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1. 发明授权

US5705083A Stabilizing leather against thermal and photochemical decomposition 失效
标题翻译：稳定皮革，防止热和光化学分解
公开(公告)号：US5705083A
公开(公告)日：1998-01-06
申请号：US662735
申请日：1996-06-10
申请人： Franz Wyss , Vladimir Arnold , Helena Dbaly , Gisbert Leuschner , Manfred Rembold , Alois Puntener
发明人： Franz Wyss , Vladimir Arnold , Helena Dbaly , Gisbert Leuschner , Manfred Rembold , Alois Puntener
IPC分类号： C08K5/3435 , C08K5/3492 , C09K3/00 , C09K15/06 , C14C9/00 , D06N3/00 , C14C9/02 , C14C11/00
CPC分类号： C08K5/34926 , C08K5/3435 , C14C9/00 , D06N3/0059
摘要： Water-emulsifiable or -dispersible physical forms of sterically hindered mines, UV absorbers and antioxidants and their use for thermal and photochemical stabilization of materials of plastics, textile coatings, imitation leather and leather are described. The physical forms comprise a) a sterically hindered amine, b) a UV absorber and/or c) an antioxidant and d) if appropriate, water and other additives.
摘要翻译：描述了空间位阻矿物，UV吸收剂和抗氧化剂的水可乳化或分散的物理形式及其对塑料，纺织品涂料，仿皮革和皮革材料的热和光化学稳定化的用途。物理形式包括a）空间位阻胺，b）UV吸收剂和/或c）抗氧化剂和d）如果合适的话，水和其它添加剂。

2. 发明授权

US5023274A Fibre-reactive formazan dyes containing .beta.-halogenethyl or vinylsulfonyl-alkanoylamino fiber-reactive groups 失效
标题翻译：含有β-卤代乙基或乙烯基磺酰基 - 烷酰氨基纤维反应性基团的纤维反应型甲an染料
公开(公告)号：US5023274A
公开(公告)日：1991-06-11
申请号：US342925
申请日：1989-04-25
申请人： Alois Puntener , Urs Lehmann , Peter Scheibli , Josef Koller
发明人： Alois Puntener , Urs Lehmann , Peter Scheibli , Josef Koller
IPC分类号： C09B29/00 , C09B62/503 , C09B67/22
CPC分类号： C09B62/5036 , C09B67/0041
摘要： The fibre-reactive formazan dyes of the formula ##STR1## where X is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, cyano or nitro, Y is .beta.-haloethyl or vinyl, m is 1, 2 or 3, n is 3 or 4, p is 0, 1 or 2 and q is 0 or 1, produce dyeings having good fastness properties on nitrogen-containing or hydroxyl-containing fibre materials.
摘要翻译：式（1）其中X为C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，氰基或硝基，Y为β-卤代乙基或乙烯基的纤维反应型甲an染料为1,2或3， n为3或4，p为0,1或2，q为0或1，产生对含氮或含羟基纤维材料具有良好牢度性能的染色。

3. 发明授权

US4962191A 1:2 chromium or cobalt complex axo dyes containing at least one 2-aryl-4-amino-6-hydroxypyrimidine radical 失效
标题翻译： 1：2含有至少一个2-芳基-4-氨基-6-羟基嘧啶基的铬或钴络合物轴染料
公开(公告)号：US4962191A
公开(公告)日：1990-10-09
申请号：US399202
申请日：1989-08-28
申请人： Alois Puntener , Kurt Burdeska
发明人： Alois Puntener , Kurt Burdeska
IPC分类号： C07D239/47 , C07D239/48 , C07D405/04 , C09B45/14 , D06P1/10 , D06P3/24 , D06P3/32 , D06P3/60 , D06P3/79
CPC分类号： D06P1/10 , C09B45/14
摘要： Dyes suitable for dyeing a wide range of textile and non-textile materials, in particular for dyeing leather and pelts, having, in the form of the free acid, the formula ##STR1## wherein D.sub.1 and D.sub.2 are each independently of the other the radical of a diazo component of the benzene or naphthalene series which carries a hydroxy or carboxy in ortho-position to the azo group and which may or may not be further substituted,K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series which carries the group X in ortho-position to the azo group and which may or may not be further substituted,Me is chromium or cobalt,Q is an unsubstituted or substituted phenyl or naphthyl radical or an unsubstituted or substituted aromatic-heterocyclic radical,R.sub.1 is unsubstituted or substituted C.sub.1 -C.sub.6 alkyl or unsubstituted or substituted phenyl,R.sub.2 is hydrogen or independently has the meaning of R.sub.1, X is --O-- or --NR.sub.3,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, andp and q are each independently of the other 0 or 1.
摘要翻译：适用于染色各种纺织和非纺织材料的染料，特别是染色皮革和毛皮，具有游离酸形式的式（1），其中D1和D2各自独立地为另一个苯或萘系列的重氮组分的基团，其在偶氮基的邻位带有羟基或羧基，并且可以被进一步取代，K是苯或萘的偶联组分的基团系列或杂环系列，其携带基团X在偶氮基上邻位并且可以被进一步取代，Me是铬或钴，Q是未取代或取代的苯基或萘基或未取代或取代的芳基 - 杂环基，R 1是未取代的或取代的C 1 -C 6烷基或未取代或取代的苯基，R 2是氢或独立地具有R 1，X是-O-或-NR 3，R 3是氢或C 1 -C 4烷基，p和 q 各自独立于0或1。

