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    • 4. 发明专利
    • Fullerene derivative, fullerene metal complex, and method for producing the same
    • 富勒烯衍生物,富勒烯金属络合物及其生产方法
    • JP2005232165A
    • 2005-09-02
    • JP2005014594
    • 2005-01-21
    • Mitsubishi Chemicals CorpEiichi Nakamura三菱化学株式会社栄一 中村
    • NAKAMURA EIICHIMATSUO YUTAKATAWARA KAZUKUNI
    • C07C13/62C07C25/22C07C43/20C07F1/06C07F15/00C07F17/00
    • PROBLEM TO BE SOLVED: To provide a new fullerene derivative having such a structure that 6 or 7 organic groups each composed of 1 to 20 carbon atoms are attached to a fullerene C 70 skeleton. SOLUTION: A method for producing the new fullerene derivative (fullerene metal complex) comprises reacting a fullerene with a monovalent organic copper reagent. The method is industrially advantageous, because it effectively produces the fullerene derivative in a small number of processes. A metal atom used in the method is not specifically limited, but each of the group 1 metal atoms and the group 8 transition metals is especially preferably used. A complex of the group 1 metal has reactivity with a cyclopentadienyl site of the fullerene skeleton, so that the complex is useful as a reactive intermediate and, on the other hand, a complex of the group 8 transition metal is stable, so that the complex is used for materials of various kinds as it is. The new fullerene derivative is suitably used in various fields, such as a field of electronic materials, semiconductors, and physiologically active substances. COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:提供一种具有这样的结构的新的富勒烯衍生物,其具有每个由1-20个碳原子组成的6或7个有机基团连接到富勒烯C 70 SB骨架上。 解决方案:制备新的富勒烯衍生物(富勒烯金属络合物)的方法包括使富勒烯与一价有机铜试剂反应。 该方法在工业上是有利的,因为它有效地在少量工艺中产生富勒烯衍生物。 该方法中使用的金属原子没有特别限定,特别优选使用1族金属原子和8族过渡金属。 第1族金属的络合物与富勒烯骨架的环戊二烯基部位具有反应性,因此该络合物可用作反应性中间体,另一方面,第8族过渡金属的络合物是稳定的,使得络合物 用于各种材料。 新的富勒烯衍生物适用于各种领域,例如电子材料,半导体和生理活性物质领域。 版权所有(C)2005,JPO&NCIPI