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    • 1. 发明申请
    • Yellow Azo Dyes for Ink Jet Printing
    • 用于喷墨印刷的黄色偶氮染料
    • US20090142554A1
    • 2009-06-04
    • US12083832
    • 2006-10-13
    • Gavin WrightRachel Anne JamesRoy BradburyLynn Bradbury
    • Gavin WrightRachel Anne JamesRoy BradburyLynn Bradbury
    • C09D11/02C07D213/84C07D213/73C07D213/81C07D403/12C07D215/22B05D5/00B41M5/00G01D11/00
    • C09B29/0007C09B29/3639C09D11/328Y10T428/24802
    • A process for printing an image on a substrate by means of an ink-jet printer which comprises applying thereto a composition comprising a liquid medium and a mono-azo compound of Formula (1) and salts thereof: wherein: D is an optionally substituted aryl group carrying at least one direct substituent selected from the group consisting of —SO3H, —CO2H, —PO3H2 or an optionally substituted nitrogen heteroaryl group carrying at least one direct substituent selected from the group consisting of —SO3H, —CO2H, —PO3H2; R1 is H: optionally substituted alkyl: amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; R2 and R3 are each independently preferably amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl: hydroxy —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; X is H, or an electron withdrawing group, or X together with R3 forms an optionally substituted five or six membered carbocycle. Also compositions and inks, compounds and ink-jet printer cartridges.
    • 一种通过喷墨打印机在基片上印刷图像的方法,该方法包括向其施涂包含液体介质和式(1)的单偶氮化合物及其盐的组合物:其中:D为任选取代的芳基 携带至少一个选自-SO 3 H,-CO 2 H,-PO 3 H 2的任选取代的氮杂芳基和至少一个选自-SO 3 H,-CO 2 H,-PO 3 H 2, R 1为H:任选取代的烷基:氨基:-NR 4 R 5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; 和R 5是任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; R2和R3各自独立地优选为氨基:-NR4R5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; 任选取代的酰基,任选取代的芳基,任选取代的杂环基:羟基-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; X是H或吸电子基团,或X与R3一起形成任选取代的五或六元碳环。 还有组合物和油墨,化合物和喷墨打印机墨盒。
    • 2. 发明申请
    • Yellow Azo Dyes for Ink Jet Printing
    • 用于喷墨印刷的黄色偶氮染料
    • US20100068472A1
    • 2010-03-18
    • US12083840
    • 2006-10-13
    • Gavin WrightRachel Anne JamesRoy BradburyLynn Patricia Bradbury
    • Gavin WrightRachel Anne JamesRoy BradburyLynn Patricia Bradbury
    • B32B3/10B05D5/00C09D11/00C09B29/36C09B31/14
    • C09B29/3669C09B29/0007C09B29/0014C09B35/03C09D11/328Y10T428/24802
    • Monomers and dimers of mono-azo compounds of formula wherein: D is an optionally substituted aryl or an optionally substituted heteroaryl group; R1 and R2 are each independently optionally substituted alkyl: halo: amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl or R4 together with R5 and the nitrogen to which they are attached forms an optionally substituted 5 or 6 membered ring: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; R3 is amino: halo; —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl or R4 together with R5 and the nitrogen to which they are attached forms an optionally substituted 5 or 6 membered ring: hydroxy: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl. Also compositions, inks and ink-jet cartridges containing these compounds and ink-jet printing processes using these compounds.