4. 发明授权

US4652269A Process for the continuous trichromatic dyeing of synthetic polyamide materials: including a blue anthraquinone reactive dye 失效
标题翻译：合成聚酰胺材料的连续三色染色工艺：包括蓝色蒽醌活性染料
公开(公告)号：US4652269A
公开(公告)日：1987-03-24
申请号：US857681
申请日：1986-04-30
申请人： James B. Bowles , Marshall White, Jr. , Alois Puntener , Jean-Marie Adam , Peter Loew
发明人： James B. Bowles , Marshall White, Jr. , Alois Puntener , Jean-Marie Adam , Peter Loew
IPC分类号： C09B67/22 , D06P3/24 , C09B49/00 , C09B62/00
CPC分类号： D06P3/241 , C09B67/0041 , D06P3/248 , Y10S534/01 , Y10S8/924
摘要： Process for the continuous trichromatic dyeing of synthetic polyamide materials which comprises using at least one blue-dyeing fibre-reactive sulfo-containing anthraquinone dye together with at least one red-dyeing sulfo-containing azo dye and at least one yellow- or orange-dyeing sulfo-containing azo dye.The process according to the invention is suitable for the continuous dyeing of synthetic polyamide materials from aqueous liquors, producing level dyeings having good fastness properties, in particular good ozone fastness.
摘要翻译：用于合成聚酰胺材料的连续三色染色的方法，其包括使用至少一种蓝染色纤维反应性含磺基蒽醌染料与至少一种红染色的含磺基偶氮染料和至少一种黄色或橙色染色含磺基偶氮染料。根据本发明的方法适用于从水性液体中连续染色合成聚酰胺材料，产生具有良好牢度性能的特别染色，特别是良好的耐臭氧性。

5. 发明授权

US4507124A 1:2 Metal complexes of azomethine dyes having arylazo groups 失效
标题翻译： 1：2具有芳基偶氮基的偶氮甲碱染料的金属络合物
公开(公告)号：US4507124A
公开(公告)日：1985-03-26
申请号：US505647
申请日：1983-06-20
申请人： Alois Puntener , Fabio Beffa
发明人： Alois Puntener , Fabio Beffa
IPC分类号： C09B45/24 , C09B55/00
CPC分类号： C09B55/001 , Y10S8/917 , Y10S8/924
摘要： The dyes of the formula I ##STR1## in which Me is cobalt or chromium, A and A' independently of each other are each the radical of an amine of the benzene series which carries the hydroxyl group in the o-position relative to the azomethine group, Ar.sub.1 and Ar.sub.3 independently of each other are each a substituted or unsubstituted phenylene or naphthylene radical, Ar.sub.2 and Ar.sub.4 independently of each other are each a substituted or unsubstituted benzene or naphthalene radical, m and n independently of each other are each 0 or 1, p is an integer from 3 to 6 and Ka.sym. is a cation, are suitable for dyeing polyamides, particularly wool and leather.
摘要翻译：其中Me是钴或铬的式I（I）的染料，A和A'彼此独立地分别是在相对位置携带羟基的苯系列的胺基团对于偶氮甲碱基团，Ar 1和Ar 3彼此独立地各自为取代或未取代的亚苯基或亚萘基，Ar 2和Ar 4彼此独立地各自为取代或未取代的苯或萘基，m和n各自独立地为彼此 0或1，p为3至6的整数，Ka（+）为阳离子，适用于染色聚酰胺，特别是羊毛和皮革。

