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1. 发明申请

WO2010096284A1 POLYETHYLENE FILMS HAVING IMPROVED BARRIER PROPERTIES 审中-公开
标题翻译：具有改进障碍物性能的聚乙烯薄膜
公开(公告)号：WO2010096284A1
公开(公告)日：2010-08-26
申请号：PCT/US2010/023264
申请日：2010-02-05
申请人： FINA TECHNOLOGY, INC. , GRAY, Steven , KNOEPPEL, David , COFFY, Tim , VIZZINI, Kayo , CHEVILLARD, Cyril , HOESING, Shannon
发明人： GRAY, Steven , KNOEPPEL, David , COFFY, Tim , VIZZINI, Kayo , CHEVILLARD, Cyril , HOESING, Shannon
IPC分类号： C08J3/22
CPC分类号： C08F110/02 , C08J5/18 , C08J2323/06 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/26 , C08F4/654
摘要： Blown films and processes of forming the same are described herein. The blown films generally include high density polyethylene exhibiting a molecular weight distribution of from about 1.5 to about 8.0 and a density of from 0.94 g/cc to less than 0.96 g/cc.
摘要翻译：吹塑膜及其形成方法在本文中描述。吹塑膜通常包括显示分子量分布为约1.5至约8.0且密度为0.94g / cc至小于0.96g / cc的高密度聚乙烯。

2. 发明申请

WO2007149911A1 FORMATION OF ZIEGLER-NATTA CATALYST 审中-公开
标题翻译： ZIEGLER-NATTA催化剂的形成
公开(公告)号：WO2007149911A1
公开(公告)日：2007-12-27
申请号：PCT/US2007/071653
申请日：2007-06-20
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , KNOEPPEL, David , GRAY, Steven , RAUSCHER, David , COFFY, Tim , ENRIQUEZ, Henry
发明人： VIZZINI, Kayo , KNOEPPEL, David , GRAY, Steven , RAUSCHER, David , COFFY, Tim , ENRIQUEZ, Henry
IPC分类号： B01J21/00
CPC分类号： B01J31/122 , C08F10/02 , C08F110/02 , C08F4/6557 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24 , C08F2500/19
摘要： Methods of forming polyolefÊns and catalysts are described herein. Such methods generally include forming Ziegler-Natta catalyst compounds in the absence of one or more blended compounds typically used to form such catalyst.
摘要翻译：形成聚烯烃和催化剂的方法在本文中描述。这样的方法通常包括在不存在通常用于形成这种催化剂的一种或多种共混化合物的情况下形成齐格勒 - 纳塔催化剂化合物。

3. 发明申请

WO2005032714A1 ZIEGLER-NATTA CATALYST FOR POLYOLEFINS 审中-公开
标题翻译： ZIEGLER-NATTA聚合物催化剂
公开(公告)号：WO2005032714A1
公开(公告)日：2005-04-14
申请号：PCT/US2004/029019
申请日：2004-09-07
申请人： FINA TECHNOLOGY, INC. , KNOEPPEL, David, W. , COFFY, Tim, J. , ENRIQUEZ, Henry , GRAY, Steven , VIZZINI, Kayo
发明人： KNOEPPEL, David, W. , COFFY, Tim, J. , ENRIQUEZ, Henry , GRAY, Steven , VIZZINI, Kayo
IPC分类号： B01J31/00
CPC分类号： B01J31/0212 , B01J31/32 , B01J31/38 , B01J2231/122 , C08F10/00 , C08F110/02 , C08F4/6557 , C08F4/651 , C08F4/6546 , C08F2500/12 , C08F2500/02 , C08F2500/23 , C08F2500/07 , C08F2500/18 , C08F2500/04 , C08F2500/24
摘要： A Ziegler-Natta type catalyst component can be produced by a process comprising contacting a magnesium dialkoxide compound with a halogenating agent to form a reaction product A, and contacting reaction product A with a first, second and third halogenating/titanating agents. Catalyst components, catalysts, catalyst systems, polyolefin, products made therewith, and methods of forming each are disclosed. The reaction products can be washed with a hydrocarbon solvent to reduce titanium species [Ti] content to less than about 100 mmol/L.
摘要翻译：齐格勒 - 纳塔型催化剂组分可以通过包括使二烷氧基镁化合物与卤化剂接触以形成反应产物A并使反应产物A与第一，第二和第三卤化/钛化剂接触的方法制备。公开了催化剂组分，催化剂，催化剂体系，聚烯烃，由其制备的产品，以及各自形成的方法。可以用烃溶剂洗涤反应产物以将钛物质[Ti]含量降低至小于约100mmol / L。

