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    • 2. 发明授权
    • Print-out compositions
    • 印刷组合物
    • US4598036A
    • 1986-07-01
    • US649002
    • 1984-09-10
    • Masayuki IwasakiMinoru MaedaFumiaki ShinozakiSadao Ishige
    • Masayuki IwasakiMinoru MaedaFumiaki ShinozakiSadao Ishige
    • G03C1/675G03C1/73G03F7/105G03C1/52G03C1/68
    • G03F7/105G03C1/732
    • A print-out composition containing a leuco dye and a photooxidizing agent is described, said print-out composition containing at least one carbazomethane compound represented by formula (I) as the leuco dye ##STR1## wherein Y represents an amino group-substituted phenyl group represented by formula (Ia) ##STR2## or an indolyl group represented by formula (Ib) ##STR3## wherein X.sub.1 and X.sub.2 each represents a hydrogen atom, an unsubstituted alkyl group, or an alkyl group substituted by a halogen atom, a hydroxy group, a cyano group, or a lower alkoxy group, said alkyl group having up to 12 carbon atoms, a cycloalkyl group, a phenyl group, a benzyl group, or a phenyl or benzyl group substituted by a halogen atom, a lower alkyl group, or a lower alkoxy group, or said X.sub.1 and X.sub.2 together may form a 5-membered or 6-membered heterocyclic group together with the nitrogen atom bonded thereto; X.sub.3 represents a hydrogen atom, a halogen atom, a nitro group, a lower alkyl group, or a lower alkoxy group; R.sub.1 and Z.sub.1 each represents a hydrogen atom, an unsubstituted alkyl group or an alkyl group substituted by a halogen atom having up to 12 carbon atoms, a hydroxy group, a cyano group, or a lower alkoxy group, an alkenyl group having up to 12 carbon atoms, an acyl group having from 1 to 12 carbon atoms, a phenyl group, a benzyl group, or a phenyl or benzyl group substituted by a member selected from the group consisting of a halogen atom, a lower alkyl group, a lower alkoxy group, and a nitro group; Z.sub.2 represents a hydrogen atom, a lower alkyl group, or a phenyl group; and rings A, B, and D each may be further substituted by a cyano group, a nitro group, a halogen atom, a lower alkyl group, a lower alkoxy group, or a lower alkylcarbonyl group.
    • 描述了含有无色染料和光氧化剂的印刷组合物,所述印刷组合物含有至少一种由式(I)表示的咔唑甲烷化合物作为无色染料(I),其中Y表示氨基 - (Ia)表示的取代苯基或由式(Ib)表示的吲哚基(Ib)其中X1和X2各自表示氢原子,未取代的烷基或烷基 被卤素原子,羟基,氰基或低级烷氧基取代,所述烷基具有至多12个碳原子,环烷基,苯基,苄基或苯基或苄基被 卤素原子,低级烷基或低级烷氧基,或者所述X1和X2一起可以与键合的氮原子一起形成5元或6元杂环基; X3表示氢原子,卤素原子,硝基,低级烷基或低级烷氧基; R1和Z1各自表示氢原子,未取代的烷基或被具有至多12个碳原子的卤素原子,羟基,氰基或低级烷氧基取代的烷基,具有至多12个 碳原子,具有1至12个碳原子的酰基,苯基,苄基或被选自以下的成员所取代的苯基或苄基:卤原子,低级烷基,低级烷氧基 组和硝基; Z2表示氢原子,低级烷基或苯基; 环A,B和D各自可以进一步被氰基,硝基,卤素原子,低级烷基,低级烷氧基或低级烷基羰基取代。
    • 3. 发明授权
    • Melting type thermal transfer recording device and melting type thermal
transfer recording method
    • 熔融型热转印记录装置和熔融型热转印记录方法
    • US6133929A
    • 2000-10-17
    • US392094
    • 1999-09-08
    • Toshihiko NegoroYoshiyuki ObataFumiaki Shinozaki
    • Toshihiko NegoroYoshiyuki ObataFumiaki Shinozaki
    • B41J2/335B41J2/325
    • B41J2/33515B41J2/33545B41J2/3357
    • A melting type thermal transfer recording system capable of providing multi-gradation images of high resolution and high image quality comparable to those of ink jet recording system or sublimation type thermal transfer recording system is disclosed which comprising: a donor film comprising a thin film and a thermal melting type ink layer provided on the thin film, the thermal melting type ink layer having a thickness in a range of 0.5 to 2.5 .mu.m, a surface porous type recording medium comprising a base material and a porous ink receiving layer having numerous minute pores provided on the base material, the ratio of the first total area of aperture portions that are occupied by all the pores to the whole surface area of the porous ink receiving layer being in a range of 10 to 60%, and the ratio of the second total area of aperture portions that are occupied by pores having a pore diameter of 0.5 to 20 .mu.m to the first total area of the aperture portions being 70 to 100%, a thermal head comprising a plurality of heating resistor units arranged in a line at intervals of 8 dots/mm or less, each of the heating resistor units comprising a pair of heating resistor elements of identical shape, a gradation control means for controlling an amount of an ink of the ink layer melted with the heating resistor units by controlling an amount of electricity supplied to the thermal head.