6. 发明授权

US5376147A Process for dyeing leather with dye mixtures 失效
标题翻译：用染料混合物染色皮革的方法
公开(公告)号：US5376147A
公开(公告)日：1994-12-27
申请号：US025214
申请日：1993-02-26
申请人： Campbell Page , Peter Moser , Alois Puntener
发明人： Campbell Page , Peter Moser , Alois Puntener
IPC分类号： C09B67/22 , D06P3/32
CPC分类号： C09B67/0055 , D06P3/3226
摘要： Dye mixtures comprising at least two metal-free dyes of different colors having in each case two sulfo or carboxyl groups and a molecular weight of between 790 and 1100 are used for dyeing leather. A trichromatic dye mixture comprising at least one yellow dye of the formula (1), at least one red dye of the formula (2) and at least one blue dye of the formula (3) according to claim 2 is preferably used. Leather can be dyed in brilliant shades using these dye mixtures.
摘要翻译：包含至少两种不同颜色的无金属染料的染料混合物用于染色皮革，每种染料在每种情况下具有两个磺基或羧基，分子量为790和1100之间。优选使用包含至少一种式（1）的黄色染料，至少一种式（2）的红色染料和至少一种根据权利要求2的式（3）的蓝色染料的三色染料混合物。可以使用这些染料混合物将皮革染成明亮的色调。

7. 发明授权

US5204453A Process for the preparation of 1:2 metal complex azo compounds by carrying out diazotization and coupling in the presence of a metal donor 失效
标题翻译：通过在金属给体的存在下进行重氮化和偶联来制备1：2金属络合物偶氮化合物的方法
公开(公告)号：US5204453A
公开(公告)日：1993-04-20
申请号：US815839
申请日：1991-12-30
申请人： Bernard Chambon , Horst H. Jager , Rudiger Oxenius , Alois Puntener
发明人： Bernard Chambon , Horst H. Jager , Rudiger Oxenius , Alois Puntener
IPC分类号： C09B45/01
CPC分类号： C09B45/01
摘要： The invention relates to a process for the preparation of 1:2 chromium, 1:2 cobalt, 1:2 nickel or 1:2 iron complex azo dyes diazotisation, coupling and metallizing, without isolation of the coupling product, which process comprises diazotizing at least one amine of the benzene or naphthalene series in aqueous solution and coupling the diazonium compound so obtained to at least one coupling component of the benzene or naphthalene series or of the heterocyclic series, such that the azo dye obtained as intermediate contains groups suitable for metal complex formation, and carrying out the diazotization or coupling in the presence of a chromium, cobalt, nickel or iron donor.The dyes obtained by the process of the invention are suitable for dyeing in particular wool or synthetic textile polyamide fibre materials as well as leather, and for use as wood mordant dyes.
摘要翻译：本发明涉及一种制备1：2铬，1：2钴，1：2镍或1：2铁络合物偶氮染料重氮化，偶联和金属化，不分离偶合产物的方法，该方法包括在将苯或萘系中的至少一种胺在水溶液中偶联，所得到的重氮化合物与苯或萘系列或杂环系列的至少一个偶联组分偶合，使得作为中间体获得的偶氮染料含有适合金属的基团复合物形成，并在铬，钴，镍或铁给体的存在下进行重氮化或偶联。通过本发明方法获得的染料适用于特别是羊毛或合成纺织品聚酰胺纤维材料以及皮革的染色，并且用作木材媒染染料。

8. 发明授权

US4874849A Asymmetric 1:2-chromium complex dyes containing two azo dyes, one containing an acetoacetanilide coupling component 失效
标题翻译：含有两种偶氮染料的不对称1：2-铬络合物染料，一种含有乙酰乙酰苯胺偶联组分
公开(公告)号：US4874849A
公开(公告)日：1989-10-17
申请号：US944621
申请日：1986-12-19
申请人： Gerhard Back , Fabic Beffa , Ulrich Schlesinger , Alois Puntener
发明人： Gerhard Back , Fabic Beffa , Ulrich Schlesinger , Alois Puntener
IPC分类号： C09B45/26 , D06P1/10 , D06P3/32
CPC分类号： C09B45/26 , D06P1/10 , D06P3/322
摘要： Dyes suitable for dyeing wool, polyamide and leather in orange, brown or olive-brown shades are disclosed, the dyes having the formula ##STR1## wherein A and D are each independently of the other a benzene or napththalene radical of a diazo component, which component carries the hydroxyl or carboxyl group in the ortho-position to the azo group;B is the radical of a coupling component which carries the group X adjacent to the azo group;X is oxygen or a radical of the formula --R--, in which R is hydrogen or C.sub.1 -C.sub.4 alkyl;Y is a radical of the formula ##STR2## in which formulae R.sup.1 and R.sup.5 are each independently of the other hydrogen or sulfo, R.sup.4 is hydrogen or nitro, R.sup.6 is hydrogen, methyl, methoxy or chlorine and R.sup.2 and R.sup.3 are each independently of the other hydrogen, halogen, nitro or sulfo;Ar.sup.1 is a benzene or napththalene radical which is unsubstituted or substituted by halogen, nitro, sulfo, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy;m is 0 or 1;n is an integer from 1 to 7; andKa.sup..sym. is a cation.
摘要翻译：公开了适用于以橙色，棕色或橄榄棕色色调染色羊毛，聚酰胺和皮革的染料，具有式“IMAGE”的染料，其中A和D各自独立地为重氮组分的苯或萘基，其中成分在偶氮基的邻位含有羟基或羧基; B是携带邻近偶氮基团的基团X的偶合组分的基团; X是氧或式-R-的基团，其中R是氢或C 1 -C 4烷基; Y是式中的基团，其中R 1和R 5各自独立地为氢或磺基，R 4是氢或硝基，R 6是氢，甲基，甲氧基或氯，R2和R3各自独立地为氢，卤素，硝基或磺基; Ar1是未被取代或被卤素，硝基，磺基，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代的苯或萘基; m为0或1; n为1〜7的整数; 而Ka（+）是阳离子。