4. 发明申请

WO2009012174A1 PROCESS FOR CONTROLLING MORPHOLOGY OF ZIEGLER-NATTA CATALYSTS 审中-公开
标题翻译：控制ZIEGLER-NATTA催化剂形态的方法
公开(公告)号：WO2009012174A1
公开(公告)日：2009-01-22
申请号：PCT/US2008/069863
申请日：2008-07-11
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , ENRIQUEZ, Henry , GRAY, Steven , COFFY, Tim
发明人： VIZZINI, Kayo , ENRIQUEZ, Henry , GRAY, Steven , COFFY, Tim
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution It comprises alteπng the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor, or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法，其包括通过控制可溶性含镁催化剂前体的浓度，使催化剂组分从包含可溶性镁的催化剂前体的催化剂合成溶液中沉淀出来其中催化剂组分的平均粒度增加，并且随着可溶性含镁催化剂前体或沉淀剂的浓度降低，粒度分布增加，其中催化剂组分的平均粒度增加，并且粒度分布随着沉淀剂浓度的增加而增加。新型催化剂组分可用于制备聚合物及其最终用途制品，具有所需的性能

5. 发明申请

WO2011085350A8 ZIEGLER-NATTA CATALYST SYSTEMS AND POLYMERS FORMED THEREFROM 审中-公开
公开(公告)号：WO2011085350A8
公开(公告)日：2011-07-14
申请号：PCT/US2011/020780
申请日：2011-01-11
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , KNOEPPEL, David , ZHANG, Lei
发明人： VIZZINI, Kayo , KNOEPPEL, David , ZHANG, Lei
IPC分类号： B01J21/10
摘要： Processes of forming catalyst systems, catalyst systems and polymers formed therefrom are described herein. The processes generally include providing a first compound including a magnesium dialkoxide, contacting the first compound with a second compound to form a solution of reaction product "A". wherein the second compound is generally represented by the formula: Ti(OR 1 J 4 ; wherein R 1 is selected from C 1 to C 10 linear to branched alkyls, contacting the solution of reaction product "A" with a first metal halide to form a solid reaction product "B", contacting solid reaction product "B" with a second metal halide to form reaction product "C"' and contacting reaction product "C" with reducing agent to form a catalyst component.

6. 发明申请

WO2009100287A1 ZIEGLER-NATTA CATALYST 审中-公开
标题翻译： ZIEGLER-NATTA催化剂
公开(公告)号：WO2009100287A1
公开(公告)日：2009-08-13
申请号：PCT/US2009/033317
申请日：2009-02-06
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , KNOEPPEL, David
发明人： VIZZINI, Kayo , KNOEPPEL, David
IPC分类号： B01J37/00
CPC分类号： C08F10/02 , C08F110/02 , C08F4/6546 , C08F4/6557 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/19 , C08F2500/07 , C08F2500/04 , C08F4/6548
摘要： The present invention relates generally to catalysts, to methods of making catalysts, to methods of using catalysts, to methods of polymerizing, and to polymers made with such catalysts. More particularly, the present invention relates to polyolefin catalysts and to Ziegler-Natta catalysts, to methods of making such catalysts, to methods of using such catalysts, to polyolefin polymerization, and to polyolefins.
摘要翻译：本发明一般涉及催化剂，制备催化剂的方法，使用催化剂的方法，聚合方法以及用这种催化剂制备的聚合物。更具体地说，本发明涉及聚烯烃催化剂和齐格勒 - 纳塔催化剂，制备这种催化剂的方法，使用这种催化剂的方法，聚烯烃聚合和聚烯烃。

7. 发明申请

WO2008024897A2 PROMOTER SYSTEM FOR POLYMERIZATION PROCESSES AND POLYMERS FORMED THEREFROM 审中-公开
标题翻译：用于聚合过程的促进剂体系和由其形成的聚合物
公开(公告)号：WO2008024897A2
公开(公告)日：2008-02-28
申请号：PCT/US2007/076618
申请日：2007-08-23
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , GRAY, Steven
发明人： VIZZINI, Kayo , GRAY, Steven
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6493 , C08F4/6557
摘要： Polymerization processes and polymers formed therefrom are described herein. Such processes generally include providing a catalyst system, introducing the catalyst system to a reaction zone, introducing 1-chlorobutane to the reaction zone, introducing an olefin monomer to the reaction zone, contacting the olefin monomer with the catalyst system in the presence of the 1-chlorobutane to form a polyolefin and withdrawing the polyolefin from the reaction zone. The catalyst system is generally formed from a process including contacting a magnesium dialkoxide compound with a first agent to form a first compound, contacting the first compound with a plurality of halogenating/titanating agents to form a reaction product and contacting the reaction product with an activating agent to form the catalyst system.
摘要翻译：本文描述了聚合方法和由其形成的聚合物。此类方法通常包括提供催化剂体系，将催化剂体系引入反应区，将1-氯丁烷引入反应区，将烯烃单体引入反应区，使烯烃单体与催化剂体系在1 生成聚烯烃并从反应区中排出聚烯烃。催化剂体系通常由以下方法形成，该方法包括使二烷醇镁化合物与第一试剂接触以形成第一化合物，使第一化合物与多种卤化/钛化剂接触以形成反应产物并使反应产物与活化剂试剂形成催化剂体系。