    • 公开了一种熔融型热转印记录系统,其能够提供与喷墨记录系统或升华型热转印记录系统相当的高分辨率和高图像质量的多灰度图像,其包括:施主膜,其包括薄膜和 设置在薄膜上的热熔型油墨层,热熔型油墨层的厚度在0.5〜2.5μm的范围内,表面多孔型记录介质包括基材和具有许多微孔的多孔油墨接收层 设置在所述基材上,所述多孔墨水接收层的所有孔的占据的开口部的第一总面积与所述多孔墨接受层的整个表面积的比率为10〜60%的范围,所述第二 孔径为孔径部分的第一总面积为0.5〜20μm的孔所占据的开口部的总面积为70〜100% ad包括以8点/ mm以下的间隔配置成一行的多个发热电阻体,每个加热电阻单元包括一对相同形状的加热电阻元件,用于控制墨水量的灰度控制装置 通过控制供给到热敏头的电量而与加热电阻器单元熔融的油墨层。
    • 4. 发明授权
    • Method of forming a spacer for use in a liquid crystal panel
    • 形成用于液晶面板的间隔物的方法
    • US5593802A
    • 1997-01-14
    • US319567
    • 1994-10-07
    • Morimasa SatoFumiaki Shinozaki
    • Morimasa SatoFumiaki Shinozaki
    • G02F1/1339C09K19/00G02F1/13
    • G02F1/13394
    • A method of forming a spacer for supporting two substrates which constitute a liquid crystal panel, wherein the spacer is disposed between the two substrates, at least one of which has thereon an alignment layer which has been subjected to aligning treatment, comprising the steps of: (1) laminating the substrate having the alignment layer on a transfer sheet comprising projections of substantially uniform thickness on a temporary support in such a manner that the projections closely contact the alignment layer, and (2) peeling-off the temporary support to transfer the projections onto the alignment layer. The inventive method forms a spacer through a simple step and at a uniform density, and prevents damage of an aligning layer.
    • 一种形成用于支撑构成液晶面板的两个基板的间隔件的方法,其中所述间隔件设置在所述两个基板之间,其中至少一个在其上具有经过对准处理的取向层,包括以下步骤: (1)将具有取向层的基板在具有基本上均匀厚度的突起的转印片上以临时支撑体的方式层叠,使得突起紧密接触对准层,和(2)剥离临时支撑以转移 投影到对准层上。 本发明的方法通过简单的步骤和均匀的密度形成间隔物,并且防止对准层的损坏。
    • 5. 发明授权
    • Image formation process
    • US5455142A
    • 1995-10-03
    • US964052
    • 1992-10-21
    • Yohnosuke TakahashiHideyuki NakamuraFumiaki ShinozakiShinji Tsuno
    • Yohnosuke TakahashiHideyuki NakamuraFumiaki ShinozakiShinji Tsuno
    • G03F3/10G03C3/00
    • G03F3/103
    • An image formation process uses two light-sensitive elements comprising first and second adhesive light-sensitive layers which become nonadhesive upon exposure to light, respectively, and first and second toner elements comprising toner layers (a') and (b') of hues (a) and (b), respectively. The process steps include:A) imagewise exposing the first light-sensitive layer;B) contacting the first light-sensitive layer with layer (a') in the first toner element;C) separating the first toner element and the first light-sensitive element, transferring the toner layer portion corresponding to the unexposed portion of the light-sensitive layer to the light-sensitive layer and leaving the toner layer portion corresponding to the exposed portion of the light-sensitive layer on the support for the first toner element;D) contacting the adhesive surface of an image receiving element with the surface of the toner layer of the first toner element on which the toner layer has been left corresponding to the exposed portion of the first light-sensitive layer;E) separating the image receiving element and the first toner element, transferring the toner layer to the image receiving element;F) repeating A) to C) with the second light-sensitive element and toner element, respectively; andG) contacting the surface of the transferred toner layer of the image receiving element on which the hue (a) toner layer has been transferred with the surface of the hue (b) toner layer and separating the image receiving element and the second toner element, transferring the hue (b) toner layer to the image receiving element.
