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    • 1. 发明授权
    • 1:2 chromium or cobalt complex axo dyes containing at least one
2-aryl-4-amino-6-hydroxypyrimidine radical
    • 1:2含有至少一个2-芳基-4-氨基-6-羟基嘧啶基的铬或钴络合物轴染料
    • US4962191A
    • 1990-10-09
    • US399202
    • 1989-08-28
    • Alois PuntenerKurt Burdeska
    • Alois PuntenerKurt Burdeska
    • C07D239/47C07D239/48C07D405/04C09B45/14D06P1/10D06P3/24D06P3/32D06P3/60D06P3/79
    • D06P1/10C09B45/14
    • Dyes suitable for dyeing a wide range of textile and non-textile materials, in particular for dyeing leather and pelts, having, in the form of the free acid, the formula ##STR1## wherein D.sub.1 and D.sub.2 are each independently of the other the radical of a diazo component of the benzene or naphthalene series which carries a hydroxy or carboxy in ortho-position to the azo group and which may or may not be further substituted,K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series which carries the group X in ortho-position to the azo group and which may or may not be further substituted,Me is chromium or cobalt,Q is an unsubstituted or substituted phenyl or naphthyl radical or an unsubstituted or substituted aromatic-heterocyclic radical,R.sub.1 is unsubstituted or substituted C.sub.1 -C.sub.6 alkyl or unsubstituted or substituted phenyl,R.sub.2 is hydrogen or independently has the meaning of R.sub.1, X is --O-- or --NR.sub.3,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, andp and q are each independently of the other 0 or 1.
    • 适用于染色各种纺织和非纺织材料的染料,特别是染色皮革和毛皮,具有游离酸形式的式(1),其中D1和D2各自独立地为 另一个苯或萘系列的重氮组分的基团,其在偶氮基的邻位带有羟基或羧基,并且可以被进一步取代,K是苯或萘的偶联组分的基团 系列或杂环系列,其携带基团X在偶氮基上邻位并且可以被进一步取代,Me是铬或钴,Q是未取代或取代的苯基或萘基或未取代或取代的 芳基 - 杂环基,R 1是未取代的或取代的C 1 -C 6烷基或未取代或取代的苯基,R 2是氢或独立地具有R 1,X是-O-或-NR 3,R 3是氢或C 1 -C 4烷基,p和 q 各自独立于0或1。
    • 4. 发明授权
    • Phenylpyrimidines as antidotes for protecting cultivated plants against
phytotoxic damage caused by herbicides
    • US4493726A
    • 1985-01-15
    • US486651
    • 1983-04-20
    • Kurt BurdeskaGuglielmo Kabas, deceasedHans-Georg BrunnerWerner Fory
    • Kurt BurdeskaGuglielmo Kabas, deceasedHans-Georg BrunnerWerner Fory
    • A01N57/10A01N25/02A01N25/32A01N37/22A01N43/54A01P13/00C07D239/30C07D239/42C07D239/46C07D239/47C07D239/52C07D405/10C07F9/6512A01N43/48C07D239/02
    • C07D239/30A01N25/32C07D239/42C07D239/47C07D239/52C07F9/65122
    • Phenylpyrimidines of the formula I as defined below are suitable as antidotes for protecting cultivated plants from phytotoxic effects caused by herbicides. These antidotes, either together with the herbicides or also by themselves, are applied to the plants or incorporated in the soil in which the plants grow, or they are used to treat the seeds of the plants. Suitable herbicides are those belonging to the class of the haloacetanilides, haloacetamides, thiocarbamates, carbamates, nitroanilides, triazines, phenylureas, haloacetic acids, phenoxy- and pyridyloxyphenoxyalkanecarboxylic acid derivatives, benzoic acid derivatives etc. The phenylpyrimidines have the formula I ##STR1## wherein n is an integer from 1 to 5,R is hydrogen, halogen, cyano, nitro or hydroxyl, a C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkylthio group, which is unsubstituted or mono- or polysubstituted by halogen, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.12 alkoxyalkyl, C.sub.1 -C.sub.6 alkylcarbonyl, C.sub.1 -C.sub.6 alkylcarbonyloxy, C.sub.1 -C.sub.6 alkoxycarbonyl, C.sub.2 -C.sub.6 alkenylcarbonyl or C.sub.2 -C.sub.6 alkynylcarbonyl, di(C.sub.1 -C.sub.6)alkylamino, C.sub.1 -C.sub.6 alkylenedioxy, phosphonyl or C.sub.1 -C.sub.6 alkylphosphonyl; or R is a C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkenyloxy group or the formyl or carboxyl group; or is a carbonyl or carbonyloxy group which is substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl, amino, di(C.sub.1 -C.sub.6)alkylamino, or by a 5- to 6-membered saturated heterocyclic ring which is bound through the nitrogen atom; or is an amino group which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkylcarbonyl; or it is an ureido radical which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy or it is the sulfonyl, a C.sub.1 -C.sub.6 alkylsulfonyl, the sulfamoyl, a C.sub.1 -C.sub.6 alkylsulfamoyl or a C.sub.1 -C.sub.6 alkylcarbonylsulfamoylrest,R.sub.1 and R.sub.3 each independently of the other is halogen, cyano, hydroxyl, sulfhydryl, a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 ethylthio radical, which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.6 alkoxy; a C.sub.2 C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl radical, a C.sub.3 -C.sub.6 cycloalkyl radical, an amino, C.sub.1 -C.sub.6 alkylamino or di(C.sub.1 -C.sub.6 alkyl) amino, group, a 5- to 6-membered saturated heterocyclic ring, which is bound through the nitrogen atom, a phenyl or phenoxyrest andR.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl or phenyl.
    • 6. 发明授权
    • 4,6-diaminopyrimidine or the like intermediates for the preparation of
fiber-reactive dyes
    • 4,6-二氨基嘧啶等制备纤维活性染料的中间体
    • US4975530A
    • 1990-12-04
    • US441132
    • 1989-11-22
    • Athanassios TzikasKurt Burdeska
    • Athanassios TzikasKurt Burdeska
    • C09B62/245C09B62/028C09B62/085C09B62/44C09B62/51D06P1/38D06P1/382D06P1/384
    • C09B62/4401C09B62/028C09B62/51
    • Intermediates useful for the preparation of fiber-reactive dyes having the formula ##STR1## in which Q is phenyl unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, cyano, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylsulfonyl, sulfo or trihalomethyl; 1- or 2-naphthyl; or unsubstituted or C.sub.1 -C.sub.4 alkyl, nitro, cyano, C.sub.1 -C.sub.4 alkoxycarbonyl or C.sub.1 -C.sub.4 alkylthio substituted furanyl, thienyl, thiazolyl, oxazolyl, isothiazolyl, benzothiazolyl, benzoisothiazolyl, pyrazolyl, imidazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl or 1,3,5-triazinyl, and A.sub.1 and A.sub.2 independently of one another are a radical of the formula ##STR2## in which R.sub.1 and R.sub.2 independently of one another are hydrogen; C.sub.1 -C.sub.4 alkyl unsubstituted or substituted by hydroxyl, sulfo, sulfato, carboxyl, cyano, halogen, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkanoyloxy or carbamoyl and uninterrupted or with the exception of methyl interrupted by --O-- or --NR.sub.4 -- wherein R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl, or naphthyl or phenyl each of which is unsubstituted or substituted by sulfo, carboxyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen or a group --N.dbd.N--K wherein K is a coupling component benzene, naphthalene or heterocyclic radical; or R.sub.1 and R.sub.2 together with the N atom form a piperidinyl, piperazinyl or pyrrolidinyl radical, with the proviso that at least one of the radicals A.sub.1 or A.sub.2 is further substituted by a fiber-reactive radical.