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    • 5. 发明申请
    • Phenylsulfonyl ureas, process for their preparation and their use as herbicides and plant growth regulators
    • US20060014644A1
    • 2006-01-19
    • US11224153
    • 2005-09-12
    • Hansjorg DietrichChristian WaldraffLothar WillmsHermann BieringerChristopher RosingerFelix ThurwachterThomas Auler
    • Hansjorg DietrichChristian WaldraffLothar WillmsHermann BieringerChristopher RosingerFelix ThurwachterThomas Auler
    • A01N47/36C07D403/02C07D239/46
    • C07D521/00A01N47/36C07C311/16C07C311/39C07D207/32C07D239/42C07D239/47C07D239/52C07D251/42C07D251/46C07D295/155C07D403/12
    • Compounds of the formula (I) or salts thereof in which R1 is a hydrogen atom, a hydrocarbon radical or a heterocyclyl radical, where each of the two last-mentioned radicals is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, R2 is a group of the formula R0-Q0- in which R0 is a hydrogen atom, a hydrocarbon radical or a heterocyclyl radical, where each of the two last-mentioned radicals is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, and Q is a direct bond or a divalent group of the formula —O— or —N(R#)—, where R# is a hydrogen atom, an acyl radical or a hydrocarbon radical and where the last-mentioned radical is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, R3 is a hydrogen atom, a hydrocarbon radical or a heterocyclyl radical, where each of the two last-mentioned radicals is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, R4 independently of one another, are halogen, OH, SH, a nitrogen-containing radical which does not contain any carbon or a carbon-containing radical, is 0, 1, 2 or 3, preferably 0 or 1, R5 is a hydrogen atom or a C1-C10-hydrocarbon radical which is unsubstituted or substituted, such as (C1-C4)alkyl, preferably H or CH3), Q is O, S or NR*, R* is a hydrogen atom or a C1-C10-hydrocarbon radical which is unsubstituted or substituted such as (C1-C4)alkyl, (C3-C4)alkenyl or (C3-C4)alkynyl, where each of the three last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)alkoxy and (C1-C4)alkylthio, W is an oxygen or sulfur atom, X,Y independently of one another are a hydrogen atom, halogen, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)alkylthio, where each of the 3 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)alkoxy and (C1-C4)alkylthio, or are mono- or di[(C1-C4)alkyl]amino, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C6)alkenyloxy or (C3-C6)alkynyloxy, and V, Z independently of one another are CH or N, are suitable for use as herbicides or plant growth regulators, for example for controlling harmful plants in crop plants, including transgenic crop plants. They can be prepared by the processes according to claim 6 via intermediates, some of which are novel (cf. compounds (II*) and (X*) and (VIII) as claimed in claims 12, 14 and 16).
    • 9. 发明授权
    • Carbamoylphenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators
    • 氨基甲酰基苯基磺酰脲,其制备方法及其作为除草剂和植物生长调节剂的用途
    • US06228808B1
    • 2001-05-08
    • US09182763
    • 1998-10-30
    • Heinz KehneLothar WillmsChristian WaldraffHansjörg DietrichHermann BieringerChristopher RosingerThomas Auler
    • Heinz KehneLothar WillmsChristian WaldraffHansjörg DietrichHermann BieringerChristopher RosingerThomas Auler
    • A01N4354
    • C07D275/06C07C311/16C07D521/00
    • Compounds of the formula (I) or salts thereof in which R1, R3=H, (subst.) hydrocarbon radical (HC) or (subst.) heterocyclyl which, including substituents, have 1-30 carbon atoms, R2=R0—Q0—, in which R0=H, (subst.) HC or (subst.) heterocyclyl radical, in each case having 1-30 carbon atoms including substituents, and Q0=a direct bond or —O—, —SO2-, —NH—, —N[(C1-C6)alkyl]-, —CO—, —CO—NH— or —O—CO—NH—; R4=H, halogen, NO2, CN, (C1-C4)alkyl, (C1-C4)alkoxy, [(C1-C4)alkyl]carbonyl or [(C1-C4)alkoxy]carbonyl, where each of the last four radicals may be halogenated; R5=H or (C1-C4)alkyl; Q=O or NR*; R*=H. (C1-C4)alkyl, (C3-C4)alkenyl or (C3-C4)alkynyl, where each of the last three radicals may be substituted by halogen, (C1-C4)alkoxy and/or (C1-C4)alkylthio, W=O or S; X,Y=H, halogen, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)alkylthio, where each of the last three radicals may be substituted by halogen, (C1-C4)alkoxy and/or (C1-C4)alkylthio, or mono- or di[(C1-C4)alkyl]amino, (C3-C4)cycloalkyl, (C2-C5)alkenyl, (C2-C5)alkynyl, (C2-C5)alkenyloxy or (C2-C5)alkynyloxy, Z=CH or N, are suitable as herbicides or plant growth regulators, for example for controlling harmful plants in crop plants, including transgenic crop plants. They can be prepared by processes according to claim 6, via intermediates, some of which are novel.
    • 式(I)化合物或其盐,其中R 1,R 3 = H,(取代)烃基(HC)或(取代)杂环基,其包括取代基,具有1-30个碳原子,R 2 = R 0 -Q 0-, 其中R 0 = H,(低级)HC或(取代)杂环基,在每种情况下具有包含取代基的1-30个碳原子,Q 0 =直接键或-O-,-SO 2 - , - NH-, -N [(C 1 -C 6)烷基] - , - CO - , - CO-NH-或-O-CO-NH-; R4 = H,卤素,NO2,CN,(C1-C4)烷基,(C1-C4)烷氧基,[(C1-C4)烷基]羰基或[(C1-C4)烷氧基]羰基, 自由基可以被卤化; R5 = H或(C1-C4)烷基; Q = O或NR *; R * = H。 (C 1 -C 4)烷基,(C 3 -C 4)烯基或(C 3 -C 4)炔基,其中最后三个基团中的每一个可以被卤素,(C 1 -C 4)烷氧基和/或(C 1 -C 4)烷硫基取代, W = O或S; X,Y = H,卤素,(C1-C4)烷基,(C1-C4)烷氧基,(C1-C4)烷硫基,其中最后三个基团中的每一个可以被卤素,(C 1 -C 4)烷氧基和/ 或(C 1 -C 4)烷硫基或单或二[(C 1 -C 4)烷基]氨基,(C 3 -C 4)环烷基,(C 2 -C 5)烯基,(C 2 -C 5)炔基,(C 2 -C 5) 或(C 2 -C 5)炔氧基Z = CH或N适合作为除草剂或植物生长调节剂,例如用于控制作物植物(包括转基因作物植物)中的有害植物。 它们可以通过根据权利要求6的方法通过中间体制备,其中一些是新颖的。