- or aralkylphosphonic acid having 1 to 20 carbon atoms, the metal compound being present in the homogeneous blend in a proportion of about 0.5 to 5 weight %.

10. 发明授权

US4096189A Production of tertiary phosphine oxides 失效
标题翻译：生产叔膦氧化物
公开(公告)号：US4096189A
公开(公告)日：1978-06-20
申请号：US696921
申请日：1976-06-17
申请人： Horst Staendeke
发明人： Horst Staendeke
IPC分类号： C07F9/53
CPC分类号： C07F9/53
摘要： Production of tertiary phosphine oxides of the general formulaR.sup.1 R.sup.2 R.sup.3 P(O),in which R.sup.1, R.sup.2 and R.sup.3 each stand for identical or different, substituted or unsubstituted alkyl, aryl or aralkyl groups. The tertiary phosphine oxides are produced by oxidizing at temperatures higher than 200.degree. C one or more quaternary phosphonium halides of the general formula[R.sup.1 R.sup.2 R.sup.3 R.sup.4 P] X,in which R.sup.1 through R.sup.3 have the meanings given above, R.sup.4 has the same meaning as R.sup.1 through R.sup.3, and X stands for a halogen atom.
摘要翻译：制备通式为R 1 R 2 R 3 P（O）的叔膦氧化物，其中R 1，R 2和R 3各自代表相同或不同的取代或未取代的烷基，芳基或芳烷基。叔膦氧化物通过在高于200℃的温度下氧化制备一种或多种通式[R1R2R3R4P] X的季鏻卤化物，其中R1至R3具有上述含义，R4具有与R 1至R 3相同的含义，X表示卤素原子。

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