8. 发明申请

WO2009085677A1 ZIEGLER-NATTA CATALYST FOR PARTICLE SIZE CONTROL 审中-公开
标题翻译： ZIEGLER-NATTA催化剂用于颗粒尺寸控制
公开(公告)号：WO2009085677A1
公开(公告)日：2009-07-09
申请号：PCT/US2008/086752
申请日：2008-12-15
申请人： FINA TECHNOLOGY, INC. , ENRIQUEZ, Henry , VIZZINI, Kayo , GRAY, Steven
发明人： ENRIQUEZ, Henry , VIZZINI, Kayo , GRAY, Steven
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6557 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/19 , C08F2500/07 , C08F2500/23 , C08F2500/04
摘要： Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product "A1", contacting the solution of reaction product "A1" with a reducing agent to form a reduced reaction product "A2", contacting reduced reaction product "A2" with a second agent to form a solid reaction product "A, contacting solid reaction product "A " with a metal halide to form reaction product "B" and contacting reaction product "B" with an organoaluminum compound to form a catalyst component.
摘要翻译：本文描述了催化剂组分，形成催化剂组合物的方法，利用催化剂组合物的聚合方法和由此形成的聚合物。所述方法通常包括提供二烷氧基镁化合物，使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液，使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”，将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A”，使固体反应产物“A”与金属卤化物接触以形成反应产物“B”并使反应产物“B”与有机铝化合物以形成催化剂组分。

9. 发明申请

WO2009097398A1 POLYETHYLENE MATERIALS PREPARED USING MIXED ZIEGLER-NATTA CATALYST SYSTEMS 审中-公开
标题翻译：使用混合的ZIEGLER-NATTA催化剂体系制备的聚乙烯材料
公开(公告)号：WO2009097398A1
公开(公告)日：2009-08-06
申请号：PCT/US2009/032386
申请日：2009-01-29
申请人： FINA TECHNOLOGY, INC. , BARRE, Vincent , VIZZINI, Kayo , GRAY, Steven, D.
发明人： BARRE, Vincent , VIZZINI, Kayo , GRAY, Steven, D.
IPC分类号： B01J31/00
CPC分类号： C08F110/02 , C08F10/00 , C08F2410/04 , Y02P20/52 , Y10T428/139 , C08F2/00 , C08F4/6546 , C08F4/025 , C08F4/022 , C08F4/6557 , C08F2500/18 , C08F2500/12
摘要： A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for the tuning or targeting of properties to fit a specific application, such as a blow molding or vapor barrier film.
摘要翻译：可以使用二氧化硅负载的催化剂和负载氯化镁的催化剂的混合物制备聚乙烯。通过改变两种催化剂的比例，所生产的聚乙烯可能具有变化的体积密度和剪切响应。该方法允许调整或定位特性以适应特定应用，例如吹塑或蒸气阻隔膜。

10. 发明公开

EP2247383A1 POLYETHYLENE MATERIALS PREPARED USING MIXED ZIEGLER-NATTA CATALYST SYSTEMS 审中-公开
标题翻译： - 混合Ziegler-Natta催化剂系统生产的聚乙烯材料
公开(公告)号：EP2247383A1
公开(公告)日：2010-11-10
申请号：EP09706425.7
申请日：2009-01-29
申请人： Fina Technology, Inc.
发明人： BARRE, Vincent , VIZZINI, Kayo , GRAY, Steven, D.
IPC分类号： B01J31/00
CPC分类号： C08F110/02 , C08F10/00 , C08F2410/04 , Y02P20/52 , Y10T428/139 , C08F2/00 , C08F4/6546 , C08F4/025 , C08F4/022 , C08F4/6557 , C08F2500/18 , C08F2500/12
摘要： A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for the tuning or targeting of properties to fit a specific application, such as a blow molding or vapor barrier film.

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