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    • 3. 发明授权
    • Multistage graft copolymer and its use for the preparation of
transparent PVC molding materials
    • 多层共聚物及其制备透明PVC模塑材料的用途
    • US5247025A
    • 1993-09-21
    • US844316
    • 1992-03-02
    • Hans-Helmut GoertzGuenter HatzmannWerner Oschmann
    • Hans-Helmut GoertzGuenter HatzmannWerner Oschmann
    • C08F2/22C08F285/00C08L51/00
    • C08L51/00C08F285/00Y10S525/902
    • Graft copolymers obtained byA) emulsion polymerization of from 5 to 35% by weight of a monomer mixture ofa.sub.1) 60-80% by weight of one or more vinylaromatic monomers,a.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,B) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage A), of 20-45% by weight of a monomer mixture ofb.sub.1) 50-75% by weight of one or more vinylaromatic monomers,b.sub.2) 25-50% by weight of one or more C.sub.1 -C.sub.18 -alkyl acrylates,C) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage B), of 5-35% by weight of a monomer mixture ofc.sub.1) 60-80% by weight of one or more vinylaromatic monomers,c.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,D) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage C), of 15-45% by weight of a monomer mixture ofd.sub.1) 80-99.9% by weight of one or more C.sub.1 -C.sub.18 -alkyl acrylates,d.sub.2) 0.1-0% by weight of one or more di- or polyethylenically unsaturated monomers.The graft copolymers can be used for the preparation of transparent PVC molding materials.
    • 通过A)乳液聚合获得的接枝共聚物,其通过5重量%至35重量%的a1)60-80重量%的一种或多种乙烯基芳族单体的混合物,a2)20-40重量%的一种或多种烯属不饱和单体 腈)B)在步骤A)中得到的乳液聚合物存在下,随后的乳液聚合为20-45重量%的b1)50-75重量%的一种或多种乙烯基芳族单体的单体混合物,b2) 25-50重量%的一种或多种丙烯酸C 1 -C 18烷基酯,C)在步骤B)中获得的乳液聚合物存在下,随后的乳液聚合为5-35重量%的单体混合物c1) 60-80重量%的一种或多种乙烯基芳族单体,c2)20-40重量%的一种或多种烯键式不饱和腈,D)在步骤C)中获得的乳液聚合物存在下的随后乳液聚合为15 -45重量%的d1)80-99.9重量%的一种或多种C1-C18烷基丙烯酸酯的单体混合物,d2)0.1-0% 一种或多种二烯或多烯属不饱和单体的重量。 接枝共聚物可用于制备透明PVC成型材料。