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1. 发明授权

US3993601A Process for preparing a heavy crude conversion catalyst 失效
标题翻译：制备重质粗转化催化剂的方法
公开(公告)号：US3993601A
公开(公告)日：1976-11-23
申请号：US533313
申请日：1974-12-16
申请人： Fred M. Long , Willard H. Sawyer
发明人： Fred M. Long , Willard H. Sawyer
IPC分类号： B01J23/74 , B01J23/85 , B01J35/10 , B01J37/00 , C10G45/08 , B01J21/04 , B01J23/10 , B01J23/84
CPC分类号： B01J37/0009 , B01J23/74 , B01J23/85 , B01J35/10 , C10G45/08 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1085
摘要： This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree. F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree. F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalyst. One of the catalysts, i.e., one having properties inclusive of a large number of pores in the 100-275A pore size diameter range, is particularly suitable as a first stage catalyst and the other, which has properties inclusive of a large number of pores in the 100-200A pore size diameter, is especially suitable as a second stage catalyst for use in processing the effluent of said first stage.
摘要翻译：本发明涉及两种不同类型的新型催化剂，其可用于重质原油和残余物中所含的1050°F +烃材料的催化加氢转化，使得所得产物将适用于常规精炼操作中的进一步加工，从而使清洁液体产品。使用包括VIB族和VIII族金属的催化剂，优选以混合物形式，优选包括具有特定临界范围物理特性（包括大的均匀孔径）的IVA族金属，特别是锗，用于转化，这些已经显示具有改善催化活性和选择性的1050°F +重料和残渣的材料的加氢转化。描述了用于制备这种催化剂的新方法，以及使用这种催化剂。一种催化剂，即在100-275A孔径范围内具有包括大量孔的特性的催化剂，特别适合作为第一级催化剂，另一种具有包括大量孔的性质 100-200A孔径直径，特别适用于用于处理所述第一阶段的流出物的第二阶段催化剂。

2. 发明授权

US3989645A Process for preparing a heavy crude conversion catalyst 失效
标题翻译：制备重质粗转化催化剂的方法
公开(公告)号：US3989645A
公开(公告)日：1976-11-02
申请号：US533311
申请日：1974-12-16
申请人： Fred M. Long , Willard H. Sawyer
发明人： Fred M. Long , Willard H. Sawyer
IPC分类号： B01J23/74 , B01J23/85 , B01J35/10 , B01J37/00 , C10G45/08 , B01J21/04 , B01J23/10 , B01J23/84
CPC分类号： B01J23/85 , B01J23/74 , B01J35/10 , B01J37/0009 , C10G45/08 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061
摘要： This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree. F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree. F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalysts. One of the catalysts, i.e., one having properties inclusive of a large number of pores in the 100-275A pore size diameter range, is particularly suitable as a first stage catalyst and the other, which has properties inclusive of a large number of pores in the 100-200A pore size diameter, is especially suitable as a second stage catalyst for use in processing the effluent of said first stage.
摘要翻译：本发明涉及两种不同类型的新型催化剂，其可用于重质原油和残余物中所含的1050°F +烃材料的催化加氢转化，使得所得产物将适用于常规精炼操作中的进一步加工，从而使清洁液体产品。使用包括VIB族和VIII族金属的催化剂，优选以混合物形式，优选包括具有特定临界范围物理特性（包括大的均匀孔径）的IVA族金属，特别是锗，用于转化，这些已经显示具有改善催化活性和选择性的1050°F +重料和残渣的材料的加氢转化。描述了用于制备这种催化剂的新方法，以及用于这种催化剂的方法。一种催化剂，即在100-275A孔径范围内具有包括大量孔的特性的催化剂，特别适合作为第一级催化剂，另一种具有包括大量孔的性质 100-200A孔径直径，特别适用于用于处理所述第一阶段的流出物的第二阶段催化剂。

3. 发明授权

US5258567A Dehydrogenation of hydrocarbons 失效
标题翻译：烃的脱氢
公开(公告)号：US5258567A
公开(公告)日：1993-11-02
申请号：US935503
申请日：1992-08-26
申请人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
发明人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
IPC分类号： C07C5/09 , C07C5/32 , C07C5/333
CPC分类号： B01J29/049 , C07C5/324 , C07C5/325 , C07C5/3337
摘要： This invention relates to a process for the dehydrogenation of C.sub.2 -C.sub.10 hydrocarbons at dehydrogenation conditions with a pillared mica catalyst which contains an active metal selected from the group consisting of Pt, Cr and mixtures thereof, and a first modifier metal selected from the group consisting of Sn, Ga and mixtures thereof. The micas may also contain a second modifier metal selected from the group consisting of alkali metals, alkaline earth metals, and rare earth metals, and mixtures thereof.
摘要翻译：本发明涉及使用含有选自Pt，Cr及其混合物的活性金属的柱撑云母催化剂在脱氢条件下脱氢C2-C10烃的方法和选自以下的第一种改性金属：的Sn，Ga及其混合物。云母还可以含有选自碱金属，碱土金属和稀土金属的第二改性金属及其混合物。

4. 发明授权

US5340657A Pillared micas 失效
标题翻译：柱状云母
公开(公告)号：US5340657A
公开(公告)日：1994-08-23
申请号：US935504
申请日：1992-08-26
申请人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
发明人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
IPC分类号： B01J29/04 , B22F5/00 , B28D1/32
CPC分类号： B01J29/049 , Y10T428/12056
摘要： This invention relates to pillared micas, which comprise an active metal selected from the group consisting of Pt, Cr, Pd, It, Rh and mixtures thereof, and a first modifier metal selected from the group consisting of Sn, Ga and mixtures thereof. The mica may also be modified with a second modifier metal selected from the group consisting of alkali metals, alkaline earth metals, or rare earth metals and mixtures thereof. This invention further relates to a process for preparing such a catalyst.
摘要翻译：本发明涉及柱状云母，其包含选自Pt，Cr，Pd，It，Rh及其混合物的活性金属和选自Sn，Ga及其混合物的第一修饰金属。云母也可以用选自碱金属，碱土金属或稀土金属的第二种改性金属及其混合物进行改性。本发明还涉及制备这种催化剂的方法。

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