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1. 发明申请

WO2010096284A1 POLYETHYLENE FILMS HAVING IMPROVED BARRIER PROPERTIES 审中-公开
标题翻译：具有改进障碍物性能的聚乙烯薄膜
公开(公告)号：WO2010096284A1
公开(公告)日：2010-08-26
申请号：PCT/US2010/023264
申请日：2010-02-05
申请人： FINA TECHNOLOGY, INC. , GRAY, Steven , KNOEPPEL, David , COFFY, Tim , VIZZINI, Kayo , CHEVILLARD, Cyril , HOESING, Shannon
发明人： GRAY, Steven , KNOEPPEL, David , COFFY, Tim , VIZZINI, Kayo , CHEVILLARD, Cyril , HOESING, Shannon
IPC分类号： C08J3/22
CPC分类号： C08F110/02 , C08J5/18 , C08J2323/06 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/26 , C08F4/654
摘要： Blown films and processes of forming the same are described herein. The blown films generally include high density polyethylene exhibiting a molecular weight distribution of from about 1.5 to about 8.0 and a density of from 0.94 g/cc to less than 0.96 g/cc.
摘要翻译：吹塑膜及其形成方法在本文中描述。吹塑膜通常包括显示分子量分布为约1.5至约8.0且密度为0.94g / cc至小于0.96g / cc的高密度聚乙烯。

2. 发明申请

WO2007149911A1 FORMATION OF ZIEGLER-NATTA CATALYST 审中-公开
标题翻译： ZIEGLER-NATTA催化剂的形成
公开(公告)号：WO2007149911A1
公开(公告)日：2007-12-27
申请号：PCT/US2007/071653
申请日：2007-06-20
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , KNOEPPEL, David , GRAY, Steven , RAUSCHER, David , COFFY, Tim , ENRIQUEZ, Henry
发明人： VIZZINI, Kayo , KNOEPPEL, David , GRAY, Steven , RAUSCHER, David , COFFY, Tim , ENRIQUEZ, Henry
IPC分类号： B01J21/00
CPC分类号： B01J31/122 , C08F10/02 , C08F110/02 , C08F4/6557 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24 , C08F2500/19
摘要： Methods of forming polyolefÊns and catalysts are described herein. Such methods generally include forming Ziegler-Natta catalyst compounds in the absence of one or more blended compounds typically used to form such catalyst.
摘要翻译：形成聚烯烃和催化剂的方法在本文中描述。这样的方法通常包括在不存在通常用于形成这种催化剂的一种或多种共混化合物的情况下形成齐格勒 - 纳塔催化剂化合物。

3. 发明申请

WO2005032714A1 ZIEGLER-NATTA CATALYST FOR POLYOLEFINS 审中-公开
标题翻译： ZIEGLER-NATTA聚合物催化剂
公开(公告)号：WO2005032714A1
公开(公告)日：2005-04-14
申请号：PCT/US2004/029019
申请日：2004-09-07
申请人： FINA TECHNOLOGY, INC. , KNOEPPEL, David, W. , COFFY, Tim, J. , ENRIQUEZ, Henry , GRAY, Steven , VIZZINI, Kayo
发明人： KNOEPPEL, David, W. , COFFY, Tim, J. , ENRIQUEZ, Henry , GRAY, Steven , VIZZINI, Kayo
IPC分类号： B01J31/00
CPC分类号： B01J31/0212 , B01J31/32 , B01J31/38 , B01J2231/122 , C08F10/00 , C08F110/02 , C08F4/6557 , C08F4/651 , C08F4/6546 , C08F2500/12 , C08F2500/02 , C08F2500/23 , C08F2500/07 , C08F2500/18 , C08F2500/04 , C08F2500/24
摘要： A Ziegler-Natta type catalyst component can be produced by a process comprising contacting a magnesium dialkoxide compound with a halogenating agent to form a reaction product A, and contacting reaction product A with a first, second and third halogenating/titanating agents. Catalyst components, catalysts, catalyst systems, polyolefin, products made therewith, and methods of forming each are disclosed. The reaction products can be washed with a hydrocarbon solvent to reduce titanium species [Ti] content to less than about 100 mmol/L.
摘要翻译：齐格勒 - 纳塔型催化剂组分可以通过包括使二烷氧基镁化合物与卤化剂接触以形成反应产物A并使反应产物A与第一，第二和第三卤化/钛化剂接触的方法制备。公开了催化剂组分，催化剂，催化剂体系，聚烯烃，由其制备的产品，以及各自形成的方法。可以用烃溶剂洗涤反应产物以将钛物质[Ti]含量降低至小于约100mmol / L。