9. 发明授权

US4443370A Chrome-complex dyes 失效
标题翻译：铬复合染料
公开(公告)号：US4443370A
公开(公告)日：1984-04-17
申请号：US267311
申请日：1981-05-28
申请人： Alois Puntener
发明人： Alois Puntener
IPC分类号： C09B45/14 , C09B55/00 , C09B56/02 , C09B45/00
CPC分类号： C09B55/001 , Y10S8/917
摘要： Chrome-complex dyes of the formula (I) ##STR1## wherein the phenyl groups A and B independently of one another are each unsubstituted or are mono- or disubstituted by chlorine, methyl, ethyl, methoxy or ethoxy, and wherein Me.sup..sym. is a cation.The dyes are suitable for dyeing nitrogen-containing materials, particularly for dyeing wool in orange shades.
摘要翻译：其中苯基A和B彼此独立的式（I）的铬络合物染料各自是未取代的或被氯，甲基，乙基，甲氧基或乙氧基单 - 或二取代，并且其中Me （+）是阳离子。该染料适用于对含氮材料进行染色，特别适用于以橙色染色染色羊毛。

10. 发明授权

US4315854A Chromium and cobalt complex amino hydroxy azomethine dyes 失效
标题翻译：铬和钴配合物氨基羟基偶氮甲碱染料
公开(公告)号：US4315854A
公开(公告)日：1982-02-16
申请号：US132964
申请日：1980-03-24
申请人： Alois Puntener , Fabio Beffa
发明人： Alois Puntener , Fabio Beffa
IPC分类号： C09B45/00 , C09B55/00 , C09B56/02 , C09B45/16 , C09B45/20 , C09B45/26 , C09B45/30
CPC分类号： C09B56/02 , C09B45/00 , C09B55/00
摘要： 1:2 Metal complex dyes of azomethines of the formula ##STR1## wherein R is hydrogen, unsubstituted or substituted alkyl, aralkyl, aryl, alkylsulfonyl or arylsulfonyl, A is the radical of an aliphatic 1,2- or 1,3-diamine or of a carbocyclic or heterocyclic 1,2-diamine, B is the radical of an aromatic o-hydroxyaldehyde, Ar.sub.1 is an aromatic radical, m is 1 or 2, and Ar.sub.2 is an aromatic-carbocyclic or heterocyclic radical. These dyes are suitable for dyeing and printing polyamide materials. The dyes are distinguished by their excellent fastness properties, especially good lightfastness. They have good covering power; produce level dyeings; and have good fastness to washing, water, perspiration, alkali, acid, diffusion and rubbing. Strong yellow, yellowish brown, reddish brown, dark brown or olive brown shades are obtained.
摘要翻译： 1：2式Ia的偶氮甲碱金属络合物染料其中R是氢，未取代或取代的烷基，芳烷基，芳基，烷基磺酰基或芳基磺酰基，A是脂族1,2-或1,3-二胺或的碳环或杂环的1,2-二胺，B是芳族O-羟基醛的基团，Ar 1是芳基，m是1或2，Ar 2是芳族 - 碳环或杂环基。这些染料适用于染色和印花聚酰胺材料。染料的优异的耐牢度特性，特别是耐光性好。他们有好的覆盖力; 生产水平染色; 耐洗，水，汗，碱，酸，扩散和摩擦牢度好。强黄，黄棕色，红棕色，深棕色或橄榄棕色。

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