    • 6. 发明授权
    • Image formation method using a photosensitive transfer material
    • 使用光敏转印材料的图像形成方法
    • US5397678A
    • 1995-03-14
    • US216327
    • 1994-03-23
    • Morimasa SatoMasayuki IwasakiFumiaki ShinozakiKoji Inoue
    • Morimasa SatoMasayuki IwasakiFumiaki ShinozakiKoji Inoue
    • G03F3/10G03F7/16G03F7/34H05K3/00G03C11/12
    • G03F7/161G03F3/10G03F7/346H05K3/0079
    • A photosensitive transfer material comprises a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the interlaminar adhesion in the transfer material being the smallest at the interface between the thermoplastic resin layer and the temporary substrate. The photosensitive resin layer can be transferred to a permanent substrate without involving failure due to fine dust, air bubbles or unevenness of the permanent substrate. An image can be formed with the transfer material by adhering the transfer material to a permanent substrate at least under heat and, after stripping the temporary substrate, imagewise exposing the photosensitive resin layer to light, and processing the transferred layers to develop the photosensitive resin layer. If the thermoplastic resin layer and the intermediate layer are first removed with a processing method with which the photosensitive resin layer is not substantially developed and then the photosensitive resin layer is developed using a processing solution other than used for revmoving the thermoplastic resin layer and the intermediate layer, excessive fatigue of the developing solution for the photosensitive resin layer and unevenness of development can be prevented.
    • 光敏转印材料包括依次设置有碱溶性热塑性树脂树脂层,中间层和感光性树脂层的临时基材,在热塑性树脂层之间的界面处,转印材料中的层间粘合力最小 和临时衬底。 可以将感光性树脂层转印到永久性基板上,而不会由于细小的灰尘,气泡或永久基板的不均匀性而导致故障。 可以通过至少在加热下将转印材料粘附到永久性基板上,并且在剥离临时基板之后,使感光性树脂层成像曝光,并且处理转印层以显影感光性树脂层 。 如果首先用感光性树脂层未显影的处理方法去除热塑性树脂层和中间层,然后使用除了用于将热塑性树脂层和中间体的旋转以外的处理溶液使感光性树脂层显影 可以防止感光性树脂层的显影液的过度疲劳和显影不均匀。
    • 9. 发明授权
    • Photopolymerizable composition
    • 可光聚合组合物
    • US5124236A
    • 1992-06-23
    • US215707
    • 1988-07-06
    • Jun YamaguchiShintaro WashizuFumiaki Shinozaki
    • Jun YamaguchiShintaro WashizuFumiaki Shinozaki
    • C08F2/50G03F7/00G03F7/027G03F7/029G03F7/031
    • G03F7/031G03F7/002G03F7/027G03F7/029Y10S430/115Y10S430/121Y10S430/122
    • A photopolymerizable composition is disclosed, which comprises a photopolymerizable compound and a photopolymerization initiator comprising a cationic dye, an organic boron compound and a compound having an --SH group in the molecule thereof, and which can be used for making printing plates, as resist materials for making printed circuit boards, as color proof materials, etc.The photopolymerizable composition can be applied for an image-forming process utilizing microcapsules, which comprises the steps of encapsulating the photopolymerizable composition with a color image-forming material in the core of microcapsules, coating the microcapsules on a support to form a photosensitive sheet, imagewise exposing the photosensitive sheet, superposing the photosensitive sheet on an image-receiving sheet, pressing the whole surface of the assembly to rupture the microcapsules at the unexposed portions, and transferring the color image-forming material into the image-receiving sheet.The color image obtained by using the photopolymerizable composition exhibits high sensitivity.
    • 公开了一种可光聚合组合物,其包含光聚合化合物和包含阳离子染料,有机硼化合物和其分子中具有-SH基团的化合物的光聚合引发剂,并且其可用于制备印刷版,作为抗蚀剂材料 用于制造印刷电路板,作为耐色材料等。可光聚合组合物可以应用于利用微胶囊的成像方法,其包括将可光聚合组合物与彩色图像形成材料包封在微胶囊芯中的步骤, 将微胶囊涂布在支撑体上以形成感光片,成像曝光感光片,将感光片重叠在图像接收片上,按压组件的整个表面以在未曝光部分破裂微胶囊,并转印彩色图像 形成材料进入图像接收片材。 通过使用可光聚合组合物获得的彩色图像显示出高灵敏度。