4. 发明申请

WO2009012174A1 PROCESS FOR CONTROLLING MORPHOLOGY OF ZIEGLER-NATTA CATALYSTS 审中-公开
标题翻译：控制ZIEGLER-NATTA催化剂形态的方法
公开(公告)号：WO2009012174A1
公开(公告)日：2009-01-22
申请号：PCT/US2008/069863
申请日：2008-07-11
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , ENRIQUEZ, Henry , GRAY, Steven , COFFY, Tim
发明人： VIZZINI, Kayo , ENRIQUEZ, Henry , GRAY, Steven , COFFY, Tim
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , Y10T428/1345 , Y10T428/139 , C08F4/6546 , C08F4/6541
摘要： Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution It comprises alteπng the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor, or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties
摘要翻译：公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法，其包括通过控制可溶性含镁催化剂前体的浓度，使催化剂组分从包含可溶性镁的催化剂前体的催化剂合成溶液中沉淀出来其中催化剂组分的平均粒度增加，并且随着可溶性含镁催化剂前体或沉淀剂的浓度降低，粒度分布增加，其中催化剂组分的平均粒度增加，并且粒度分布随着沉淀剂浓度的增加而增加。新型催化剂组分可用于制备聚合物及其最终用途制品，具有所需的性能

5. 发明申请

WO2008024897A2 PROMOTER SYSTEM FOR POLYMERIZATION PROCESSES AND POLYMERS FORMED THEREFROM 审中-公开
标题翻译：用于聚合过程的促进剂体系和由其形成的聚合物
公开(公告)号：WO2008024897A2
公开(公告)日：2008-02-28
申请号：PCT/US2007/076618
申请日：2007-08-23
申请人： FINA TECHNOLOGY, INC. , VIZZINI, Kayo , GRAY, Steven
发明人： VIZZINI, Kayo , GRAY, Steven
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6493 , C08F4/6557
摘要： Polymerization processes and polymers formed therefrom are described herein. Such processes generally include providing a catalyst system, introducing the catalyst system to a reaction zone, introducing 1-chlorobutane to the reaction zone, introducing an olefin monomer to the reaction zone, contacting the olefin monomer with the catalyst system in the presence of the 1-chlorobutane to form a polyolefin and withdrawing the polyolefin from the reaction zone. The catalyst system is generally formed from a process including contacting a magnesium dialkoxide compound with a first agent to form a first compound, contacting the first compound with a plurality of halogenating/titanating agents to form a reaction product and contacting the reaction product with an activating agent to form the catalyst system.
摘要翻译：本文描述了聚合方法和由其形成的聚合物。此类方法通常包括提供催化剂体系，将催化剂体系引入反应区，将1-氯丁烷引入反应区，将烯烃单体引入反应区，使烯烃单体与催化剂体系在1 生成聚烯烃并从反应区中排出聚烯烃。催化剂体系通常由以下方法形成，该方法包括使二烷醇镁化合物与第一试剂接触以形成第一化合物，使第一化合物与多种卤化/钛化剂接触以形成反应产物并使反应产物与活化剂试剂形成催化剂体系。

6. 发明申请

WO2009085677A1 ZIEGLER-NATTA CATALYST FOR PARTICLE SIZE CONTROL 审中-公开
标题翻译： ZIEGLER-NATTA催化剂用于颗粒尺寸控制
公开(公告)号：WO2009085677A1
公开(公告)日：2009-07-09
申请号：PCT/US2008/086752
申请日：2008-12-15
申请人： FINA TECHNOLOGY, INC. , ENRIQUEZ, Henry , VIZZINI, Kayo , GRAY, Steven
发明人： ENRIQUEZ, Henry , VIZZINI, Kayo , GRAY, Steven
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6557 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/19 , C08F2500/07 , C08F2500/23 , C08F2500/04
摘要： Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product "A1", contacting the solution of reaction product "A1" with a reducing agent to form a reduced reaction product "A2", contacting reduced reaction product "A2" with a second agent to form a solid reaction product "A, contacting solid reaction product "A " with a metal halide to form reaction product "B" and contacting reaction product "B" with an organoaluminum compound to form a catalyst component.
摘要翻译：本文描述了催化剂组分，形成催化剂组合物的方法，利用催化剂组合物的聚合方法和由此形成的聚合物。所述方法通常包括提供二烷氧基镁化合物，使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液，使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”，将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A”，使固体反应产物“A”与金属卤化物接触以形成反应产物“B”并使反应产物“B”与有机铝化合物以形成催化剂组分。