    • 单偶氮和二聚体的单偶氮化合物其中:D是任选取代的芳基或任选取代的杂芳基; R 1和R 2各自独立地是任选取代的烷基:卤素:氨基:-NR 4 R 5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; R 5是任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基或R 4与R 5一起,它们所连接的氮形成任选取代的5或6元环:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; R3是氨基:卤素; -NR4R5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; R 5为任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基或R 4与R 5一起并与它们相连的氮形成任选取代的5或6元环:羟基:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7是任选取代的烷基。 也包含这些化合物的组合物,油墨和喷墨墨盒以及使用这些化合物的喷墨印刷方法。
    • 5. 发明申请
    • Ink-Jet Printing Using Disazo Dyes
    • 喷墨打印使用双偶氮染料
    • US20090017278A1
    • 2009-01-15
    • US12086981
    • 2006-12-18
    • Rachel Anne James
    • Rachel Anne James
    • B41J2/175C09D11/02B05D5/00B32B3/10
    • C09B31/14C09B35/50C09B43/00C09D11/328Y10T428/24934
    • Compounds of Formula (1) and dimers thereof: wherein: A and B independently are optionally substituted aryl or optionally substituted heteroaryl groups; R1 and R2 are each independently optionally substituted alkyl: halo: amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl or R4 together with R5 and the nitrogen to which they are attached forms an optionally substituted 5 or 6 membered ring: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; R3 is optionally substituted alkyl: halo: amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl or R4 together with R5 and the nitrogen to which they are attached forms an optionally substituted 5 or 6 membered ring: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; also ink-jet inks and processes and printed materials.
    • 式(1)的化合物及其二聚体:其中:A和B独立地为任选取代的芳基或任选取代的杂芳基; R 1和R 2各自独立地是任选取代的烷基:卤素:氨基:-NR 4 R 5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; R 5是任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基或R 4与R 5一起,它们所连接的氮形成任选取代的5或6元环:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; R3是任选取代的烷基:卤素:氨基:-NR4R5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; R 5是任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基或R 4与R 5一起,它们所连接的氮形成任选取代的5或6元环:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; 还有喷墨油墨和工艺和印刷材料。
    • 10. 发明授权
    • Metallized azo dyes and inks for ink-jet printing containing same
    • 金属化偶氮染料和含有其的喷墨印刷用油墨
    • US06712890B2
    • 2004-03-30
    • US10050178
    • 2002-01-18
    • Maria Soteri HadjisoteriouRachel Anne James
    • Maria Soteri HadjisoteriouRachel Anne James
    • C09D1102
    • C09D11/328C09B45/14C09B45/22
    • A water soluble compound of Formula (1) or a salt thereof: wherein: Y is an electron withdrawing group; Y1 is H, alkyl or aryl, OR or NR2 in which each R independently is H, optionally substituted alkyl or optionally substituted aryl; or Y and Y1 together form a 5- or 6- membered ring; X1 is a group or atom with co-ordinates with M; M is hexa co-ordinate metal; G is a group of Formula (2), (3) or (4); and L1, L2 and L3, each independently represent ligands required to complete hexa-coordinate geometry around metal M; wherein: S is a water solubilizing group; Ar is a benzene or naphthalene group in which X is located ortho to the azo group; X is a group or atom which co-ordinates with M; Z provides atoms or groups which complete an optionally substituted 5- or 6-membered aromatic heterocyclic ring; Ring A is an optionally substituted aromatic ring; Ring B is an optionally substituted 5- or 6-membered aromatic heterocyclic ring; n is 0, 1, 2 or 3; and the * signify the points of attachment of the groups of Formulae (2), (3) and (4) to the N and M atoms in the compound of Formula (1). The compounds are used in compositions for ink jet printing.
    • 式(1)的水溶性化合物或其盐:其中:Y是吸电子基团; Y 1是H,烷基或芳基,OR或NR 2,其中每个R独立地是H,任选取代的烷基或任选地 取代的芳基;或Y和Y 1一起形成5-或6-元环; X 1是与M具有坐标的基团或原子; M是六配位金属; G是 式(2),(3)或(4); 和L 1,L 2和L 3各自独立地表示在金属M周围完成六坐标几何形状所需的配体;其中:S是水溶性基团; Ar是苯或萘基,其中X是 位于偶氮基的邻位; X是与M相配的基团或原子; Z提供完成任选取代的5或6元芳族杂环的原子或基团;环A是任选取代的芳环;环 B是任选取代的5或6元芳族杂环; n是0,1,2或3; 并且*表示式(2),(3)和(4)的基团与式(1)化合物中的N和M原子的连接点。该化合物用于喷墨印刷用组合物中。