7. 发明申请

WO2008137413A1 POLYMERIZATION PROCESS PROVIDING POLYETHYLENE OF ENHANCED OPTICAL PROPERTIES 审中-公开
标题翻译：提供增强光学性能的聚乙烯的聚合方法
公开(公告)号：WO2008137413A1
公开(公告)日：2008-11-13
申请号：PCT/US2008/061883
申请日：2008-04-30
申请人： FINA TECHNOLOGY, INC. , GEUNTHER, Gerhard , GRAY, Steven , COFFY, Tim
发明人： GEUNTHER, Gerhard , GRAY, Steven , COFFY, Tim
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/69 , C08F2/14 , C08F210/14 , C08F2500/12
摘要： A process for the polymerization of ethylene to provide an ethylene polymer of reduced Yellowness Index. A feed stream, comprising an inert hydrocarbon diluent containing ethylene in a minor amount, is supplied to a polymerization reactor. A chromium-based polymerization catalyst and a triethylboron co-catalyst are incorporated into the feed stream within the reactor. The polymerization catalyst will normally be used in an amount within the range of 0.008-0.1 wt. % of the diluent in the feed stream and the triethylboron co-catalyst is incorporated in an amount within the range of 0.1-50 ppm of the diluent. The polymer fluff from the reactor is heated to a temperature sufficient to melt the fluff which is then extruded to produce a polymer product. The Yellowness Index after high temperature aging is at least 5% less than the corresponding Yellowness Index of a corresponding polymer product produced without the triethylboron co- catalyst.
摘要翻译：一种聚合乙烯以提供降低黄度指数的乙烯聚合物的方法。将包含少量乙烯的惰性烃稀释剂的进料流供给到聚合反应器中。将铬基聚合催化剂和三乙基硼助催化剂并入反应器内的进料流中。聚合催化剂通常的用量范围为0.008-0.1wt。进料流和三乙基硼助催化剂中稀释剂的％的掺入量在稀释剂的0.1-50ppm的范围内。将来自反应器的聚合物绒毛加热到足以熔化绒毛的温度，然后将其挤出以产生聚合物产物。高温老化后的黄度指数比相应的不含三乙基硼助催化剂的聚合物产物的黄度指数小至少5％。

8. 发明申请

WO2008137722A1 BIMODAL POLYETHYLENE RESINS THAT HAVE HIGH STIFFNESS AND HIGH ESCR 审中-公开
标题翻译：双重聚乙烯树脂具有高耐磨性和高耐磨性
公开(公告)号：WO2008137722A1
公开(公告)日：2008-11-13
申请号：PCT/US2008/062474
申请日：2008-05-02
申请人： FINA TECHNOLOGY, INC. , COFFY, Tim , GEUNTHER, Gerhard , GRAY, Steven
发明人： COFFY, Tim , GEUNTHER, Gerhard , GRAY, Steven
IPC分类号： C08G85/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F2/001 , C08F2500/05 , C08F2500/13 , C08F2500/07 , C08F2500/11 , C08F2500/12 , C08F210/08
摘要： A bimodal polyethylene having a high density ranging from about 0.955 to about 0.959 g/cc, an improved environmental stress cracking resistance (ESCR) of from about 400 to about 2500 hours, and an improved 0.4% flesxural modulus of from about 180,000 to about 260,000 psi (1,200 MPa to about 1,800 MPa) may be formed using a Ziegler-Natta polymerization catalyst using two reactors in series. The bimodal polyethylene may have a high load melt index (HLMI) of from about 2 and about 30 dg/min and may be optionally made with a small amount of alpha-olefinic comonomer in the second reactor. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.72(b).
摘要翻译：具有约0.955至约0.959g / cc的高密度的双峰聚乙烯，约400至约2500小时的改善的耐环境应力开裂性（ESCR）以及约180,000至约260,000的改善的0.4％纤维模量可以使用串联的两个反应器的齐格勒 - 纳塔聚合催化剂形成psi（1,200MPa至约1800MPa）。双峰聚乙烯可以具有约2和约30dg / min的高负载熔体指数（HLMI），并且可以任选地在第二反应器中用少量的α-烯烃共聚单体制备。要强调的是，该摘要被提供以符合要求摘要的规则，这将允许搜索者或其他读者快速确定技术公开的主题。提交它的理解是，它不会用于解释或限制权利要求的范围或含义。 37 CFR 1.72（b）。

9. 发明申请

WO2006065713A3 SOLUBLE MAGNESIUM COMPLEXES USEFUL FOR THE PRODUCTION OF POLYOLEFIN CATALYSTS AND CATALYSTS PREPARED THEREWITH 审中-公开
公开(公告)号：WO2006065713A3
公开(公告)日：2006-06-22
申请号：PCT/US2005/044826
申请日：2005-12-12
申请人： FINA TECHNOLOGY, INC. , COFFY, Tim , GRAY, Steven
发明人： COFFY, Tim , GRAY, Steven
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J37/00 , C08F2/00 , C08F4/02 , C08F4/60 , C07F7/22 , C07F7/26 , C07F7/30 , B29B9/00 , C08G85/00
摘要： A method of forming a polyolefin catalyst component includes halogenating metal complexes. The metal complexes result from reacting a metal alkoxide with an alcohol-ether. A particular non-limiting example is a magnesium complex formed by reacting magnesium alkoxide with an ethylene alcohol-ether, and then chlorinating the magnesium complex. Catalyst components, catalysts, catalyst systems, polyolefin polymers and methods of making each are disclosed.

10. 发明申请

WO2009061715A1 PRODUCTION OF HYDROPEROXIZED FUNCTIONALIZED OLEFINIC COMPOUNDS 审中-公开
标题翻译：生产水合氧化官能化烯烃化合物
公开(公告)号：WO2009061715A1
公开(公告)日：2009-05-14
申请号：PCT/US2008/082327
申请日：2008-11-04
申请人： FINA TECHNOLOGY, INC. , KHABASHESKU, Olga , CLARK, Jason , HARDEN, Steve , GRAY, Steven , STEVENS, Vance , CORLETO, Carlos
发明人： KHABASHESKU, Olga , CLARK, Jason , HARDEN, Steve , GRAY, Steven , STEVENS, Vance , CORLETO, Carlos
IPC分类号： C07C409/00
CPC分类号： C08J3/28 , C08J2321/00
摘要： Process for the preparation of a hydroperoxide functionalized olefinic compound in an oxidation reactor containing a particulate catalyst bed comprising a light induced photosensitized catalyst component supported on a particulate substrate material forming a permeable catalyst bed. The photoenergized catalyst component is a photoreductant material which is effective for the conversion of triplet oxygen to singlet oxygen under illumination with ultraviolet or visible light. An oxygen containing feed stream containing triplet oxygen is supplied to the catalyst bed. The catalyst bed is irradiated at an intensity to convert triplet oxygen to singlet oxygen to produce a singlet oxygen enriched gas stream. The enriched gas stream is supplied to a second reactor which contains a dispersion of an olefmic component having an allylic hydrogen which is contacted with the enriched gas stream under conditions effective to cause an allylic rearrangement and introduce hydroperoxide functionalization into the olefinic component.
摘要翻译：在含有颗粒催化剂床的氧化反应器中制备氢过氧化物官能化烯烃化合物的方法，所述颗粒催化剂床包含负载在形成可渗透催化剂床的颗粒基质材料上的光诱导的光敏催化剂组分。光电催化剂组分是一种光致抗蚀剂材料，其在用紫外线或可见光照明下有效地将三线态氧转化为单线态氧。将含有三重态氧的含氧进料流供给催化剂床。以强度照射催化剂床，以将三线态氧转化为单线态氧以产生单线态富氧气流。将富集的气体流供应到第二反应器，该第二反应器含有具有烯丙基氢的烯烃组分的分散体，所述烯烃氢在有效引起烯丙基重排的条件下与富集气流接触，并将氢过氧化物官能化引入到烯烃组分中。

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